Fully Charged Royal Institution Christmas Lectures


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This fantastic prototype sports car is powered by a remarkable

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energy storage device -

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a device that we carry around in our pockets and a device that's helped

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revolutionise the modern world.

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The battery.

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In this lecture, I'm going to investigate one of the most

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important scientific challenges of our generation.

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What's the best way to store energy?

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To find out, we are going to try and get into

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the Guinness Book Of World Records with a very special battery.

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Welcome to my final 80th anniversary Christmas lectures.

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I'm Saiful Islam, I'm a professor of chemistry at the University of Bath.

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When we talk about energy storage, we're often talking about one thing,

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the battery. Try to imagine a world without them -

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you'd have no mobile phones, no laptops,

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tablet computers or even remotes for your TV.

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I think batteries are amazing.

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But they can be very, very familiar,

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so I wanted to show you an unusual and slightly, in fact, I think,

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quite scary, demonstration of what batteries can do.

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So I've rigged this up.

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This is...

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..an arc welder, not something I thought I'd be doing.

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It uses electricity to cut through solid metal.

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It's one of the most energy-intensive processes you can think of.

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The actual tip here can reach 20,000 Celsius,

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and that extractor fan there is going to take up the fumes.

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But the welder is hooked up to just a couple of ordinary car batteries

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and come with me and I'll show you what they look like.

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So right here are two ordinary car batteries and we've hooked them up

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but we've put them out here because there is a small chance

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they might explode.

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So let's try and set things up.

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So, I'm no welder, I'm just a humble chemist,

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but I'll be happy to give it a go.

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So this is my hand in glove.

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So it is really important at this stage, right, before I get down here...

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So if you can put your goggles on now.

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I tried something earlier.

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It wasn't a fantastic effort.

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Right.

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Let's see if that's better than my first attempt.

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Well, let's have a look.

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So if you look here, I tried to do RI twice.

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I don't think I'll give up my day job and become a welder.

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So I'd say that's my abstract period and that's my sort of dodgy period.

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So, anyway, I hope the sparks were flying there.

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So that is a very intensive process.

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But remember, that was done from the energy from a couple of

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car batteries. Storing energy is more important now than at any time

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in human history. It affects all aspects of our lives.

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So how many of you

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have got phones in your pockets?

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I imagine most of you.

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So why don't you get them out?

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Let's have a look at them.

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OK, and you can turn them on.

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So a simple question - how many of them are fully-charged?

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Who's got them fully-charged?

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Not that many. How many are less than half-charged?

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Right.

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And how many of you have actually run out of battery altogether?

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Just a few of you.

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So our phones often struggle to last a single day.

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Over the next hour, I'm going to try and do something truly amazing -

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I'm going to look at how we might supercharge a mobile phone

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and get it to last a whole year without plugging into the mains.

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So I'm sure all of you, and I know I would, would love one of those.

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So how much energy would that take?

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Look at this energy meter over here.

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OK, so...

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This meter uses units we can all understand -

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AA batteries.

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Our target for the year is about 800 AA batteries, which you will see,

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vroom, 800.

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So, to give you a better feel of what that looks like,

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I've got this large container and I'm going to go up the...

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..ladder to pour them in.

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Oh, they are down there.

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Erm, I think I need a volunteer to help out.

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Any volunteers to help out?

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So do you want to come round? Yes, come over.

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Can I take your name?

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Asheen?

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This is Asheen, he's going to help me put those batteries in there.

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So if you could pass me one bucket at a time.

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So this is what the 800 AA batteries look like if you wanted to power

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your mobile phone for a whole year.

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OK. Do you want to give me another bucket there?

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So, that's...

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..two.

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So this is...

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Just two more to go.

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And the last one.

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Let's see. So you can see, it's already really gone up

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to a high height. And then, the last lot.

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So it's already gone to the top.

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So that's what you would need to power your phone for a year.

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Can you imagine trying to carry that around in your pocket?

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You'd need some very large pockets there.

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Thank you, thank you very much.

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Let's thank him.

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So you can see already it's going to be a tough challenge.

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The key is storing more energy in a smaller size and a lighter weight.

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We want to increase something we call energy density.

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But first, it always helps to know our scientific history.

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Who made the first chemical battery?

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So one of the earliest batteries is right here in the vaults

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of the Royal Institution and we can show it to you right now.

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So this is our museum curator, Charlotte, and she'll be holding it.

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I'm not allowed to touch it because it's very precious.

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Here is a voltaic pile.

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It was made by Alessandro Volta in Italy and given to Michael Faraday

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nearly 200 years ago.

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So what is it made of?

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So you can see,

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it's got these kind of metal slabs and they are the metal electrodes,

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so zinc and copper.

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Between them, I don't know whether you can see on the camera,

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there's kind of cloth, a bit of cloth there,

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and that would have been soaked with salt water.

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It might look crude, but it did store a small electrical charge.

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So you'd probably need 1,000 of these to power your current

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modern mobile phone.

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But this was a key moment in the history of science.

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It was one of the first times anyone had been able to store electricity.

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It gave birth to a whole new field called electrochemistry.

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So thank you, Charlotte, thank you.

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So the voltaic pile I've just shown you and all batteries basically work

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on the same principle.

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A good way of explaining batteries

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is with a very complex piece of machinery.

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A lemon.

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And here, we're going to actually...

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Something I prepared earlier.

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We've got basically how a lemon battery works.

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As before, with that voltaic pile, you've got a metal electrode,

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in this case, a copper nail.

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And we've got at the end of this one, you can see a magnesium strip,

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which is the other electrode.

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So let's have a look at this voltmeter.

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So if you look at the value at the moment, it should be reading zero.

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So if I plug this in, it should, hopefully, give us a voltage.

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So you can see that

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and it's gone up to 1.42, 1.43 volts.

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Actually, 1.44.

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So actually it's showing a voltage.

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But these are the Christmas lectures.

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One lemon is not enough.

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So I wanted to go large.

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I told the Royal Institution I wanted to go very large,

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and it's so large it won't even squeeze into this lecture theatre.

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So follow me and I'm going to show you what it looks like.

