Stuff: A Horizon Guide to Materials


Stuff: A Horizon Guide to Materials

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The buildings we live in,

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the roads we drive on...

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..the phones we speak into,

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the screens we watch at night.

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Our world is made up of materials.

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They are the framework, the stuff of modern life.

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Discovering and exploiting the materials that make up our planet

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has been one of the most enduring quests of science

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and helped us build the modern world.

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Learning how to manipulate these materials

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can be the making of both scientific reputations and potential fortunes.

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For over 40 years, Horizon and the BBC has followed

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science's bid to reveal and conquer the material world.

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Charting the discovery of new materials...

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We can see it and work with it,

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and that was really the moment of high excitement for me.

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..and proposing radical new uses for old favourites.

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Super connectivity is beyond question

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the most significant technological innovation

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since the invention of the wheel.

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Each new discovery offers a tantalising glimpse

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of the Holy Grail of material science -

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finding a material that's cheap to manufacture

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which has the potential to change our world.

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ROBOTIC VOICE: Go left onto the A3095.

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And a series of extraordinary breakthroughs have done just that.

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From superconductors to the silicon revolution,

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materials have changed everything.

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In 1990, an extraordinary new material hit the headlines.

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This laser burns through half an inch of steel in a fraction of a second.

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Few substances can survive such blasts of energy.

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If the claims of this former hairdresser are true,

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he holds the secret to a formulation that appears to defy science.

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He calls his invention Starlite.

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Maurice Ward was an amateur scientist,

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yet he claimed to have invented an astonishing new plastic.

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This torch here is producing a temperature of 1,200 degrees Celsius.

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Try cooking an ordinary egg like that

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and in a very few seconds, the results would be quite an explosion.

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I'm going to leave this torch here blowing on this egg

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for a couple of minutes before we crack it open

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and it ought to survive the inferno,

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because it's coated with a remarkable new plastic...

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Its heat-resistant properties

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apparently outstripped any known material.

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-So how is it doing?

-It hasn't broken up at all.

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And you can see on the front, it's glowing red hot. Watch this.

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If I turn the flame off,

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and remember it was producing 1,200 degrees Celsius,

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and I take the charred bit and I put it flat in the palm of my hand,

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it only just feels warm.

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And if I then crack it open, what's more...

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..the egg hasn't even begun to start cooking.

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The scientific community was intrigued.

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We have heard so much about you.

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We have seen films of you torching the egg.

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In tests at the British Atomic Weapons Establishment,

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Starlite even withstood blasts of over 900 kilotonnes,

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more than 75 times the strength of the Hiroshima bomb.

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So much power is being reflected off the surface of the Starlite,

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it has actually blown up the thermal fuse

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and switched the interlock system of the laser down.

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It looked like Ward's new material had huge commercial potential...

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..and he was determined to protect his incredible find.

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No. We don't supply you the formulation.

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Yes. Yeah. If we give the world the formulation, that's exit us.

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Despite huge interest from big business and even NASA,

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Ward refused to let any samples of Starlite out of his sight

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or reveal any information about it.

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All we are saying really is that I'm protecting my material,

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and you ain't going to pinch it.

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In 2011, he died, having neither made his fortune

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nor diverged the formula of his plastic to anyone outside his family.

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In many ways, Starlite epitomises the cutthroat world of materials.

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A world where scientists search relentlessly

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for ways of exploiting a new substance and big business watches,

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waiting for signs of a breakthrough,

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but if that breakthrough doesn't happen,

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the spotlight sweeps on and one man's career-defining breakthrough

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becomes yesterday's news.

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Discovering new materials can be costly.

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Even a man-made substance like plastic is derived from the earth's natural resources

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and that means the expense of drilling for oil

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or mining underground.

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The lure for business is in finding the killer application.

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One that can turn a material from an intriguing oddity

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to a hot commodity almost overnight.

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And sometimes, that happens with materials

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we've known about for years.

