
Browse content similar to Stuff: A Horizon Guide to Materials. Check below for episodes and series from the same categories and more!
| Line | From | To | |
|---|---|---|---|
The buildings we live in, | 0:00:03 | 0:00:06 | |
the roads we drive on... | 0:00:06 | 0:00:08 | |
..the phones we speak into, | 0:00:10 | 0:00:13 | |
the screens we watch at night. | 0:00:13 | 0:00:16 | |
Our world is made up of materials. | 0:00:16 | 0:00:19 | |
They are the framework, the stuff of modern life. | 0:00:29 | 0:00:32 | |
Discovering and exploiting the materials that make up our planet | 0:00:36 | 0:00:40 | |
has been one of the most enduring quests of science | 0:00:40 | 0:00:43 | |
and helped us build the modern world. | 0:00:43 | 0:00:45 | |
Learning how to manipulate these materials | 0:00:45 | 0:00:48 | |
can be the making of both scientific reputations and potential fortunes. | 0:00:48 | 0:00:53 | |
For over 40 years, Horizon and the BBC has followed | 0:00:54 | 0:00:59 | |
science's bid to reveal and conquer the material world. | 0:00:59 | 0:01:03 | |
Charting the discovery of new materials... | 0:01:03 | 0:01:08 | |
We can see it and work with it, | 0:01:08 | 0:01:10 | |
and that was really the moment of high excitement for me. | 0:01:10 | 0:01:13 | |
..and proposing radical new uses for old favourites. | 0:01:14 | 0:01:17 | |
Super connectivity is beyond question | 0:01:17 | 0:01:21 | |
the most significant technological innovation | 0:01:21 | 0:01:24 | |
since the invention of the wheel. | 0:01:24 | 0:01:26 | |
Each new discovery offers a tantalising glimpse | 0:01:32 | 0:01:35 | |
of the Holy Grail of material science - | 0:01:35 | 0:01:38 | |
finding a material that's cheap to manufacture | 0:01:38 | 0:01:42 | |
which has the potential to change our world. | 0:01:42 | 0:01:46 | |
ROBOTIC VOICE: Go left onto the A3095. | 0:01:46 | 0:01:48 | |
And a series of extraordinary breakthroughs have done just that. | 0:01:53 | 0:01:57 | |
From superconductors to the silicon revolution, | 0:01:57 | 0:02:00 | |
materials have changed everything. | 0:02:00 | 0:02:03 | |
In 1990, an extraordinary new material hit the headlines. | 0:02:21 | 0:02:26 | |
This laser burns through half an inch of steel in a fraction of a second. | 0:02:26 | 0:02:31 | |
Few substances can survive such blasts of energy. | 0:02:31 | 0:02:35 | |
If the claims of this former hairdresser are true, | 0:02:37 | 0:02:40 | |
he holds the secret to a formulation that appears to defy science. | 0:02:40 | 0:02:44 | |
He calls his invention Starlite. | 0:02:44 | 0:02:47 | |
Maurice Ward was an amateur scientist, | 0:02:51 | 0:02:53 | |
yet he claimed to have invented an astonishing new plastic. | 0:02:53 | 0:02:58 | |
This torch here is producing a temperature of 1,200 degrees Celsius. | 0:03:00 | 0:03:04 | |
Try cooking an ordinary egg like that | 0:03:04 | 0:03:07 | |
and in a very few seconds, the results would be quite an explosion. | 0:03:07 | 0:03:12 | |
I'm going to leave this torch here blowing on this egg | 0:03:12 | 0:03:15 | |
for a couple of minutes before we crack it open | 0:03:15 | 0:03:17 | |
and it ought to survive the inferno, | 0:03:17 | 0:03:19 | |
because it's coated with a remarkable new plastic... | 0:03:19 | 0:03:22 | |
Its heat-resistant properties | 0:03:22 | 0:03:24 | |
apparently outstripped any known material. | 0:03:24 | 0:03:28 | |
-So how is it doing? -It hasn't broken up at all. | 0:03:28 | 0:03:30 | |
And you can see on the front, it's glowing red hot. Watch this. | 0:03:30 | 0:03:34 | |
If I turn the flame off, | 0:03:34 | 0:03:35 | |
and remember it was producing 1,200 degrees Celsius, | 0:03:35 | 0:03:38 | |
and I take the charred bit and I put it flat in the palm of my hand, | 0:03:38 | 0:03:42 | |
it only just feels warm. | 0:03:42 | 0:03:45 | |
And if I then crack it open, what's more... | 0:03:45 | 0:03:48 | |
..the egg hasn't even begun to start cooking. | 0:03:49 | 0:03:53 | |
The scientific community was intrigued. | 0:03:55 | 0:03:58 | |
We have heard so much about you. | 0:03:58 | 0:04:00 | |
We have seen films of you torching the egg. | 0:04:00 | 0:04:04 | |
In tests at the British Atomic Weapons Establishment, | 0:04:07 | 0:04:10 | |
Starlite even withstood blasts of over 900 kilotonnes, | 0:04:10 | 0:04:15 | |
more than 75 times the strength of the Hiroshima bomb. | 0:04:15 | 0:04:19 | |
So much power is being reflected off the surface of the Starlite, | 0:04:22 | 0:04:26 | |
it has actually blown up the thermal fuse | 0:04:26 | 0:04:29 | |
and switched the interlock system of the laser down. | 0:04:29 | 0:04:31 | |
It looked like Ward's new material had huge commercial potential... | 0:04:35 | 0:04:39 | |
..and he was determined to protect his incredible find. | 0:04:44 | 0:04:50 | |
No. We don't supply you the formulation. | 0:04:50 | 0:04:54 | |
Yes. Yeah. If we give the world the formulation, that's exit us. | 0:04:56 | 0:05:01 | |
Despite huge interest from big business and even NASA, | 0:05:01 | 0:05:07 | |
Ward refused to let any samples of Starlite out of his sight | 0:05:07 | 0:05:10 | |
or reveal any information about it. | 0:05:10 | 0:05:13 | |
All we are saying really is that I'm protecting my material, | 0:05:13 | 0:05:15 | |
and you ain't going to pinch it. | 0:05:15 | 0:05:18 | |
In 2011, he died, having neither made his fortune | 0:05:18 | 0:05:22 | |
nor diverged the formula of his plastic to anyone outside his family. | 0:05:22 | 0:05:28 | |
In many ways, Starlite epitomises the cutthroat world of materials. | 0:05:33 | 0:05:38 | |
A world where scientists search relentlessly | 0:05:38 | 0:05:41 | |
for ways of exploiting a new substance and big business watches, | 0:05:41 | 0:05:45 | |
waiting for signs of a breakthrough, | 0:05:45 | 0:05:47 | |
but if that breakthrough doesn't happen, | 0:05:47 | 0:05:50 | |
the spotlight sweeps on and one man's career-defining breakthrough | 0:05:50 | 0:05:54 | |
becomes yesterday's news. | 0:05:54 | 0:05:56 | |
Discovering new materials can be costly. | 0:06:07 | 0:06:10 | |
Even a man-made substance like plastic is derived from the earth's natural resources | 0:06:12 | 0:06:20 | |
and that means the expense of drilling for oil | 0:06:20 | 0:06:22 | |
or mining underground. | 0:06:22 | 0:06:24 | |
The lure for business is in finding the killer application. | 0:06:29 | 0:06:33 | |
One that can turn a material from an intriguing oddity | 0:06:33 | 0:06:37 | |
to a hot commodity almost overnight. | 0:06:37 | 0:06:40 | |
And sometimes, that happens with materials | 0:06:47 | 0:06:51 | |
we've known about for years. | 0:06:51 | 0:06:53 | |
This film is the story of a metal. | 0:06:53 | 0:06:55 | |
A metal which, for 150 years, | 0:06:55 | 0:06:57 | |
since its discovery at the end of the 18th century, was virtually unused. | 0:06:57 | 0:07:01 | |
Now, this metal is being dug and blasted from the earth | 0:07:03 | 0:07:06 | |
at such a rapidly increasing rate | 0:07:06 | 0:07:08 | |
that all known reserves could well be exhausted before the year 2000. | 0:07:08 | 0:07:13 | |
This is the story of uranium. | 0:07:13 | 0:07:16 | |
For decades, uranium had little value, | 0:07:23 | 0:07:25 | |