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So this here is the biggest lemon battery the world has ever seen.

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It's gigantic.

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Look at it. Over 1,000 lemons.

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In fact, we cut them in half and sliced them

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to make 2,016 lemon slices, so this is cutting-edge technology.

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LAUGHTER

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Let me get a closer look at one of these batteries, OK.

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Joe, do you want to get closer to one of these batteries?

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So look - this is exactly one of the batteries that I showed you inside,

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with the electrodes and clips.

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So let me meet the adjudicator from the Guinness Book Of World Records,

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Craig, Craig Glenday, great to meet you.

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So let's move over to the voltmeter.

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So as you know, there were some issues with some of the lemons,

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so we weren't sure if we were going to quite reach the target.

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But what's the target we need to get to, to break a world record?

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To achieve the official Guinness World Records title,

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you must exceed 1,000 on the meter.

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So we are looking for 1,000 or more to be successful.

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OK, so, I'm going to do the connection

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and it rests on whether I can connect them up properly

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and we're going to pass that total.

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But I need a very large...

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..countdown from the audience so I can hear it from here.

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So give me a countdown.

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AUDIENCE: Three, two, one.

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So what does it read, Craig?

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I'm very pleased to say it reads 1,275,

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so you've more than broken the Guinness World Records title.

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-Congratulations.

-Great!

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We've done it! We've got a world record!

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Yay!

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That was exciting. It was actually very nerve-racking and it was quite

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close to the edge, just before this lecture.

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So this may be the biggest lemon battery in the world.

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But could it power our phone for a year?

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We have a scientific term for that.

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No way, Jose.

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To really understand how that lemon battery worked,

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we need to get at the atomic level,

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we need to understand the chemistry.

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And this, right in front of you,

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is a scaled up version of that lemon battery.

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So let me explain what we have here.

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So this is the magnesium strip, that's one of the electrodes.

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And here we have a very oversized nail,

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the copper nail that was in there.

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And in between that is a representation of the lemon juice,

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the electrolytes, in between those two electrodes.

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So that is the battery.

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So what's going around the side?

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So around here is...

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..the wire, the external circuit,

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where the electrons should pass through.

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OK. So that is basically the battery and the external circuit.

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So I need a volunteer, please.

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And I think we have one already arranged, so, Isaac,

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do you want to come down?

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OK.

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So, Isaac, do you want to come round to the front here?

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So, we've got...

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..a board for you to wear.

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I know it's not a very fetching board,

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but it tells us exactly what you are for this evening.

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So you are, for this evening only, you're going to be a magnesium atom.

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OK? So what does a magnesium atom have?

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-It has...

-Is it electrons?

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Electrons, it does.

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So if you stay around just to the side here, right to the side there.

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So you're going to hold these two electrons.

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So get those two hands ready.

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The thing about these electrons,

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they do wander off, they're very mobile.

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So let's have a look. So if you hold that.

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Just to make it more difficult for you, I know you are not a juggler,

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you're going to hold those two electrons like that.

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So this is the magnesium atom with two electrons.

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So electrons are the smallest particles of the atom.

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They act as carriers of electrical charge.

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So when we talk about electricity, we are really talking about

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electrons moving.

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So what happens when we connect the wire?

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So you can see already that there is a clip there,

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already connected to that electrode so there's one clip here

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representing our other connection.

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So I'm going to connect that to the magnesium electrode and I'm going to

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connect it to the circuit in a second.

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And before that, can you get ready with your electron?

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So if you hold it there but don't let it roll it yet.

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So just hold it there and when I connect them,

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just give it a little nudge, a little push around that circuit, OK.

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So let me make the connection now and then give it a little nudge, yeah.

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So this electron moving is electricity and actually,

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it would power that lamp. There you are.

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Here's another electron.

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There you are. So those electrons, ie,

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these large balls representing them are actually powering a device.

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And that's how the start of that process works.

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But there's another driving force -

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that magnesium atom has just lost two negatively charged electrons.

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So what happens there?

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It becomes...

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..a magnesium ion.

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Yes. And there is a driving force that pushes that ion

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across the pool, the electrolyte.

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So do you want to go through that pool, but very carefully, because it's full of balls.

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Right to the other side.

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So, if you come to the side here.

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Great. So you're an ion now.

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How you feeling? Positive?

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Great.

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LAUGHTER

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So that's basically how that lemon battery worked.

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What happens here,

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there are some further chemical reactions to balance the charges.

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But this is not rechargeable.

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What happens is that, once we've used up all the metal,

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it goes from that side to this side and if it uses up all that metal,

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you actually don't produce any more electricity.

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So this is not a rechargeable battery

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like the ones that you find in your phones.

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Thank you, Isaac, for helping out.

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And thank you very much. OK. Do you want to go back to your place?

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Almost all of the rechargeable batteries

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in your phones and laptops rely on a single rare

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and extraordinary metal.

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As part of our 80th celebrations,

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we are inviting Christmas lecturers past to help out.

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To introduce you to the properties of this material,

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please welcome the 2012 Christmas Lecturer

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and fellow chemist, Dr Peter Wothers.

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-Hi there, Peter.

-Hi there.

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Peter, I'm so glad you could join us.

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It's great to be back.

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So, tell us about your lectures back four years ago, 2012.

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So we were looking at the chemistry of the elements,

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so all the different elements around us and how important they are

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-in our everyday lives.

-I really enjoyed watching them.

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So what was your favourite demonstration amongst the lectures?

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I think my favourite one was actually when we burnt a diamond

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in oxygen gas.

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So Harry Kroto, Nobel Prize winner, came down and helped out and it was

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just absolutely fantastic to see this tiny little diamond in the gas

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there just glowing beautifully like a little star trapped in a jar.

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-It is quite stunning to see, isn't it?

-That's right, yes.

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There are no flames coming from this, so this is just,

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again, the heat of the reaction as the carbon combines with the oxygen

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that's present flowing through here forming carbon dioxide.

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That is absolutely stunning.

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Just look at that, it's glowing all by itself,

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it's absolutely brilliant.

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So I've got you on for a specific reason -

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I've mentioned this strange material.

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Can you tell us a bit more about it?