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This film is the story of a metal.

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A metal which, for 150 years,

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since its discovery at the end of the 18th century, was virtually unused.

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Now, this metal is being dug and blasted from the earth

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at such a rapidly increasing rate

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that all known reserves could well be exhausted before the year 2000.

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This is the story of uranium.

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For decades, uranium had little value,

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but the discovery that it was radioactive

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was the key to unlocking its ultimate use...

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..nuclear power.

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Uranium doesn't have much of a past and it may well

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not have much of a future,

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but its present is to be the most sought-after

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and most politicised commodity of the last decades of the 20th century.

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For the last 25 years,

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uranium has been the fuel of the world's nuclear reactors.

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The fuel which is now expected to satisfy

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a growing proportion of our energy needs.

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And this is what all that effort is about.

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And unremarkable bronze grey metal which for 40 years now,

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we've known to have properties that make it unique.

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During the 1970s, it was thought that nuclear power

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would eventually supply more than half the world's electricity.

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And the assumption that uranium reserves were limited

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only added to its value.

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A stampede of prospectors headed for the planet's

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most remote locations in search of fresh uranium fields.

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The uranium Klondike of the 1980s is in northern Saskatchewan, Canada.

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The uranium that was known to occur around Uranium City

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it's now suggested may extend over the whole of a geological feature

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called the Athabasca basin.

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This is the sort of country where you may stumble upon a boulder

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made up of 50% uranium.

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Do you want to come over and take a look at this?

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I think we've got ourselves a bonus boulder.

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It puts this enormous deposit in perspective and is a measure of the uranium problem

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to realise that in the 1990s,

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we'll have to find and mine a new Athabasca Basin every two years.

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But more than 30 years later, new deposits are still being discovered

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and uranium prices have fallen in real terms.

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The idea that there's money to be made has often fuelled

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a boom or bust gold rush for new finds,

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but such obsessions are nothing new.

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200-odd years ago, aluminium was actually rarer than uranium

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and the Emperor Napoleon had an aluminium dinner set made.

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So valuable was it, he was the only one allowed to use it

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and his guests were forced to make do with plates of silver and gold.

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Nowadays, most of us occasionally have an aluminium dinner set

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and when we've finished with it, we throw it away.

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Each time an idea for a potentially valuable material appears,

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both science and industry get excited.

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In 1978, it was the turn of something called manganese nodules.

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Take a fair-sized ship

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almost anywhere in the north-east Pacific Ocean.

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Drop overboard a television camera

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on the end of five kilometres of cable and you will see,

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as these German technicians are seeing, mile upon mile

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of small, round black things

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scattered across the deep ocean floor.

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They are manganese nodules, and they are infinitely more interesting

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than they look at first sight.

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What you are looking at is one small corner of a magic carpet

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whose cash value has been estimated at ten million million dollars.

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Manganese nodules are fascinating to scientists,

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who cannot completely explain what they are and where they come from.

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Manganese nodules are tempting to industrialists,

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who need the valuable copper and nickel in them.

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The past and the future of these humble blackish stones, then,

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is of absolutely vital interest to the world.

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The lure of rich profits prompted industrialists to pour money

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into identifying the best nodule fields.

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This computer can actually draw a contour map of the metal percentage

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of a field of nodules,

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but the information is destined to help the next boardroom decision.

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Oceanographers may never see it.

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But harvesting the nodules was just the first step.

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Scientists still had to work out a way to extract the valuable minerals

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once they'd brought them up from the sea bed.

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RINGING

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As much as success at sea,

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profitability depends on the tricky chemistry of turning dull, grey grit

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into shining and valuable metal.

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The basis of the process is to leach out the metals with ammonia,

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but with an extremely clever pre-treatment process.

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The capital cost of a full-size plant is thought to be 340 million dollars,

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another 220 million capital for the ocean mining system.

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Annual income - 250 million dollars from sale of the copper, nickel and cobalt.