but the discovery that it was radioactive | 0:07:25 | 0:07:29 | |
was the key to unlocking its ultimate use... | 0:07:29 | 0:07:31 | |
..nuclear power. | 0:07:33 | 0:07:35 | |
Uranium doesn't have much of a past and it may well | 0:07:36 | 0:07:39 | |
not have much of a future, | 0:07:39 | 0:07:41 | |
but its present is to be the most sought-after | 0:07:41 | 0:07:44 | |
and most politicised commodity of the last decades of the 20th century. | 0:07:44 | 0:07:48 | |
For the last 25 years, | 0:07:48 | 0:07:50 | |
uranium has been the fuel of the world's nuclear reactors. | 0:07:50 | 0:07:53 | |
The fuel which is now expected to satisfy | 0:07:53 | 0:07:57 | |
a growing proportion of our energy needs. | 0:07:57 | 0:07:59 | |
And this is what all that effort is about. | 0:08:02 | 0:08:05 | |
And unremarkable bronze grey metal which for 40 years now, | 0:08:05 | 0:08:08 | |
we've known to have properties that make it unique. | 0:08:08 | 0:08:11 | |
During the 1970s, it was thought that nuclear power | 0:08:16 | 0:08:21 | |
would eventually supply more than half the world's electricity. | 0:08:21 | 0:08:25 | |
And the assumption that uranium reserves were limited | 0:08:25 | 0:08:28 | |
only added to its value. | 0:08:28 | 0:08:30 | |
A stampede of prospectors headed for the planet's | 0:08:35 | 0:08:37 | |
most remote locations in search of fresh uranium fields. | 0:08:37 | 0:08:41 | |
The uranium Klondike of the 1980s is in northern Saskatchewan, Canada. | 0:08:41 | 0:08:47 | |
The uranium that was known to occur around Uranium City | 0:08:47 | 0:08:50 | |
it's now suggested may extend over the whole of a geological feature | 0:08:50 | 0:08:54 | |
called the Athabasca basin. | 0:08:54 | 0:08:57 | |
This is the sort of country where you may stumble upon a boulder | 0:08:57 | 0:09:00 | |
made up of 50% uranium. | 0:09:00 | 0:09:03 | |
Do you want to come over and take a look at this? | 0:09:03 | 0:09:05 | |
I think we've got ourselves a bonus boulder. | 0:09:05 | 0:09:07 | |
It puts this enormous deposit in perspective and is a measure of the uranium problem | 0:09:07 | 0:09:11 | |
to realise that in the 1990s, | 0:09:11 | 0:09:14 | |
we'll have to find and mine a new Athabasca Basin every two years. | 0:09:14 | 0:09:19 | |
But more than 30 years later, new deposits are still being discovered | 0:09:23 | 0:09:28 | |
and uranium prices have fallen in real terms. | 0:09:28 | 0:09:32 | |
The idea that there's money to be made has often fuelled | 0:09:34 | 0:09:37 | |
a boom or bust gold rush for new finds, | 0:09:37 | 0:09:39 | |
but such obsessions are nothing new. | 0:09:39 | 0:09:42 | |
200-odd years ago, aluminium was actually rarer than uranium | 0:09:42 | 0:09:46 | |
and the Emperor Napoleon had an aluminium dinner set made. | 0:09:46 | 0:09:50 | |
So valuable was it, he was the only one allowed to use it | 0:09:50 | 0:09:53 | |
and his guests were forced to make do with plates of silver and gold. | 0:09:53 | 0:09:58 | |
Nowadays, most of us occasionally have an aluminium dinner set | 0:09:58 | 0:10:01 | |
and when we've finished with it, we throw it away. | 0:10:01 | 0:10:04 | |
Each time an idea for a potentially valuable material appears, | 0:10:07 | 0:10:11 | |
both science and industry get excited. | 0:10:11 | 0:10:14 | |
In 1978, it was the turn of something called manganese nodules. | 0:10:15 | 0:10:21 | |
Take a fair-sized ship | 0:10:21 | 0:10:23 | |
almost anywhere in the north-east Pacific Ocean. | 0:10:23 | 0:10:26 | |
Drop overboard a television camera | 0:10:26 | 0:10:28 | |
on the end of five kilometres of cable and you will see, | 0:10:28 | 0:10:31 | |
as these German technicians are seeing, mile upon mile | 0:10:31 | 0:10:35 | |
of small, round black things | 0:10:35 | 0:10:37 | |
scattered across the deep ocean floor. | 0:10:37 | 0:10:41 | |
They are manganese nodules, and they are infinitely more interesting | 0:10:41 | 0:10:44 | |
than they look at first sight. | 0:10:44 | 0:10:47 | |
What you are looking at is one small corner of a magic carpet | 0:10:47 | 0:10:51 | |
whose cash value has been estimated at ten million million dollars. | 0:10:51 | 0:10:57 | |
Manganese nodules are fascinating to scientists, | 0:10:58 | 0:11:00 | |
who cannot completely explain what they are and where they come from. | 0:11:00 | 0:11:05 | |
Manganese nodules are tempting to industrialists, | 0:11:05 | 0:11:09 | |
who need the valuable copper and nickel in them. | 0:11:09 | 0:11:11 | |
The past and the future of these humble blackish stones, then, | 0:11:11 | 0:11:15 | |
is of absolutely vital interest to the world. | 0:11:15 | 0:11:19 | |
The lure of rich profits prompted industrialists to pour money | 0:11:25 | 0:11:29 | |
into identifying the best nodule fields. | 0:11:29 | 0:11:32 | |
This computer can actually draw a contour map of the metal percentage | 0:11:34 | 0:11:38 | |
of a field of nodules, | 0:11:38 | 0:11:40 | |
but the information is destined to help the next boardroom decision. | 0:11:40 | 0:11:44 | |
Oceanographers may never see it. | 0:11:44 | 0:11:47 | |
But harvesting the nodules was just the first step. | 0:11:47 | 0:11:51 | |
Scientists still had to work out a way to extract the valuable minerals | 0:11:51 | 0:11:55 | |
once they'd brought them up from the sea bed. | 0:11:55 | 0:11:58 | |
RINGING | 0:12:00 | 0:12:02 | |
As much as success at sea, | 0:12:02 | 0:12:04 | |
profitability depends on the tricky chemistry of turning dull, grey grit | 0:12:04 | 0:12:09 | |
into shining and valuable metal. | 0:12:09 | 0:12:12 | |
The basis of the process is to leach out the metals with ammonia, | 0:12:12 | 0:12:16 | |
but with an extremely clever pre-treatment process. | 0:12:16 | 0:12:19 | |
The capital cost of a full-size plant is thought to be 340 million dollars, | 0:12:22 | 0:12:27 | |
another 220 million capital for the ocean mining system. | 0:12:27 | 0:12:31 | |
Annual income - 250 million dollars from sale of the copper, nickel and cobalt. | 0:12:33 | 0:12:38 | |
Assuming 48% tax, total profits from a 25-year project | 0:12:38 | 0:12:43 | |
have been estimated as one-and-a-half thousand million dollars. | 0:12:43 | 0:12:47 | |
Millions were ploughed into developing the industrial process | 0:12:52 | 0:12:56 | |
needed to exploit the manganese nodules. | 0:12:56 | 0:12:59 | |
But the huge investment bore little fruit. | 0:13:00 | 0:13:04 | |
Within a few years, a cheaper source of nickel | 0:13:05 | 0:13:08 | |
had been discovered on land, and the nodules lost their allure. | 0:13:08 | 0:13:13 | |
In their continuing pursuit of profitable materials, | 0:13:18 | 0:13:21 | |
scientists began to look even further afield. | 0:13:21 | 0:13:26 | |
CONTROL TOWER: Go for landing. | 0:13:36 | 0:13:38 | |
Eagle, Houston here. Go for landing. Over. | 0:13:38 | 0:13:41 | |
The six Apollo missions had brought back several hundred kilograms | 0:13:50 | 0:13:55 | |
of moon rock for scientific analysis. | 0:13:55 | 0:13:57 | |
Tests revealed that the rock contained a fuel | 0:13:59 | 0:14:03 | |
that could be used in fusion energy, | 0:14:03 | 0:14:06 | |