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Yes, so, this is one of the elements and it's a metal

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and I've got a little sample in the jar here.

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This metal is actually incredibly reactive,

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much more reactive than a lump of iron would be.

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It's in fact so reactive that it reacts with air and with water,

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as we shall see in a minute.

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So this is...

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Let me just take a piece out. This is in the form of foil.

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And you can see it's just a nice,

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shiny metal there and it's the element lithium.

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And this is actually in fact so light that it will float on water,

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-which is rather nice.

-Let's have a see.

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-OK, but you might want to step back a little bit.

-I will do.

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OK, there we go.

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And that's because it's instantly reacting with the water.

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The lithium metal is turning into lithium ions,

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which are dissolving in the water there and also giving out

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hydrogen gas and forming an alkaline hydroxide solution.

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-It's gone already.

-It's great.

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Well, thank you, Peter, for telling us about this strange material,

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the lithium metal, and with an elegant demonstration.

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-Let's thank Peter Wothers once again.

-Thank you.

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So why keep such a reactive metal in our pockets?

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What makes lithium so good?

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To illustrate this I've got a pair of lead acid batteries here.

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How much work can they do?

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Well, we've decided to show them a slightly different way.

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We've calculated how far they would turn a famous London landmark.

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So on this screen, you should see...

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This is just a time-lapse photography of the London Eye.

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Those lead acid batteries can actually turn the London Eye

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a certain amount. So let's see how much that could be.

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So we can see,

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it's only about 6%, OK.

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That would be around 27 metres of those pods moving round.

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These are lithium ion batteries

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of the same weight as our lead acid ones there.

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So let's see what they would do to this London Eye.

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So let's have a look. They would go round...

0:22:240:22:26

..25%.

0:22:290:22:31

So it moves the pods over 100 metres.

0:22:310:22:35

And that's because a lithium battery stores a lot more energy

0:22:350:22:39

than any older lead acid battery of the same weight.

0:22:390:22:42

It's what we call a higher energy density.

0:22:420:22:46

And this has big implications.

0:22:470:22:50

It's a great pleasure to welcome the 1987 Christmas Lecturer and previous

0:22:500:22:55

director of the Royal Institution, Professor Sir John Meurig Thomas.

0:22:550:23:01

APPLAUSE

0:23:010:23:02

Thank you very much.

0:23:060:23:08

Thank you.

0:23:080:23:09

Your lectures were some time ago.

0:23:150:23:16

What was the subject that you covered back then?

0:23:160:23:19

Crystals and lasers and I dealt mainly with crystalline materials.

0:23:190:23:24

Crystalline platinum in particular, not crystalline lithium.

0:23:240:23:29

Well, related to that, I've got you on for a specific reason,

0:23:290:23:32

holding a very interesting device. Tell us about what you are holding.

0:23:320:23:35

Well, this is a mobile phone manufactured in Texas in 1983.

0:23:350:23:40

It cost £4,000.

0:23:400:23:43

It's about 5lbs in weight.

0:23:430:23:46

It could allow you to speak for 30 minutes,

0:23:460:23:49

but you needed ten hours to charge it.

0:23:490:23:54

So I didn't buy one, I didn't buy one.

0:23:540:23:56

OK. So, Sir John, I think we've got some footage

0:23:560:24:00

from a previous lecture.

0:24:000:24:01

It's Professor David Pye of Queen Mary College, as it then was.

0:24:010:24:06

Find the phone under your seat there, it's ringing.

0:24:060:24:09

OK. Would you like to press the orange button please?

0:24:090:24:13

Take the call, then use it as an ordinary phone.

0:24:130:24:16

Hold it up to your ear.

0:24:170:24:19

Hello. Can you hear me on the phone?

0:24:200:24:23

-Very clearly.

-Good.

0:24:230:24:25

Can you tell me your name please?

0:24:250:24:26

Charles.

0:24:260:24:29

Great. Sir John, it's been a real pleasure and I'm glad you could

0:24:300:24:33

join us to describe that particular device.

0:24:330:24:37

So thank you very much.

0:24:370:24:38

It's a delight to be here.

0:24:380:24:40

Thank you.

0:24:400:24:41

Lithium ion batteries first came on the market in the early 1990s.

0:24:490:24:54

Probably way before most of you were born, actually.

0:24:550:24:59

They've helped power a worldwide portable revolution.

0:24:590:25:04

They've changed all our lives.

0:25:040:25:07

So why are lithium ion batteries so much better at storing energy?

0:25:070:25:11

To understand that, we need to get back to chemistry,

0:25:110:25:15

which is where I like to be.

0:25:150:25:17

So lithium has the smallest atoms or ions of any metal

0:25:170:25:23

in the periodic table.

0:25:230:25:25

So this is just a lithium atom,

0:25:250:25:29

but how does it compare to another atom in the periodic table?

0:25:290:25:33

So I'm going to hand it over to a couple of people here.

0:25:330:25:35

Can you just hold those?

0:25:350:25:37

So this is sort of a relative scale.

0:25:370:25:42

You've got lithium

0:25:420:25:44

and you've got the potassium.

0:25:440:25:47

And if you can hold those, you can see quite clearly

0:25:470:25:50

that lithium is a lot smaller

0:25:500:25:53

and the more ions you can pack into a battery or into a space,

0:25:530:25:59

the more energy you can store.

0:25:590:26:01

In fact, you can cram more lithium ions, the small lithium ions,

0:26:010:26:05

into the same space than any other metal.

0:26:050:26:09

So this gives lithium batteries their high energy density.

0:26:090:26:14

Because lithium ions are so tiny,

0:26:150:26:17

it's very difficult to see them using experiment alone.

0:26:170:26:21

So, as a chemist, I'm lucky that my research can use

0:26:220:26:27

modern supercomputers to model what is happening inside batteries

0:26:270:26:32

at the atomic level.

0:26:320:26:34

In fact, at parties,

0:26:340:26:36

when I get invited, that is,

0:26:360:26:38

when people ask me what I do, I sometimes say, "I model."

0:26:380:26:43

And this is a computer model of the atomic structure of that lithium,

0:26:440:26:50

of a lithium battery material.