thought to be the future of electricity production here on Earth | 0:14:06 | 0:14:09 | |
and a resource potentially worth billions of dollars a tonne. | 0:14:09 | 0:14:14 | |
The twelfth and final man to walk on the surface of the moon | 0:14:16 | 0:14:20 | |
became obsessed with an extraordinary idea - mining it. | 0:14:20 | 0:14:26 | |
Harrison Schmidt was the only research scientist | 0:14:33 | 0:14:36 | |
among the 12 Apollo astronauts. | 0:14:36 | 0:14:39 | |
-This boulder is typical of the granitic rocks that form the core... -He's a trained geologist. | 0:14:39 | 0:14:44 | |
Probably an intrusive rock, | 0:14:44 | 0:14:46 | |
although it's sometimes very difficult to tell. | 0:14:46 | 0:14:49 | |
'See if I can't grab the corner and get that contact. | 0:14:49 | 0:14:52 | |
'It's obviously very, very cohesive, | 0:14:52 | 0:14:56 | |
'and fragmental-like.' | 0:14:56 | 0:14:59 | |
Schmidt came back from the moon and analysed samples he'd collected. | 0:14:59 | 0:15:04 | |
He found they contained significant quantities of helium 3. | 0:15:04 | 0:15:09 | |
We have significant information about the distribution of helium 3. | 0:15:11 | 0:15:15 | |
We of course sampled the soils | 0:15:15 | 0:15:17 | |
at Tranquillity Base, where Neil Armstrong landed. | 0:15:17 | 0:15:20 | |
We have indications of high titanium, | 0:15:20 | 0:15:24 | |
which is a surrogate for helium 3, | 0:15:24 | 0:15:27 | |
and then also, the polar regions | 0:15:27 | 0:15:29 | |
have high concentrations there, | 0:15:29 | 0:15:32 | |
so we have a pretty good basic understanding of where it is. | 0:15:32 | 0:15:36 | |
Helium 3 is a gas ejected from the surface of the sun... | 0:15:40 | 0:15:45 | |
..and blown through space by solar winds. | 0:15:48 | 0:15:51 | |
When it reaches the Earth, it's blocked by the atmosphere. | 0:15:53 | 0:15:58 | |
But on the moon, where there's nothing to block it, | 0:15:58 | 0:16:02 | |
the gas is trapped by the lunar soil. | 0:16:02 | 0:16:04 | |
Slowly, over billions of years, huge deposits have built up. | 0:16:06 | 0:16:11 | |
At first blush, using the most conservative figures | 0:16:15 | 0:16:18 | |
for the amount of helium 3 that's in the soils of the moon, | 0:16:18 | 0:16:22 | |
what we call the regolith of the moon, | 0:16:22 | 0:16:24 | |
there's about a million tonnes. | 0:16:24 | 0:16:27 | |
That's a lot of helium! | 0:16:27 | 0:16:29 | |
It would be enough to power the Earth for hundreds of years. | 0:16:31 | 0:16:34 | |
It's only within the last few decades that we've ever | 0:16:35 | 0:16:38 | |
thought about the moon as being a large source of energy. | 0:16:38 | 0:16:41 | |
In fact, it may be the Persian Gulf of the 21st century. | 0:16:41 | 0:16:44 | |
It seems preposterous, but Schmidt and Kulcinski | 0:16:46 | 0:16:50 | |
have set up a company with the extraordinary idea | 0:16:50 | 0:16:53 | |
of strip mining the moon and transporting helium 3 | 0:16:53 | 0:16:56 | |
as a liquefied gas a quarter of a million miles back to Earth. | 0:16:56 | 0:17:02 | |
It's not a madman's dream to go to the moon and access these resources. | 0:17:15 | 0:17:19 | |
We've been there, we know how to do it, we can estimate the cost. | 0:17:19 | 0:17:22 | |
That's not a madman's dream. | 0:17:24 | 0:17:27 | |
While it may be technically possible, | 0:17:36 | 0:17:38 | |
the economics of mining the moon remain prohibitive. | 0:17:38 | 0:17:41 | |
For now, Harrison Schmidt's dream remains in the realms of fantasy. | 0:17:44 | 0:17:48 | |
Back on Earth, scientists have been constant in their quest | 0:17:55 | 0:17:59 | |
not just to exploit the raw materials around us, | 0:17:59 | 0:18:01 | |
but to understand them as well, and if the key to progress | 0:18:01 | 0:18:05 | |
lies in manipulating materials, then we must know what gives them | 0:18:05 | 0:18:08 | |
their distinctive properties, | 0:18:08 | 0:18:12 | |
like clay - squishy, malleable. | 0:18:12 | 0:18:14 | |
Iron - hard as. | 0:18:15 | 0:18:19 | |
Through intriguing experiments and testing things to destruction, | 0:18:26 | 0:18:32 | |
scientists gradually learned more about the nature of materials. | 0:18:32 | 0:18:38 | |
It's a compact, almost claustrophobic world | 0:18:38 | 0:18:41 | |
and the men working in it are, perhaps have to be, | 0:18:41 | 0:18:44 | |
total enthusiasts. | 0:18:44 | 0:18:46 | |
But to understand them fully, | 0:18:46 | 0:18:49 | |
they needed to find a way of peering inside. | 0:18:49 | 0:18:52 | |
In the 1970s, a new generation of technology changed | 0:18:54 | 0:18:59 | |
materials research by allowing scientists to scrutinise them in far greater detail. | 0:18:59 | 0:19:05 | |
They're helped by pictures produced by this machine. | 0:19:09 | 0:19:12 | |
It's a scanning electron microscope | 0:19:12 | 0:19:14 | |
and it can be used to study | 0:19:14 | 0:19:15 | |
the internal structure of, for example, this specimen, | 0:19:15 | 0:19:19 | |
something which, to the naked eye, | 0:19:19 | 0:19:21 | |
looks like a tiny fragment of unfired pottery. | 0:19:21 | 0:19:24 | |
The sample is enclosed in the inspection chamber, | 0:19:24 | 0:19:27 | |
which is sealed so that it can be pumped down to a vacuum. | 0:19:27 | 0:19:30 | |
The fragment will then be scanned by an electron beam | 0:19:31 | 0:19:34 | |
to produce an image of the exposed surface, which is projected like a television picture. | 0:19:34 | 0:19:39 | |
New imaging technology vastly improved our understanding of materials. | 0:19:43 | 0:19:49 | |
Deeper insight enabled scientists to manipulate substances | 0:19:49 | 0:19:54 | |
and push them to new capabilities, | 0:19:54 | 0:19:56 | |
such as creating a metal that behaved like a plastic, | 0:19:56 | 0:20:00 | |
a super-plastic metal. | 0:20:00 | 0:20:03 | |
Here, a foot-square panel of metal is being heated | 0:20:03 | 0:20:08 | |
and it'll be blown up by air pressure. | 0:20:08 | 0:20:10 | |
Pressure is now coming on. | 0:20:11 | 0:20:14 | |
An ordinary soft metal would already be thinning, ready to burst. | 0:20:20 | 0:20:24 | |
Vacuum on. | 0:20:24 | 0:20:25 | |
Stage two, it's now being sucked down into the box | 0:20:28 | 0:20:31 | |
and still without any sign of bursting. | 0:20:31 | 0:20:34 | |
This metal's an alloy of seven parts of zinc to two of aluminium, | 0:20:34 | 0:20:37 | |
but it's not the composition that's important. | 0:20:37 | 0:20:40 | |
It's the crystalline structure inside the metal which, in some way, | 0:20:40 | 0:20:44 | |
makes it behave like bubblegum, which allows it to get thinner | 0:20:44 | 0:20:47 | |
and thinner, the metal spreading and extending evenly. | 0:20:47 | 0:20:50 | |
This behaviour is now totally unlike that of a metal, | 0:20:50 | 0:20:53 | |
even of a soft, hot metal. | 0:20:53 | 0:20:55 | |
What is it in the metal that causes it to behave like this? | 0:20:59 | 0:21:03 | |
Nobody really knows, though it must be something to do with the abnormally | 0:21:03 | 0:21:06 | |
small size of the crystal grains that are found in super-plastic metals. | 0:21:06 | 0:21:10 | |
They're 100 times smaller than those in ordinary metal. | 0:21:10 | 0:21:14 | |
They seem to move over each other as easily as grains of sand, | 0:21:14 | 0:21:18 | |
but if you can press a pulley wheel in metal | 0:21:18 | 0:21:20 | |
as easily as if it were made of plastic, you're onto a winner. | 0:21:20 | 0:21:24 | |
These unusual new materials sometimes turned out | 0:21:27 | 0:21:31 | |
to have unanticipated commercial benefits. | 0:21:31 | 0:21:35 | |
A material doesn't have to be brand new to be surprising. | 0:21:35 | 0:21:38 | |
Sometimes, it's just a matter of looking at | 0:21:38 | 0:21:41 | |
a familiar substance in a different way. | 0:21:41 | 0:21:43 | |
As simple a process as altering something's temperature | 0:21:43 | 0:21:46 | |
can radically change its properties, | 0:21:46 | 0:21:49 | |
and it was by cooling a metal that researchers made one of the biggest | 0:21:49 | 0:21:53 | |
discoveries in material science - the discovery of super conductivity. | 0:21:53 | 0:21:58 | |
This magnet's strength comes from | 0:22:05 | 0:22:07 | |
an electric current | 0:22:07 | 0:22:09 | |
that will run forever without any source of power. | 0:22:09 | 0:22:11 | |
The phenomenon - zero electrical resistance, super conductivity. | 0:22:20 | 0:22:25 | |
Super conductivity is beyond question the most significant | 0:22:28 | 0:22:32 | |
technological innovation since the invention of the wheel. | 0:22:32 | 0:22:36 | |
Now, that may sound facetious, but if you think of it, | 0:22:36 | 0:22:39 | |
I think the statement can be defended. | 0:22:39 | 0:22:42 | |
The wheel provided us with frictionless transport of matter, | 0:22:42 | 0:22:46 | |
and super conductivity provides us | 0:22:46 | 0:22:48 | |
with frictionless transport of electricity. | 0:22:48 | 0:22:51 | |
Super conductors proved to be extraordinary materials. | 0:23:05 | 0:23:08 | |
They behave normally at room temperature, | 0:23:11 | 0:23:13 | |
but when they're made very cold, | 0:23:13 | 0:23:16 | |
their properties change. | 0:23:16 | 0:23:19 | |
At temperatures lower than minus 140 degrees Celsius, | 0:23:22 | 0:23:26 | |
they emit a powerful magnetic force, | 0:23:26 | 0:23:29 | |
and they also conduct electricity almost perfectly. | 0:23:29 | 0:23:34 | |
Scientists were convinced that they were on the brink | 0:23:36 | 0:23:39 | |
of a great leap for progress. | 0:23:39 | 0:23:41 | |
I wanted to say I did something with my life, | 0:23:46 | 0:23:49 | |
and when this thing came, | 0:23:49 | 0:23:50 | |
for me, it was my chance | 0:23:50 | 0:23:52 | |
to really try and make an impact on things. | 0:23:52 | 0:23:54 | |
I had the feeling that we were very close to a breakthrough, | 0:23:56 | 0:23:59 | |
so I could enjoy my beer in the evening. | 0:23:59 | 0:24:03 | |
Scientists thought that super conducting transmission lines | 0:24:03 | 0:24:07 | |
could revolutionise our power supply. | 0:24:07 | 0:24:09 | |
Conventional cables lose around 10% of the electricity | 0:24:11 | 0:24:14 | |
they carry because of resistance, | 0:24:14 | 0:24:17 | |
the natural opposition a material poses to the passage of electrons. | 0:24:17 | 0:24:21 | |
Zero resistance in a super conducting wire | 0:24:22 | 0:24:25 | |
would mean no loss of energy. | 0:24:25 | 0:24:28 | |
Niobium titanium rods are packed into copper canisters, | 0:24:30 | 0:24:34 | |
and these are then drawn down to long thin rods, | 0:24:34 | 0:24:37 | |
rather like making Blackpool rock. | 0:24:37 | 0:24:39 | |
As well as transforming energy, super conducting engines | 0:24:42 | 0:24:46 | |
could power our battleships, and their strong magnetic fields | 0:24:46 | 0:24:50 | |
could give medical science new ways to look inside our bodies. | 0:24:50 | 0:24:54 | |
It's something like an X-ray, but far more effective, | 0:24:54 | 0:24:57 | |
and also much less damaging to the patient. | 0:24:57 | 0:25:00 | |
Some scientists even thought they could revolutionise | 0:25:01 | 0:25:05 | |
our transport systems by using superconductors to power a train. | 0:25:05 | 0:25:10 | |
At the Massachusetts Institute Of Technology, | 0:25:14 | 0:25:16 | |
they're developing something that could literally help superconductivity take off. | 0:25:16 | 0:25:20 | |
A train filled with liquid helium | 0:25:20 | 0:25:22 | |
that flies on superconducting magnets. | 0:25:22 | 0:25:25 | |
This is a 25th scale model, built to demonstrate electromagnetic flight. | 0:25:29 | 0:25:33 | |
This Magneplane vehicle contains | 0:25:33 | 0:25:35 | |
three saddle-shaped superconducting magnets | 0:25:35 | 0:25:38 | |
and another one is here. | 0:25:38 | 0:25:41 | |
And a third one... | 0:25:42 | 0:25:44 | |
As long as the test vehicle was kept cold enough, | 0:25:44 | 0:25:46 | |
it could sustain a magnetic field that would lift it | 0:25:46 | 0:25:50 | |
and hold it up off the track. | 0:25:50 | 0:25:52 | |
It's not enough to lift the vehicle, | 0:25:52 | 0:25:54 | |
we also need to propel it to move it along. | 0:25:54 | 0:25:57 | |
For this purpose, | 0:25:57 | 0:25:59 | |
we have wires across the centre of this guideway which form meanders... | 0:25:59 | 0:26:04 | |
These wires could create magnetic waves to push the vehicle along. | 0:26:04 | 0:26:10 | |
What looked like a fantasy in 1974 became a reality within ten years | 0:26:33 | 0:26:39 | |
when the first Maglev trains broke all the records. | 0:26:39 | 0:26:42 | |
Here, the superconducting magnets, cooled by liquid helium, | 0:26:45 | 0:26:48 | |
are in the experimental train. | 0:26:48 | 0:26:51 | |
As it gathers speed, they lift it off the track. | 0:26:51 | 0:26:55 | |
It's not the only Maglev train in the world, | 0:26:59 | 0:27:01 | |
but this Japanese superconducting prototype is certainly the fastest. | 0:27:01 | 0:27:05 | |
In fact, it's claimed a world record 321 mph. | 0:27:05 | 0:27:10 | |
Although superconductivity grabbed the world's attention, | 0:27:12 | 0:27:16 | |
it was received with a note of realism. | 0:27:16 | 0:27:19 | |
For the products of superconductivity to become real, | 0:27:19 | 0:27:22 | |
it must bridge the gap from the laboratory to the marketplace. | 0:27:22 | 0:27:26 | |
It must make the transition | 0:27:26 | 0:27:29 | |
from a scientific phenomenon to an everyday reality. | 0:27:29 | 0:27:32 | |
From a specialty item to a commodity. | 0:27:32 | 0:27:35 | |
Today, superconductors do have some specialist applications. | 0:27:38 | 0:27:43 | |
1,600 of them power the large Hadron Collider. | 0:27:43 | 0:27:47 | |
But the extremely low temperatures they need to function | 0:27:49 | 0:27:53 | |
means they've not yet bridged that gap to commodity status. | 0:27:53 | 0:27:58 | |
Greater insight into the internal structure of materials | 0:27:58 | 0:28:03 | |
enabled us to manipulate them as never before. | 0:28:03 | 0:28:05 | |
But the ultimate proof that scientists could understand them | 0:28:05 | 0:28:09 | |
right down at the atomic level would only come | 0:28:09 | 0:28:12 | |
if they could recreate that structure in the lab. | 0:28:12 | 0:28:15 | |
And what more desirable a material to recreate than diamond! | 0:28:15 | 0:28:18 | |
# The French are glad to die for love... # | 0:28:21 | 0:28:26 | |
The brilliance of a diamond is what makes it so highly prized. | 0:28:26 | 0:28:31 | |