0:26:500:26:52

So this is a lithium cobalt oxide electrode.

0:26:520:26:55

The cobalts are in purple, the oxygens are in red.

0:26:550:26:59

We can see the lithium ions zipping through between the channels.

0:26:590:27:03

So it's a very sheet-like structure and the important stuff is happening

0:27:030:27:09

between the sheets, so we can see the lithium ion just zipping through.

0:27:090:27:13

So they just indicate very fast ion motion.

0:27:130:27:18

So when you charge up your phone tonight,

0:27:180:27:20

probably Snapchatting to late in the evening,

0:27:200:27:25

when you see those red and green symbols, they just indicate

0:27:250:27:29

that tiny lithium ions are moving through a battery material.

0:27:290:27:33

Those tiny lithium ions are moving through those sheets.

0:27:330:27:36

But as you may have seen in the news recently,

0:27:380:27:41

batteries sometimes go wrong.

0:27:410:27:45

They overheat and it's usually due to short circuiting

0:27:450:27:48

and I should stress that this is a very rare event,

0:27:480:27:51

considering the billions of cells that have been sold

0:27:510:27:54

practically every week.

0:27:540:27:57

So we've set up a demonstration and this one is so dangerous

0:27:570:28:01

that we couldn't actually do it in the lecture theatre.

0:28:010:28:03

So we're doing it outside and we've set it up on the roof.

0:28:030:28:08

So what you see there is a lithium battery pack.

0:28:080:28:12

It's within a Perspex box, and right above it

0:28:120:28:15

you can just about see a tube and at the top of the tube,

0:28:150:28:21

you will see a giant nail.

0:28:210:28:24

And it's going to go straight down into that lithium ion battery.

0:28:240:28:28

And this is a serious point, do not attempt this at home.

0:28:280:28:33

OK. It's going to be pulled by that small string there,

0:28:330:28:36

that's going to release the rod

0:28:360:28:37

and that nail's going to go straight down.

0:28:370:28:39

So I think we need a countdown here, all right?

0:28:390:28:42

Another countdown.

0:28:420:28:44

ALL: Three, two, one.

0:28:440:28:46

So what you are seeing there is the reaction right on that

0:28:560:28:59

lithium ion battery.

0:28:590:29:00

So, as you can see, that is an intense reaction,

0:29:040:29:07

just from that nail going right through that lithium ion battery.

0:29:070:29:10

So what's happening there?

0:29:100:29:12

So what's happening is that the nail connects the two electrodes

0:29:130:29:17

and short-circuits the battery, which makes it overheat.

0:29:170:29:22

And this mimics the short-circuiting caused by bad battery design.

0:29:220:29:26

But it's not the lithium that explodes.

0:29:280:29:31

It's actually something else.

0:29:310:29:35

It's the liquid electrolyte that sits between

0:29:350:29:38

the two electrodes.

0:29:380:29:40

And that electrolyte is made up of a lithium salt in a solvent,

0:29:400:29:45

and that solvent is highly flammable.

0:29:450:29:48

Get it too hot and it simply erupts out of the casing.

0:29:480:29:52

So we're going to see a demonstration of this right now.

0:29:520:29:56

Natasha, I think we're ready, so give us a demonstration.

0:29:560:29:59

Great.

0:30:030:30:04

Thank you.

0:30:090:30:10

OK, so that's a very violent reaction.

0:30:140:30:17

So this overheating is sometimes called thermal runaway.

0:30:170:30:21

Which is a very rare event.

0:30:230:30:25

Obviously, as long as you don't drive a nail through your battery

0:30:250:30:29

or phone. So, let's get back to our original question.

0:30:290:30:33

Can we power our phone for a whole year

0:30:330:30:37

without plugging in to the mains?

0:30:370:30:39

Well, we've been working very hard behind the scenes, and guess what?

0:30:390:30:45

We've done it.

0:30:470:30:49

Here it is. We've done the maths and this would definitely run your phone

0:30:490:30:55

for a whole year. Inside, as you can see,

0:30:550:30:58

are several lithium ion batteries,

0:30:580:31:01

the size of car batteries wired together.

0:31:010:31:03

I need a volunteer here.

0:31:050:31:08

Yes. Yes, front row, come on over.

0:31:080:31:11

So, this is on a sort of rucksack.

0:31:180:31:22

Oh, yes, can I take your name?

0:31:220:31:24

-Adam.

-Adam, sorry.

0:31:240:31:26

Adam, well, Adam, you're going to try and lift that up.

0:31:260:31:29

So why don't you come round and give it a good pull up.

0:31:290:31:33

You're probably stronger than I am, so can you try and lift that up?

0:31:330:31:36

-This?

-Yeah.

0:31:360:31:37

That is heavy, isn't it?

0:31:380:31:39

Would you like to carry that with your mobile phone?

0:31:410:31:43

-No.

-Right, well, you've given that a good attempt,

0:31:430:31:46

so come over on this side here.

0:31:460:31:48

In fact, do you know how much that weighs?

0:31:480:31:50

You probably could tell - that weighs 30 kilos.

0:31:500:31:55

Actually, I can barely lift it as well.

0:31:550:31:57

So you're not going to put that very soon into your pocket,

0:31:570:32:00

unless you've got very large pockets.

0:32:000:32:03

So to make this work, we need somebody else to help out.

0:32:030:32:07

Please welcome Britain's strongest woman Andrea Thompson.

0:32:070:32:11

Thank you.

0:32:160:32:17

Thank you, Andrea, for joining us.

0:32:210:32:23

Thanks for having me.

0:32:230:32:25

You are Britain's strongest woman.

0:32:250:32:27

What did you have to do to get that accolade?

0:32:270:32:30

Well, I had to pick up 220 kilos in my hands, pull a truck,

0:32:310:32:37

a three-tonne truck

0:32:370:32:39

and lift a series of atlas stones from 80-120 kilos.

0:32:390:32:43

A three-tonne truck?

0:32:430:32:45

-Yes.

-So how far did you move with that?

0:32:450:32:48

20 metres.

0:32:480:32:49

-20 metres?

-Yeah. It was tough.

-Oh, right!