But scientists love it because of its amazing properties. | 0:28:31 | 0:28:36 | |
As well as being the hardest known naturally occurring material, | 0:28:36 | 0:28:40 | |
it is the most transparent and least compressible. | 0:28:40 | 0:28:43 | |
# ..Jewels | 0:28:44 | 0:28:47 | |
# A kiss of the hand may be quite continental | 0:28:47 | 0:28:51 | |
# But diamonds are a girl's best friend... # | 0:28:51 | 0:28:56 | |
The idea of creating Earth's hardest substance in a laboratory seemed incredible. | 0:28:57 | 0:29:03 | |
But in 1955, scientists at General Electric in the USA did just that. | 0:29:03 | 0:29:10 | |
Using an ultra-high pressure and high temperature machine, | 0:29:12 | 0:29:16 | |
they transformed a mixture of metal and carbon into diamond. | 0:29:16 | 0:29:21 | |
The stones were perfect | 0:29:23 | 0:29:25 | |
for industrial applications like cutting and polishing. | 0:29:25 | 0:29:27 | |
But their small size and lack of sparkle | 0:29:29 | 0:29:32 | |
gave them little appeal to the gem business. | 0:29:32 | 0:29:35 | |
Over time, the process was refined, | 0:29:38 | 0:29:40 | |
yet one thing still set synthetic diamonds apart. | 0:29:40 | 0:29:45 | |
Their colour. | 0:29:46 | 0:29:48 | |
Any synthetic diamond you grow | 0:29:48 | 0:29:50 | |
will have a lot of nitrogen in the structure. | 0:29:50 | 0:29:52 | |
This nitrogen is incorporated | 0:29:52 | 0:29:54 | |
into single substitutional nitrogen atoms. | 0:29:54 | 0:29:57 | |
Isolated nitrogen atoms dotted around the diamond lattice. | 0:29:57 | 0:30:00 | |
The consequence of having nitrogen there is that it gives the diamond | 0:30:00 | 0:30:04 | |
a not very attractive brown colour. | 0:30:04 | 0:30:06 | |
In 2000, Horizon visited a Russian researcher | 0:30:09 | 0:30:12 | |
who claimed to have solved the mystery | 0:30:12 | 0:30:15 | |
of making perfectly clear synthetic diamonds. | 0:30:15 | 0:30:18 | |
To get colourless diamonds, | 0:30:19 | 0:30:22 | |
what we had to do was get rid of the nitrogen, | 0:30:22 | 0:30:25 | |
which gives them the yellow colour. | 0:30:25 | 0:30:27 | |
A clue for getting rid of the nitrogen | 0:30:34 | 0:30:37 | |
came from an American experiment 20 years before. | 0:30:37 | 0:30:41 | |
It suggested that the nitrogen atoms could be chemically attracted away | 0:30:41 | 0:30:45 | |
from a growing diamond by using a nitrogen 'getter'. | 0:30:45 | 0:30:48 | |
The nitrogen 'getter' Fiegelson chose was aluminium. | 0:30:52 | 0:30:56 | |
Fiegelson found that by putting aluminium in the growth cell, | 0:31:01 | 0:31:04 | |
it melted into the metal solvent | 0:31:04 | 0:31:07 | |
and the nitrogen atoms were irresistibly drawn towards it, | 0:31:07 | 0:31:11 | |
leaving the carbon atoms free to form as pure and colourless diamond. | 0:31:11 | 0:31:15 | |
When we got our first good diamonds, we were absolutely overwhelmed. | 0:31:20 | 0:31:26 | |
They have the same characteristics as real diamonds. | 0:31:31 | 0:31:35 | |
The same hardness, same conductivity, the same sparkle. | 0:31:35 | 0:31:39 | |
Although he can't make many, | 0:31:41 | 0:31:43 | |
his diamonds can now be both clear and colourless. | 0:31:43 | 0:31:46 | |
Within a short time, synthetic stones like these | 0:31:52 | 0:31:55 | |
posed a serious threat to the diamond industry. | 0:31:55 | 0:31:59 | |
One of the major players, De Beers, | 0:31:59 | 0:32:01 | |
was determined to find a way of protecting their valuable material. | 0:32:01 | 0:32:06 | |
So, at a discreet facility | 0:32:10 | 0:32:12 | |
on the outskirts of London, | 0:32:12 | 0:32:13 | |
De Beers created the Gem Defensive Program. | 0:32:13 | 0:32:17 | |
At vast cost, the new scientific division was set up | 0:32:21 | 0:32:25 | |
to develop techniques to distinguish between natural and synthetic diamonds. | 0:32:25 | 0:32:30 | |
Clearly, we knew that some day, synthetic gems | 0:32:30 | 0:32:33 | |
would be made available on the consumer market. | 0:32:33 | 0:32:36 | |
The crucial thing for us was to make sure that first, the industry, | 0:32:36 | 0:32:39 | |
but more importantly, the consumer, | 0:32:39 | 0:32:42 | |
had every means possible to ensure we could detect | 0:32:42 | 0:32:46 | |
the synthetic from the genuine article. | 0:32:46 | 0:32:50 | |
The problem they faced | 0:32:50 | 0:32:52 | |
was that synthetics were now very high quality. | 0:32:52 | 0:32:56 | |
It forced them to study down to the diamond's atomic structure | 0:32:56 | 0:32:59 | |
to detect even the tiniest differences. | 0:32:59 | 0:33:04 | |
De Beers developed a machine that used ultraviolet light | 0:33:04 | 0:33:07 | |
to reveal the difference between natural and synthetic diamonds. | 0:33:07 | 0:33:12 | |
Under ultraviolet light, | 0:33:12 | 0:33:15 | |
both natural and synthetic diamonds will glow to some degree. | 0:33:15 | 0:33:19 | |
This is called fluorescence. | 0:33:19 | 0:33:21 | |
But it is the patterns that are revealed by this glowing fluorescence | 0:33:21 | 0:33:25 | |
that can tell the two apart. | 0:33:25 | 0:33:28 | |
It's immediately obvious | 0:33:29 | 0:33:30 | |
from the strong blocky, blue fluorescence patterns | 0:33:30 | 0:33:34 | |
that this is a synthetic. | 0:33:34 | 0:33:37 | |
You wouldn't get these strong shapes of blue fluorescence from a natural. | 0:33:37 | 0:33:42 | |
Under the UV light, natural diamonds look very different, | 0:33:44 | 0:33:48 | |
producing a consistent, yet very faint blue glow. | 0:33:48 | 0:33:52 | |
De Beers are confident in the ability of their equipment | 0:33:54 | 0:33:58 | |
to detect these new colourless diamonds | 0:33:58 | 0:34:01 | |
and have sent their detection kit to gem labs around the world. | 0:34:01 | 0:34:05 | |
But the question is, | 0:34:06 | 0:34:08 | |
will that be enough to protect them in the long run? | 0:34:08 | 0:34:10 | |
As it turns out, | 0:34:13 | 0:34:15 | |
synthetic diamonds have never become as popular as the natural form. | 0:34:15 | 0:34:19 | |
Once material scientists found a way | 0:34:20 | 0:34:23 | |
of definitively identifying natural diamonds, | 0:34:23 | 0:34:25 | |
consumers opted for the genuine article, | 0:34:25 | 0:34:29 | |
proving that science can't always determine | 0:34:29 | 0:34:32 | |
whether a material will have value. | 0:34:32 | 0:34:35 | |
Diamond is a material made of pure carbon. | 0:34:42 | 0:34:46 | |
And surprisingly, it is not the only one. | 0:34:46 | 0:34:49 | |
Graphite, used in pencils, is also a pure carbon crystal. | 0:34:51 | 0:34:56 | |
Scientists believed that these were the only two naturally occurring forms, | 0:34:57 | 0:35:02 | |
until 1992, when they were stunned to find a third type. | 0:35:02 | 0:35:08 | |
And it was found by accident. | 0:35:08 | 0:35:11 | |
This story of discovery and revolution in chemistry | 0:35:15 | 0:35:19 | |
begins with astronomy. | 0:35:19 | 0:35:21 | |
The death of stars and the birth of planets. | 0:35:21 | 0:35:23 | |
Dying stars are pumping out carbon atoms into the interstellar medium. | 0:35:25 | 0:35:29 | |
The carbon in our body originated in space. | 0:35:29 | 0:35:32 | |
We now know that it was ejected from some star a long, long time ago | 0:35:32 | 0:35:36 | |
and was reprocessed and ended up on the Earth's biosphere. | 0:35:36 | 0:35:40 | |
What's absolutely fascinating and certainly something that excited me | 0:35:40 | 0:35:44 | |
when I first discovered it is that every one of us is made of carbon | 0:35:44 | 0:35:47 | |
and therefore, every one of us is made of stardust. | 0:35:47 | 0:35:50 | |
Ten years ago, Harry Kroto was studying stardust. | 0:35:50 | 0:35:55 | |
One thing we're not so sure about is, what is the form of that dust? | 0:35:55 | 0:35:58 | |
What's the structure? | 0:35:58 | 0:36:00 | |
How does the carbon nucleate to form these little wodges that go on to grow into planets? | 0:36:00 | 0:36:04 | |
Harry Kroto thought if he could create his own stardust here on Earth, | 0:36:07 | 0:36:12 | |
he might be able to learn more about its carbon structure | 0:36:12 | 0:36:15 | |
and even work out how planets formed. | 0:36:15 | 0:36:19 | |
He wanted to vaporise pieces of graphite | 0:36:25 | 0:36:27 | |
and then watch how the atoms came together. | 0:36:27 | 0:36:31 | |
So when he was granted access to a high-powered laser in Texas, | 0:36:32 | 0:36:36 | |
he jumped at the chance. | 0:36:36 | 0:36:38 | |
I was so excited, I pinched some money out of my wife's bank account, | 0:36:42 | 0:36:45 | |
got the cheapest ticket I could, and was there within three days. | 0:36:45 | 0:36:49 | |
I was keen on doing the experiment myself. | 0:36:52 | 0:36:55 | |
I was absolutely over the moon that I could do it. | 0:36:55 | 0:36:58 | |
What followed, none of them will forget. | 0:37:05 | 0:37:09 | |
Harry worked with the students, | 0:37:13 | 0:37:15 | |
doing run after run of graphite vaporised by laser. | 0:37:15 | 0:37:18 | |
It was practical, creative science at its best. | 0:37:23 | 0:37:26 | |
They saw evidence of Harry's long chains of carbon atoms captured fleetingly by the laser. | 0:37:34 | 0:37:38 | |
They also saw something else. | 0:37:38 | 0:37:42 | |
Harry Kroto and his team | 0:37:44 | 0:37:45 | |
repeatedly noticed clusters of 60 carbon atoms. | 0:37:45 | 0:37:49 | |
Again and again, 60 was the cluster that carbon preferred. | 0:37:53 | 0:37:57 | |
Why did carbon atoms form such a stable cluster? | 0:37:57 | 0:38:00 | |
What was special about the magic number 60? | 0:38:02 | 0:38:05 | |
The team tried to imagine what 60 carbon atoms would look like | 0:38:12 | 0:38:18 | |
if they were in a stable structure. | 0:38:18 | 0:38:20 | |
After trying every possible combination, | 0:38:20 | 0:38:23 | |
they settled on one shape that seemed to work. | 0:38:23 | 0:38:27 | |
It looked like they had discovered a new form of carbon. | 0:38:28 | 0:38:32 | |
One that was round. | 0:38:34 | 0:38:36 | |
The team turned to mathematicians for help. | 0:38:44 | 0:38:46 | |
We couldn't be the first people in the universe | 0:38:49 | 0:38:51 | |
to have discovered this structure. | 0:38:51 | 0:38:53 | |
They ought to know about the mathematics department. | 0:38:53 | 0:38:56 | |
So I called up Bill Beech and said, | 0:38:56 | 0:38:57 | |
"Sorry to bother you, | 0:38:57 | 0:38:59 | |
"but we have this hot new structure for a carbon molecule | 0:38:59 | 0:39:02 | |
"and it has 12 pentagons and 20 hexagons. | 0:39:02 | 0:39:05 | |
"I wonder if you could bother asking one of you students | 0:39:05 | 0:39:08 | |
"to find out what this polyhedral object is and give us a call back." | 0:39:08 | 0:39:12 | |
He did call back. | 0:39:12 | 0:39:14 | |
Bob Curl answered the phone and the mathematics chairman said, | 0:39:14 | 0:39:17 | |
"I could explain this to you in a number of ways, | 0:39:17 | 0:39:20 | |
"but what you've got there is a soccer ball." | 0:39:20 | 0:39:23 | |
You can imagine this excitement that you've discovered | 0:39:25 | 0:39:28 | |
a way of putting 60 carbon atoms together | 0:39:28 | 0:39:30 | |
and it turns out not only to be beautifully symmetric, but it's a soccer ball too! | 0:39:30 | 0:39:34 | |
Their paper to 'Nature' was a front cover story. | 0:39:42 | 0:39:45 | |
A really beautiful picture of C60. | 0:39:47 | 0:39:50 | |
It almost looks like you are looking at stars in the sky. | 0:39:50 | 0:39:53 | |
It was just such a fantastic moment. | 0:39:53 | 0:39:56 | |
But as I took the plane back, I was on such a high that I don't think... | 0:39:56 | 0:39:59 | |
I think the aeroplane would have flown without the engines running. | 0:39:59 | 0:40:03 | |
They named their structure Buckminster Fullerene. | 0:40:04 | 0:40:07 | |
Bucky Balls. | 0:40:07 | 0:40:09 | |
But Bucky Balls was still only a theory. | 0:40:13 | 0:40:18 | |
To prove C-60 existed as more than a blip on a graph, | 0:40:18 | 0:40:22 | |
they needed to synthesise it in the lab. | 0:40:22 | 0:40:24 | |
Rival research teams raced to be the first | 0:40:33 | 0:40:36 | |
to create this new form of carbon. | 0:40:36 | 0:40:38 | |
The most promising lead was a red solution of graphite soot. | 0:40:41 | 0:40:45 | |
But although the machines reported that C-60 was present, | 0:40:46 | 0:40:50 | |
nobody could see it. | 0:40:50 | 0:40:52 | |
Then, two physicists came up with a disarmingly simple answer. | 0:40:54 | 0:40:59 | |
The way it really happened was, Kratschmer called me from Germany | 0:41:02 | 0:41:06 | |
and said, "If you just take a little vial of the red material | 0:41:06 | 0:41:09 | |
"and you put a drop of it on a microscope slide, | 0:41:09 | 0:41:12 | |
"then you'll see an incredibly beautiful sight." | 0:41:12 | 0:41:15 | |
So I reproduced the experiment | 0:41:15 | 0:41:17 | |
by putting a tiny drop of the red liquid on the microscope slide. | 0:41:17 | 0:41:21 | |
And in just a very few seconds, as a matter of fact, | 0:41:24 | 0:41:28 | |
I was able to see these beautiful little crystals, | 0:41:28 | 0:41:31 | |
which were hexagonal platelets of brownish, orange colour. | 0:41:31 | 0:41:36 | |
'No longer fleeting atoms in a laser, | 0:41:36 | 0:41:40 | |
'not merely in red solution, now a new solid, pure carbon crystals.' | 0:41:40 | 0:41:45 | |
We realised by this time that we were surely seeing a crystalline form | 0:41:47 | 0:41:51 | |
of carbon 60, which was really a genuinely new form of carbon | 0:41:51 | 0:41:55 | |
and that we were probably the first people on Earth ever to even see this. | 0:41:55 | 0:42:00 | |
'This is the first ever film of a new carbon, Bucky Balls crystallising before your eyes.' | 0:42:00 | 0:42:07 | |
As a solid states physicist, it was incredibly nice to be able to say "Ah-ha! | 0:42:07 | 0:42:11 | |
"Now we've got something that we can really begin to experiment with. | 0:42:11 | 0:42:16 | |
"We can see it and work with it." And that was the moment of high excitement for me. | 0:42:16 | 0:42:20 | |
Don Huffman wasn't the only one who was excited. | 0:42:27 | 0:42:30 | |
C-60 was a promising new material. | 0:42:30 | 0:42:33 | |
It seemed everyone wanted to work with it. | 0:42:33 | 0:42:36 | |
Hello. My name is Don Cox. I am currently the project leader... | 0:42:39 | 0:42:44 | |
Hello. My name is Sergio Goran. I prepare and characterise southern containing fuellerene crystals... | 0:42:44 | 0:42:51 | |