0:32:490:32:52

Well, let's see what you can do with this.

0:32:520:32:54

As you can see, we've got some straps here, so I wonder if you

0:32:550:32:58

could pick that up and see if you can put that on your back.

0:32:580:33:01

-OK.

-Let's give it a go.

0:33:010:33:03

So that's 30 kilos, remember.

0:33:030:33:05

It's a bit of a tight strap.

0:33:100:33:11

-There you are.

-Thank you.

0:33:140:33:15

-Does that fit now?

-That's fine.

0:33:150:33:17

Oh, yes!

0:33:180:33:19

That looks quite snug.

0:33:200:33:22

Yes!

0:33:220:33:23

That might be a solution for Andrea,

0:33:310:33:32

but I don't think it's practical for everyone else.

0:33:320:33:35

So, you can see, it's a possible solution,

0:33:350:33:37

but not quite a practical one.

0:33:370:33:40

You're going to carry that around for a whole year next to your phone.

0:33:400:33:43

Let's thank Adam, once again.

0:33:440:33:47

And we're going to thank Andrea. Thank you. Can you do us a favour?

0:33:470:33:51

-Can you take that off with you?

-Of course I will.

-Thank you. Thank you.

0:33:510:33:55

So can we do better?

0:34:040:34:06

Can we help our phones last longer on a single charge?

0:34:060:34:10

So we've talked about more powerful batteries, but obviously,

0:34:110:34:15

if your phone uses less,

0:34:150:34:18

then obviously it would last longer.

0:34:180:34:20

So which function on your phone uses the most energy?

0:34:200:34:24

Well, to answer this question, we need to smash open

0:34:240:34:28

someone's smartphone.

0:34:280:34:30

Actually, at this point, I would love to use my daughter's,

0:34:330:34:36

but I couldn't possibly do that.

0:34:360:34:38

So, any volunteers to have their phone smashed?

0:34:380:34:40

Yes. Give us your phone.

0:34:400:34:43

OK. Right, let's put it there.

0:34:430:34:45

So.

0:34:450:34:46

We need a countdown for this, OK.

0:34:470:34:50

So, three, two, one.

0:34:500:34:54

No, no, no.

0:34:540:34:56

No, of course I couldn't do that.

0:34:570:34:59

Don't worry, we've got our own set up here.

0:35:010:35:04

So this is obviously something again we've prepared earlier.

0:35:040:35:08

It has a voltmeter there and a typical mobile phone.

0:35:080:35:11

Mobile phones do lots of things, OK.

0:35:130:35:15

And this just actually gives an indication of the energy

0:35:150:35:21

used by the different functions

0:35:210:35:24

within that mobile phone.

0:35:240:35:26

And the numbers are really a relative number,

0:35:260:35:30

so don't worry about the units exactly,

0:35:300:35:32

but just look at the relative values.

0:35:320:35:34

So at the moment, you can see the relative values are fairly low, OK.

0:35:340:35:40

And that's the phone on idle.

0:35:400:35:43

So now...

0:35:430:35:44

..I think we're just turning it on.

0:35:450:35:47

And you can see straight away, just by turning it on,

0:35:470:35:51

the energy usage has gone up.

0:35:510:35:54

So if you look at the photo function, it whacks up.

0:35:540:35:58

Look at that. Taking photos, you can see the energy usage

0:35:580:36:05

sometimes touches numbers as high as 400.

0:36:050:36:08

And then you've got to use the internet to transmit that photo.

0:36:080:36:15

So this is the Wi-Fi.

0:36:150:36:17

So Wi-Fi drops down a bit, but still,

0:36:170:36:20

you've got relative energy usage.

0:36:200:36:23

And then lastly, I think we'll go on to Twitter and go to the

0:36:230:36:29

RI website and I think you'll see a very dodgy photo.

0:36:290:36:35

There you are. So again,

0:36:350:36:37

you can see the different functions are using different relative amounts

0:36:370:36:41

of energy. So taking photos and having your screen lit up

0:36:410:36:45

uses your battery up quickly.

0:36:450:36:47

But if you really want to save battery life,

0:36:470:36:50

then GPS is worth turning off, too.

0:36:500:36:53

Saving battery life is OK, but can only get you so far.

0:36:550:36:59

To stand a chance of powering our phone for a year,

0:37:000:37:04

we're going to need a new battery design.

0:37:040:37:08

So hundreds of research labs around the world,

0:37:090:37:13

including our research lab,

0:37:130:37:16

are searching for the next big battery discovery.

0:37:160:37:19

There are lots of new designs out there,

0:37:190:37:23

and I'd like to tell you about one of the most exciting examples,

0:37:230:37:27

actually theoretically, the best battery.

0:37:270:37:31

Can you please welcome Dr Lee Johnson

0:37:310:37:34

from Peter Bruce's group to operate this battery for me.

0:37:340:37:37

Thank you.

0:37:410:37:42

So this unusual battery uses just lithium metal reacting with oxygen

0:37:480:37:55

from the air. So it's a lithium oxygen battery.

0:37:550:37:59

This makes it very lightweight and very energy dense.

0:37:590:38:03

So what you have here, this is a vacuum chamber and inside it is

0:38:030:38:08

actually the lithium battery cell.

0:38:080:38:10

It's not powering these lights at the moment, OK.

0:38:100:38:14

The battery itself is made up of what we call a chemical sandwich.

0:38:160:38:21

So let me show you what that sandwich looks like.

0:38:210:38:24

Here it is. This is about half a gram of lithium metal, OK.

0:38:240:38:31

And that's within that very cell, only half a gram of lithium metal.

0:38:310:38:35

The other...

0:38:360:38:37

..part of that sandwich is just this kind of carbon mesh.

0:38:390:38:43

And this carbon mesh has a very high surface area,

0:38:450:38:49

and what that allows is the oxygen to react with the metal.

0:38:490:38:53

So if you let the air in,

0:38:530:38:55

we should see hopefully the lights go on from that reaction.

0:38:550:38:59

-Are you ready?

-Tell us what you're going to be doing here.

0:38:590:39:02

OK, so there's a vacuum in here. And I'm going to open this valve,

0:39:020:39:04

and that's going to let the air into this chamber.

0:39:040:39:06

And hopefully what you'll see is the pressure go up here,

0:39:060:39:10

and you'll see these lights come on.

0:39:100:39:12

-So, are we ready?

-OK.

-Yeah.

0:39:120:39:13

OK. So you'll hear a hiss.

0:39:130:39:15

And we should see it start to light up now.

0:39:200:39:23

-OK.

-So there you see, you can see it going.

0:39:230:39:26

So this is being produced by this lithium oxygen battery.

0:39:300:39:34

And that was only half a gram of lithium.

0:39:390:39:42

So this stores a high amount of chemical energy,

0:39:420:39:46

at least three times more energy than today's lithium ion batteries

0:39:460:39:51

in your mobile phones.

0:39:510:39:53

So these batteries are exciting.

0:39:530:39:56

They do need more research,

0:39:560:39:58

but they're probably at least a decade away for practical devices

0:39:580:40:03

in your phone.

0:40:030:40:05

So let's thank Dr Lee Johnson again. Thank you.

0:40:050:40:08

So, so far in this lecture,

0:40:170:40:19

we've mostly been looking into how to power our phone for a year.

0:40:190:40:23

I'm going to move away from that for a moment,

0:40:250:40:27

because I want to talk about some other ways energy storage

0:40:270:40:31

affects our lives.

0:40:310:40:33

One important area is the huge growth in renewable energy,

0:40:330:40:38

such as wind and solar.

0:40:380:40:41

Last year, the UK generated a quarter of our electricity

0:40:420:40:46

from renewables - solar, wind and wave power.

0:40:460:40:50

But what happens when the wind isn't blowing and the sun isn't shining?

0:40:500:40:55

So currently, there is no single solution.

0:40:550:40:59

Batteries will play a part, but we need something

0:41:000:41:04

on a much bigger scale.

0:41:040:41:06

There are a number of options.

0:41:070:41:09

People have tried pumping water into raised reservoirs when

0:41:090:41:14

energy's plentiful and releasing it to give us power at a later date.

0:41:140:41:19

This is sometimes called pumped hydro.

0:41:190:41:23

But there's one fascinating form of large-scale energy storage

0:41:230:41:26

I'd like to tell you about. It's called magnetic energy storage.

0:41:260:41:31

This is a strip of powerful magnets.

0:41:320:41:36

So you can see here, it forms this track round here.

0:41:360:41:39

And what we have here is some superconductors

0:41:410:41:45

in that liquid nitrogen.

0:41:450:41:47

These superconductors actually only work at very low temperatures.

0:41:470:41:51

So could you place that on this powerful strip of magnets?

0:41:510:41:55

And let's see it levitating around.

0:41:550:41:58

So let's give it another nudge there. Yes, it goes.

0:42:010:42:04

CROWD MURMURS EXCITEDLY

0:42:040:42:05

Yes. Yes, that's much better.

0:42:050:42:07

There it... Oh!

0:42:100:42:11

Yes!

0:42:130:42:14

Yes.

0:42:180:42:20

A superconductor is a material that shows powerful magnetic behaviour.

0:42:200:42:24

The reason this vehicle floats is because inside the superconductor

0:42:240:42:29

is an electric current that meets no resistance.

0:42:290:42:34

And if you make a ring out of this superconductor,

0:42:340:42:36

it forms a never-ending electrical circuit.

0:42:360:42:40

So this circuit can store large amounts of electricity to be used

0:42:400:42:44

later on. OK, so a round of applause there.

0:42:440:42:47

There's one other crucial area of our lives that better energy storage

0:43:030:43:08

could completely revolutionise -

0:43:080:43:11

the cars we drive.

0:43:110:43:13

We saw that sporty electric car at the beginning of the lecture.

0:43:130:43:18

Thanks to advances in lithium batteries, we're at the dawn

0:43:180:43:22

of the era of the electric car.

0:43:220:43:25

But they've got stiff competition.

0:43:250:43:29

We've seen that a couple of large lithium batteries could power

0:43:310:43:35

the London Eye a quarter turn.

0:43:350:43:38

So what would the same weight of petrol do?

0:43:380:43:42

So that's a quarter of a turn for the lithium ion battery.

0:43:420:43:47

How far would that petrol go?

0:43:470:43:51

So let's have a look.

0:43:510:43:53

It will go

0:43:530:43:54

three revolutions, four, 16, 18, 19, 20.

0:43:540:43:59

20 revolutions of the London Eye.

0:43:590:44:03

It stores more than 50 times the best lithium ion battery.

0:44:030:44:07

So in terms of energy, it's way, way ahead.

0:44:070:44:12

But as I'm sure you'll know, petrol has some serious problems.

0:44:130:44:17

So, a bit of chemistry here, and I am a chemist.

0:44:180:44:21

So, petrol...

0:44:210:44:23

..is made up of long chains of hydrogen and carbon,

0:44:260:44:30

which we call hydrocarbons.

0:44:300:44:33

So these are beautiful

0:44:370:44:41

molecular models of... This is octane.

0:44:410:44:44

So you can see the black are carbons,

0:44:440:44:48

the small white balls are hydrogen.

0:44:480:44:51

But there's a problem.

0:44:510:44:53

When you burn these, you get pure carbon, that black.

0:44:540:44:59

But you also get something else, something you can't see -

0:44:590:45:02

carbon dioxide.

0:45:020:45:03

And that's this feature there,

0:45:030:45:07

so that's carbon dioxide.

0:45:070:45:09

So if you take that.

0:45:090:45:10

So this is carbon dioxide.

0:45:110:45:13

So the carbon has reacted with oxygen,

0:45:130:45:16

so the reds are the oxygens and the carbon is in black.

0:45:160:45:19

But that's just the molecular model.

0:45:190:45:21

We're going to look and see how much energy they produce,

0:45:230:45:26

but also some of the pollution they may produce.

0:45:260:45:29

So we're going to burn just a bit of petrol.

0:45:290:45:32

There's a bit of petrol in that crucible,

0:45:320:45:35

and we're going to see the effect of burning that.