I'm Mons Toman and I'm exploring the uses of fuellerenes... | 0:42:51 | 0:42:54 | |
I'm Ravio Parsni and I'm involved in synthesis and characterisation... | 0:42:54 | 0:42:58 | |
I'm Bill Shriver. I study the selectivity of fuellerene reactions... | 0:42:58 | 0:43:02 | |
I'm Lon Chen. We're working on the functionisation chemistry of C-60... | 0:43:02 | 0:43:07 | |
I'm Glen Miller and I'm studying the reactivity and structure of... | 0:43:07 | 0:43:11 | |
One of our interests is to see what it is you can do with C-60 | 0:43:11 | 0:43:16 | |
once you make it behave differently than it does as a pure material. | 0:43:16 | 0:43:22 | |
We'd love to be the company that finds a way of putting a fuellerene | 0:43:22 | 0:43:27 | |
into a can of oil that will improve the performance of engine oils. | 0:43:27 | 0:43:31 | |
Scientists proposed a wide range of uses for C-60. | 0:43:39 | 0:43:43 | |
From targeting medicines in the body to acting as electrical conductors in microcircuits. | 0:43:43 | 0:43:49 | |
But 25 years later, they're still looking for the ultimate money-spinning application. | 0:43:52 | 0:43:58 | |
In material science, what counts is not just coming up with | 0:44:01 | 0:44:05 | |
the right use, | 0:44:05 | 0:44:06 | |
but finding a cost-effective way of realising it too. | 0:44:06 | 0:44:10 | |
Since the discovery of Bucky Balls, other even more intriguing forms of carbon have been found. | 0:44:12 | 0:44:19 | |
The latest to excite both the scientific and business communities is graphine. | 0:44:19 | 0:44:24 | |
It has incredible properties. It's the thinnest material ever known, | 0:44:24 | 0:44:30 | |
it's more conductive than copper and stronger than diamond, | 0:44:30 | 0:44:34 | |
meaning it could have huge potential in the electronics and computer industries. | 0:44:34 | 0:44:40 | |
Graphine really could be the next big thing, but it's still too early to tell. | 0:44:43 | 0:44:48 | |
It may even go on to join a small number of materials that have come to represent entire eras, | 0:44:48 | 0:44:54 | |
like the Stone Age, the Bronze Age and the Iron Age. | 0:44:54 | 0:44:58 | |
When we look back, we could well regard the 20th century as the Silicon Age. | 0:44:58 | 0:45:04 | |
Silicon was first isolated nearly two centuries ago. | 0:45:11 | 0:45:16 | |
But its electronic properties were not exploited until the 1940s. | 0:45:16 | 0:45:20 | |
That's when scientists discovered a feature of silicon | 0:45:28 | 0:45:31 | |
that would ultimately lead to the electronics revolution. | 0:45:31 | 0:45:35 | |
By adding small amounts of other minerals, they were able | 0:45:37 | 0:45:41 | |
to transform silicon from an insulator into a semi-conductor. | 0:45:41 | 0:45:44 | |
This new material could be made to behave like a switch that could turn on and off. | 0:45:46 | 0:45:52 | |
Or even amplify an electric signal being passed through it. | 0:45:52 | 0:45:57 | |
A transistor. | 0:45:57 | 0:45:59 | |
Transistors were to become the building blocks of something | 0:46:02 | 0:46:06 | |
that would change our lives forever - computers. | 0:46:06 | 0:46:09 | |
PLAYS TUNE | 0:46:11 | 0:46:14 | |
If you listen to the experts, they say that because of this chip, | 0:46:14 | 0:46:17 | |
startling changes are going to be made in all our lives - the way we live, work and play. | 0:46:17 | 0:46:23 | |
But how dramatic a revolution is it going to be? | 0:46:23 | 0:46:25 | |
In the early 1970s, Horizon investigated the potential impact of computers on the workplace. | 0:46:30 | 0:46:38 | |
'A strip mill is like a 2,000ft-long pastry board, | 0:46:40 | 0:46:43 | |
'rolling the hot steel progressively thinner. | 0:46:43 | 0:46:46 | |
'Two computers run this show and they're already recruiting a third. | 0:46:46 | 0:46:50 | |
'The steel ends up as a coil one tenth of an inch thick. | 0:46:54 | 0:46:58 | |
'The last human decision is taken here. | 0:47:00 | 0:47:03 | |
'A bell rings every 80 seconds and the man has to decide whether to press a button or not. | 0:47:03 | 0:47:09 | |
'If he does, the next slab comes out of the furnace and is sent off down the line. | 0:47:09 | 0:47:13 | |
'From then on, unless something goes wrong, the men in the other | 0:47:13 | 0:47:18 | |
'control pulpits perched high above the steel just sit back and watch. | 0:47:18 | 0:47:23 | |
'How does a man feel about coming to work, only as a back-up to the computer? | 0:47:23 | 0:47:28 | |
'One problem is isolation. | 0:47:28 | 0:47:30 | |
'An intercom is a poor substitute for a chat with your mates. | 0:47:30 | 0:47:34 | |
'And a fish tank is cold company for a sociable man.' | 0:47:34 | 0:47:37 | |
But while it was initially viewed with suspicion, | 0:47:40 | 0:47:43 | |
the silicon revolution gathered pace. | 0:47:43 | 0:47:46 | |
To perform more complicated tasks, | 0:47:48 | 0:47:50 | |
groups of transistors were placed together on a wafer of pure silicon. | 0:47:50 | 0:47:55 | |
This became known as the silicon chip. | 0:47:55 | 0:47:57 | |
A device that promised a brave new world. | 0:48:02 | 0:48:05 | |
'You're going to see something absolutely amazing, | 0:48:08 | 0:48:11 | |
'a machine reading to a blind man. | 0:48:11 | 0:48:13 | |
'A computer will read an ordinary book. | 0:48:20 | 0:48:24 | |
'It will speak it aloud in its own artificial voice. | 0:48:24 | 0:48:27 | |
'The first words of the book are, "Why suddenly do so many feel | 0:48:35 | 0:48:40 | |
'"so strongly about Jimmy Carter, pro and con?"' | 0:48:40 | 0:48:44 | |
-COMPUTER-GENERATED VOICE: -Why suddenly do so many feel | 0:48:45 | 0:48:48 | |
so strongly about Jimmy Carter, pro and con? | 0:48:48 | 0:48:52 | |
This book attempts to unravel the mysteries of Carter's extraordinary success story, | 0:48:52 | 0:48:59 | |
as remembered from Jimmy, | 0:48:59 | 0:49:02 | |
the nominee of the one-nine-seven-six | 0:49:02 | 0:49:05 | |
Democratic National Convention, as well as to provide "gui-de" lines... | 0:49:05 | 0:49:10 | |
G-U-I-D-E-L-I-N-E-S, "gui-de" lines... | 0:49:12 | 0:49:18 | |
for understanding and evaluating the event... | 0:49:18 | 0:49:22 | |
'A man will talk and a computer obey.' | 0:49:23 | 0:49:27 | |
Turn right, stop. | 0:49:27 | 0:49:30 | |
Turn right, stop. | 0:49:30 | 0:49:31 | |
'A man's voice being understood by a machine.' | 0:49:33 | 0:49:37 | |
Stop. Forward. | 0:49:37 | 0:49:39 | |
Run. | 0:49:39 | 0:49:40 | |
Turn left. | 0:49:44 | 0:49:46 | |
'At the heart of both these machines are tiny powerful computers | 0:49:48 | 0:49:52 | |
'built around the new technology of silicon chips. | 0:49:52 | 0:49:56 | |
'This is the size of a computer today. | 0:49:58 | 0:50:01 | |
'As powerful as the biggest of only a few years ago, | 0:50:01 | 0:50:04 | |
'but 1,000 times cheaper. | 0:50:04 | 0:50:06 | |
'What makes it possible is this. | 0:50:06 | 0:50:09 | |
'Inside here is a silicon chip, with all the important components | 0:50:09 | 0:50:15 | |
'of the computer etched onto its tiny surface. | 0:50:15 | 0:50:19 | |
'It's called a micro-processor. | 0:50:21 | 0:50:23 | |
'Under an electron microscope, magnified and slowed down, it's possible to see it at work. | 0:50:25 | 0:50:30 | |