0:45:350:45:38

OK. So there's some petrol burning.

0:45:410:45:43

And what happens when you just put a simple tile over it?

0:45:440:45:49

Obviously do not do this at home.

0:45:540:45:56

And you can see very quickly how much carbon soot's been produced.

0:45:560:46:02

OK.

0:46:040:46:05

Thanks. Thanks, Natasha.

0:46:070:46:09

So that's the problem with today's cars -

0:46:100:46:14

petrol-powered road transport produces a lot of air pollution,

0:46:140:46:18

and going electric would be much better for air quality,

0:46:180:46:22

and better for the planet.

0:46:220:46:23

But first we need to solve a big issue with electric cars -

0:46:230:46:27

can we go a long distance without charging?

0:46:270:46:31

Some people call this range anxiety.

0:46:310:46:34

Did you know, though, that most car journeys in the UK are less

0:46:350:46:40

than 30 miles? But obviously it's nice to know that we can go further

0:46:400:46:44

if we need to.

0:46:440:46:46

And I've always wanted to celebrate New Year in Scotland,

0:46:460:46:51

so I wanted to find out if I could drive an electric car from

0:46:510:46:55

the Royal Institution here

0:46:550:46:57

to Edinburgh on one charge.

0:46:570:47:00

So we can see here,

0:47:010:47:04

hopefully you can, if you're not geographically challenged,

0:47:040:47:07

that here is London.

0:47:070:47:09

And to get to Edinburgh, you'd follow the A1

0:47:090:47:12

right up this path here.

0:47:120:47:15

So we want to look at different types of electric vehicle

0:47:160:47:21

and see how far we could go.

0:47:210:47:22

So I need a volunteer to help with this.

0:47:220:47:25

So I should get somebody from there, do you want to come down?

0:47:250:47:28

Great.

0:47:280:47:29

OK. So can I take your name?

0:47:340:47:35

-Sam.

-Sam, good. Could you come on this side here?

0:47:350:47:39

So we've got some different vehicles and I'm going to pass them to you.

0:47:390:47:43

Right, so first of all, we've got an electric golf cart.

0:47:430:47:50

OK. So what I'd like you to do, you're going to start there.

0:47:500:47:54

If you could just gently go up the A1 and when you feel a bit of

0:47:540:47:58

magnetic pull, just stop there, OK.

0:47:580:48:01

Let's go along there. Yes.

0:48:010:48:03

So the second vehicle, the G-Wiz.

0:48:030:48:06

Right. That's a G-Wiz vehicle,

0:48:080:48:10

that electric vehicle.

0:48:100:48:12

Right. See if you can actually feel some magnetic tension again.

0:48:120:48:16

There. Does it feel there? Yeah.

0:48:160:48:18

That's it. Actually, it doesn't go much further.

0:48:180:48:21

That G-Wiz car goes only about 50 miles outside London.

0:48:210:48:25

So let's go to the third vehicle.

0:48:250:48:27

And this is...

0:48:280:48:29

..a Nissan Leaf. This is an all-electric Nissan Leaf.

0:48:310:48:34

So if you can go along the A1.

0:48:340:48:35

About there. So that's actually about 124 miles outside London.

0:48:360:48:41

OK. So there are some actual London buses that are electric powered.

0:48:410:48:46

OK, let's have a go.

0:48:460:48:47

Let's do up from there and let's see how far you can get.

0:48:470:48:51

Is it feeling...? Around there. That's a good one.

0:48:520:48:54

So that is about 180 miles,

0:48:540:48:56

just a bit further than the Nissan Leaf.

0:48:560:48:58

The last one, this is the latest Tesla Model S.

0:48:580:49:03

OK. And let's see how far that goes.

0:49:030:49:07

So you can start from the London bus, let's see.

0:49:070:49:10

Gently go up there.

0:49:100:49:11

About there. It doesn't quite get to Edinburgh.

0:49:110:49:14

In fact, it's gone just over 300 miles from London.

0:49:140:49:19

So thank you again. Thank you.

0:49:190:49:21

Thank you.

0:49:210:49:22

So as we've seen, I'm not going to get to Edinburgh on one charge.

0:49:260:49:31

Petrol cars still have the edge on range.

0:49:310:49:35

But batteries are improving, thanks to worldwide research efforts.

0:49:350:49:40

So one way electric cars are seriously competing

0:49:400:49:43

is in performance.

0:49:430:49:45

And if you love fast cars like that sporty electric car I arrived in,

0:49:450:49:50

going electric might not be as bad as you think.

0:49:500:49:53

I asked the 2014 Christmas Lecturer, Professor Danielle George,

0:49:530:50:00

to put this to the test.

0:50:000:50:02

Hi, Saiful. Hi, everyone.

0:50:020:50:04

I'm here at a closed-off racetrack with two very exciting cars.

0:50:040:50:09

One of them is a petrol-powered supercar,

0:50:090:50:12

the Bentley Continental Titan,

0:50:120:50:14

which has been souped-up to within an inch of its life.

0:50:140:50:17

The other is an electric car, the Tesla Model S,

0:50:170:50:21

which looks a bit like a posh saloon.

0:50:210:50:23

But I'm going to be putting these two cars to the test to see

0:50:230:50:26

which one reaches 60mph the quickest.

0:50:260:50:29

Very, very exciting.

0:50:330:50:34

Three...

0:50:460:50:47

ENGINE REVS

0:50:470:50:48

Two, one.

0:50:480:50:50

HORN BLOWS

0:50:500:50:51

Wow!

0:50:510:50:53

Oh, my Lord!

0:50:530:50:54

Good grief!

0:51:030:51:04

That is amazing!

0:51:060:51:09

Oh. I'm still shaking!

0:51:090:51:11

It is seriously like being on some sort of roller-coaster.

0:51:140:51:18

It is so fast, and so quiet.

0:51:180:51:20

And I definitely left the Bentley Continental for dust.

0:51:230:51:28

Now, an all-electric car similar to this actually holds the record

0:51:280:51:32

for the fastest 0-60 time, and there's a reason for that.

0:51:320:51:36

A petrol car uses gears,

0:51:370:51:40

and so as we increase our speed,

0:51:400:51:42

we need to increase the gear that we're using.

0:51:420:51:44

And you can really see this on this graph here.

0:51:440:51:46

So what we have are both cars plotted here, time and speed.

0:51:460:51:50

The red is the electric car, and the black is the petrol car.

0:51:500:51:54

And you can see the speed and then the gear change here,

0:51:540:51:59

and then the increase in speed again after the gear has changed.

0:51:590:52:02

But with an all electric car,

0:52:020:52:04

we get peak performance from that electric motor as soon as our foot

0:52:040:52:08

hits that pedal. So there's no need for gears.

0:52:080:52:11

And the result is one mean, green speed machine.

0:52:120:52:17

And this is all possible thanks to better batteries.

0:52:170:52:20

Yes.

0:52:210:52:22

Thank you, Danielle. I think we'll be seeing a lot more electric cars

0:52:310:52:35

on our roads in the future, but maybe not going as fast

0:52:350:52:38

as that one, obviously.

0:52:380:52:41

For the moment, we're still stuck on petrol.

0:52:410:52:44

Is there anything that can beat it in terms of energy density?

0:52:440:52:48

Here are our lithium and potassium atoms from earlier.

0:52:480:52:52

And this is... I think it's nice to use a couple of volunteers.

0:52:520:52:58

If you hold on to those.

0:52:580:53:00

So I showed you... Just remind you, that's potassium and that's lithium,

0:53:000:53:04

and just to show their relative sizes.

0:53:040:53:06

Obviously, that's not the real size of their atoms.

0:53:060:53:10

But there's an even smaller atom we can use.

0:53:100:53:14

Hydrogen.

0:53:150:53:16

Just a single proton.

0:53:160:53:18

So I might as well put it right there, so if you just hold that.

0:53:180:53:23

So if you see the relative sizes,

0:53:230:53:25

this is to scale.

0:53:250:53:27

Hydrogen is five times smaller than lithium.

0:53:270:53:31

In fact, hydrogen is the smallest and lightest element

0:53:310:53:34

in the periodic table.

0:53:340:53:36

By weight, hydrogen is the most energy-dense fuel.

0:53:360:53:41

I think it's London Eye time again, to see how they compare.

0:53:410:53:46

So if you remember...

0:53:460:53:47

..30kg of lithium battery turned it a quarter, OK.

0:53:500:53:56

The same weight of petrol turned it...

0:53:560:53:59

..20 times.

0:54:000:54:02

This is the same weight of hydrogen fuel as a liquid.

0:54:020:54:07

Let's have a look.

0:54:070:54:08

Starts off 20, past 30, past 40.

0:54:100:54:15

62 revolutions.

0:54:150:54:18

It would power it for three whole days.

0:54:180:54:22

There's no doubt hydrogen contains a huge amount of energy,

0:54:220:54:27

and I can show you this with another simple demonstration -

0:54:270:54:31

a balloon full of hydrogen.

0:54:310:54:34

But this demo needs hands over your ears.

0:54:360:54:40

OK.

0:54:430:54:44

Whoa! Go on, yes!

0:54:490:54:52

Yes!

0:54:520:54:53

Right, so can we harness the energy from this powerful chemical reaction

0:54:570:55:02

more efficiently?

0:55:020:55:03

Yes, we can.

0:55:040:55:06

Hydrogen is used in things called fuel cells,

0:55:060:55:09

that are actually being used to power several London buses

0:55:090:55:12

right now. So can I use this super fuel to power my phone?

0:55:120:55:16

OK. This is a commercial fuel cell, it's a tiny one,

0:55:170:55:22

but you can't quite see inside it.

0:55:220:55:24

So we've got a demonstration fuel cell to show how it works

0:55:240:55:28

in this Perspex device here.

0:55:280:55:31

So what we have here is the oxygen

0:55:310:55:34

and the hydrogen. If they react within this fuel cell,

0:55:340:55:38

they can produce energy.

0:55:380:55:39

Now that can be shown easily by this fan here.

0:55:390:55:42

There you are.

0:55:440:55:45

A fuel cell is very similar to a battery -

0:55:500:55:52

it has two electrodes and an electrolyte.

0:55:520:55:55

But there's a big, big difference -

0:55:550:55:57

the battery is self-contained.

0:55:570:56:00

A fuel cell needs to be fed with hydrogen as a fuel.

0:56:000:56:04

So let me drink a typical fuel cell by-product.

0:56:040:56:08

It's just water.

0:56:130:56:14

So you can't get any cleaner than that.

0:56:140:56:16

But can it power my phone?

0:56:180:56:21

Shall we plug our phone into our working fuel cell?

0:56:210:56:25

OK, so this is a typical phone.

0:56:250:56:30

So let's turn on the device.

0:56:300:56:32

Hopefully you can now see the charging.

0:56:350:56:38

So this could power our phone for a whole year without plugging

0:56:380:56:43

in to the mains, but we still need to top it up with hydrogen.

0:56:430:56:48

Sadly, hydrogen is not the answer to all our energy problems, not yet.

0:56:480:56:53

We have to store it at a temperature of minus 250 degrees Celsius

0:56:530:56:58

to keep it a liquid.

0:56:580:57:00

This means that hydrogen is costly to store,

0:57:000:57:03

takes a lot of energy to produce, and has safety issues.

0:57:030:57:08

Finding better ways to store energy is still a vital challenge.

0:57:080:57:12

In these lectures,

0:57:140:57:15

we've celebrated the 80th anniversary

0:57:150:57:18

with Christmas lecturers past.

0:57:180:57:20

We've celebrated energy in all its different forms,

0:57:200:57:23

and broken a world record.

0:57:230:57:27

I've got one final energetic celebration -

0:57:270:57:31

I want to go out with a big bang.

0:57:310:57:33

Hands over your ears, and goggles on!

0:57:330:57:36

We're at the dawn of a new era in clean energy.

0:58:000:58:04

The next chapter of fuelling the future is for all of you to write.

0:58:040:58:09

So go out and charge ahead.

0:58:090:58:12

Thank you, and good night!

0:58:120:58:13

Thank you.

0:58:160:58:17

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