'Electric pulses being directed by switches. | 0:50:32 | 0:50:35 | |
'By sending the pulses along different channels, | 0:50:35 | 0:50:38 | |
'a chip can be made to do anything from arithmetic to reading a book. | 0:50:38 | 0:50:41 | |
'Such chips will totally revolutionise our way of life. | 0:50:44 | 0:50:48 | |
'They're the reason why Japan is abandoning its ship building | 0:50:48 | 0:50:51 | |
'and why our children will grow up without jobs to go to.' | 0:50:51 | 0:50:55 | |
The extent of the revolution became apparent, | 0:50:57 | 0:51:00 | |
as computers were increasingly integrated into our daily lives. | 0:51:00 | 0:51:04 | |
'There's a new machine coming into use. | 0:51:04 | 0:51:07 | |
'It's called a word processor and it's probably a more important step | 0:51:07 | 0:51:11 | |
'than the invention of the typewriter. | 0:51:11 | 0:51:14 | |
'It uses no paper, the text can be moved around, | 0:51:17 | 0:51:21 | |
'edited and instantly corrected. | 0:51:21 | 0:51:24 | |
'The machine works out line lengths, where to begin a new page, | 0:51:24 | 0:51:27 | |
'and even corrects simple spelling mistakes. | 0:51:27 | 0:51:30 | |
'The text is stored in memory chips, controlled by two micro-processors. | 0:51:33 | 0:51:37 | |
'They rearrange the text by shunting it from one memory block to another.' | 0:51:37 | 0:51:42 | |
But whilst we cautious Brits were still working out what we thought | 0:51:44 | 0:51:48 | |
about the silicon revolution, other nations were quick to embrace it. | 0:51:48 | 0:51:52 | |
'These children are programming their own Space Invaders. | 0:51:52 | 0:51:57 | |
'This little boy can be no more than eight years old. | 0:52:00 | 0:52:03 | |
'In the market place at Akihabara in Tokyo, | 0:52:03 | 0:52:07 | |
'micro-electronics has gone do-it-yourself. | 0:52:07 | 0:52:10 | |
'This shop goes further still. It's the cheapest place in town to buy integrated circuits, chips. | 0:52:13 | 0:52:19 | |
'On a Saturday afternoon, | 0:52:19 | 0:52:21 | |
'they queue up to buy the latest memory chips for a handful of yen. | 0:52:21 | 0:52:24 | |
'The Silicon Age has gone DIY too. | 0:52:24 | 0:52:27 | |
'Its very immediacy gives you an indication of just how far | 0:52:27 | 0:52:30 | |
'micro-electronics has sunk into Japanese culture. | 0:52:30 | 0:52:34 | |
'A whole generation is growing up in Japan as familiar | 0:52:34 | 0:52:37 | |
'with building home computers as our children are at building Lego.' | 0:52:37 | 0:52:41 | |
This willingness to adopt new technology meant Japan | 0:52:44 | 0:52:48 | |
was at the forefront of the silicon goldrush. | 0:52:48 | 0:52:51 | |
Japanese business raced neck and neck with the US to develop the world's fastest silicon chips. | 0:52:53 | 0:53:00 | |
'Dominating big computers means toppling the world leader, America's IBM. | 0:53:00 | 0:53:05 | |
'And in Kawasaki City, Fujitsu are preparing to do just that. | 0:53:05 | 0:53:09 | |
'Sat in the corner, looking as exciting as a row of filing cabinets, is the machine | 0:53:09 | 0:53:14 | |
'they hope to do it with, their latest number cruncher - the M380. | 0:53:14 | 0:53:17 | |
'But for the M380, Fujitsu has moved ahead. | 0:53:24 | 0:53:28 | |
'These are the latest chips, the much more powerful 64,000 bit, | 0:53:28 | 0:53:32 | |
'known in the trade as the 64K.' | 0:53:32 | 0:53:35 | |
64K sounds tiny today, when we have megabytes and terabytes. | 0:53:35 | 0:53:41 | |
But in 1984, it was extraordinarily powerful. | 0:53:41 | 0:53:45 | |
In 20 years, silicon had gone from a material in which scientists | 0:53:47 | 0:53:51 | |
had observed interesting behaviour to one that had given us digital watches, personal computers | 0:53:51 | 0:53:57 | |
and all manner of technological advances. | 0:53:57 | 0:54:00 | |
It was our deep understanding of silicon's potential that kick-started | 0:54:00 | 0:54:04 | |
a vast electronics revolution. | 0:54:04 | 0:54:07 | |
Ah! | 0:54:10 | 0:54:12 | |
As I move it around the table top, | 0:54:12 | 0:54:16 | |
a little cursor, or arrow, on the screen moves in a relative position. | 0:54:16 | 0:54:21 | |
An operator can change the photographic record, | 0:54:21 | 0:54:24 | |
using a device similar to an electronic paintbrush. | 0:54:24 | 0:54:28 | |
This is a highly intelligent car. | 0:54:28 | 0:54:30 | |
'Go left onto the A3095.' | 0:54:31 | 0:54:34 | |
Ever smaller transistors that worked faster | 0:54:43 | 0:54:47 | |
and were cheaper to make cemented silicon's success. | 0:54:47 | 0:54:50 | |
A few years ago, | 0:54:53 | 0:54:54 | |
the computers operating this little model | 0:54:54 | 0:54:57 | |
would have been so big, | 0:54:57 | 0:54:59 | |
you could hardly have got them inside a double-decker bus. | 0:54:59 | 0:55:02 | |
By 1989, a million transistors fitted on a single chip. | 0:55:06 | 0:55:11 | |
In 2005, it was a billion. | 0:55:11 | 0:55:14 | |
'When you're dealing with figures like this, it isn't an evolution any more, it's a revolution.' | 0:55:16 | 0:55:22 | |
But there is a physical limit to how small silicon transistors can be made. | 0:55:28 | 0:55:33 | |
And that means we must find a replacement material | 0:55:38 | 0:55:42 | |
if we want even smaller, faster and cheaper computing at our fingertips. | 0:55:42 | 0:55:47 | |
At the cutting edge of semi-conductor science | 0:56:09 | 0:56:12 | |
is organic electronics, where transistors are made of carbon-based materials 100 times smaller | 0:56:12 | 0:56:19 | |
than the tiniest silicon switches. | 0:56:19 | 0:56:21 | |
Experts predict that silicon's dominance may finally be over within the next ten years. | 0:56:32 | 0:56:37 | |
Scientists have gone to the ends of the Earth | 0:56:53 | 0:56:58 | |
and even beyond in their bid to find and develop the materials that have dramatically changed our world, | 0:56:58 | 0:57:05 | |
and the way we all live in it. | 0:57:05 | 0:57:07 | |
They've explored ocean depths, invented groundbreaking new techniques, and come to understand | 0:57:10 | 0:57:17 | |
materials at a subatomic level. | 0:57:17 | 0:57:20 | |
And all the while, | 0:57:23 | 0:57:26 | |
big business has been watching for the next major breakthrough. | 0:57:26 | 0:57:30 | |
The potential a material has to change every aspect of our lives means that science and industry | 0:57:33 | 0:57:40 | |
will never give up in their pursuit of the next big thing. | 0:57:40 | 0:57:43 | |
With the right application, a material can truly propel us | 0:57:43 | 0:57:47 | |
out of one age and into the next. | 0:57:47 | 0:57:49 | |
And it's likely that understanding them at the most fundamental level possible will be crucial | 0:57:49 | 0:57:56 | |
to finding new ways of exploiting them. | 0:57:56 | 0:57:58 | |
But beyond that, who knows where the next big breakthrough is going to take us! | 0:57:58 | 0:58:03 | |
# Cos we are living in a material world | 0:58:09 | 0:58:14 | |
# And I am a material girl | 0:58:14 | 0:58:17 | |
# You know that we are living in a material world | 0:58:17 | 0:58:21 | |
# And I am a material girl | 0:58:21 | 0:58:24 | |
# (Living in a material) Material! # | 0:58:24 | 0:58:27 | |
Subtitles by Red Bee Media Ltd | 0:58:29 | 0:58:33 |