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Assuming 48% tax, total profits from a 25-year project

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have been estimated as one-and-a-half thousand million dollars.

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Millions were ploughed into developing the industrial process

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needed to exploit the manganese nodules.

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But the huge investment bore little fruit.

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Within a few years, a cheaper source of nickel

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had been discovered on land, and the nodules lost their allure.

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In their continuing pursuit of profitable materials,

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scientists began to look even further afield.

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CONTROL TOWER: Go for landing.

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Eagle, Houston here. Go for landing. Over.

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The six Apollo missions had brought back several hundred kilograms

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of moon rock for scientific analysis.

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Tests revealed that the rock contained a fuel

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that could be used in fusion energy,

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thought to be the future of electricity production here on Earth

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and a resource potentially worth billions of dollars a tonne.

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The twelfth and final man to walk on the surface of the moon

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became obsessed with an extraordinary idea - mining it.

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Harrison Schmidt was the only research scientist

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among the 12 Apollo astronauts.

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-This boulder is typical of the granitic rocks that form the core...

-He's a trained geologist.

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Probably an intrusive rock,

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although it's sometimes very difficult to tell.

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'See if I can't grab the corner and get that contact.

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'It's obviously very, very cohesive,

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'and fragmental-like.'

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Schmidt came back from the moon and analysed samples he'd collected.

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He found they contained significant quantities of helium 3.

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We have significant information about the distribution of helium 3.

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We of course sampled the soils

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at Tranquillity Base, where Neil Armstrong landed.

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We have indications of high titanium,

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which is a surrogate for helium 3,

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and then also, the polar regions

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have high concentrations there,

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so we have a pretty good basic understanding of where it is.

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Helium 3 is a gas ejected from the surface of the sun...

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..and blown through space by solar winds.

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When it reaches the Earth, it's blocked by the atmosphere.

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But on the moon, where there's nothing to block it,

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the gas is trapped by the lunar soil.

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Slowly, over billions of years, huge deposits have built up.

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At first blush, using the most conservative figures

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for the amount of helium 3 that's in the soils of the moon,

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what we call the regolith of the moon,

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there's about a million tonnes.

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That's a lot of helium!

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It would be enough to power the Earth for hundreds of years.

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It's only within the last few decades that we've ever

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thought about the moon as being a large source of energy.

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In fact, it may be the Persian Gulf of the 21st century.

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It seems preposterous, but Schmidt and Kulcinski

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have set up a company with the extraordinary idea

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of strip mining the moon and transporting helium 3

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as a liquefied gas a quarter of a million miles back to Earth.

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It's not a madman's dream to go to the moon and access these resources.

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We've been there, we know how to do it, we can estimate the cost.

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That's not a madman's dream.

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While it may be technically possible,

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the economics of mining the moon remain prohibitive.

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For now, Harrison Schmidt's dream remains in the realms of fantasy.

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Back on Earth, scientists have been constant in their quest

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not just to exploit the raw materials around us,

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but to understand them as well, and if the key to progress

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lies in manipulating materials, then we must know what gives them

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their distinctive properties,

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like clay - squishy, malleable.

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Iron - hard as.

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Through intriguing experiments and testing things to destruction,

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scientists gradually learned more about the nature of materials.

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It's a compact, almost claustrophobic world

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and the men working in it are, perhaps have to be,

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total enthusiasts.

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But to understand them fully,

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they needed to find a way of peering inside.

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In the 1970s, a new generation of technology changed

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materials research by allowing scientists to scrutinise them in far greater detail.

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They're helped by pictures produced by this machine.

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It's a scanning electron microscope

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and it can be used to study

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the internal structure of, for example, this specimen,

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something which, to the naked eye,

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looks like a tiny fragment of unfired pottery.

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The sample is enclosed in the inspection chamber,

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which is sealed so that it can be pumped down to a vacuum.

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The fragment will then be scanned by an electron beam

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to produce an image of the exposed surface, which is projected like a television picture.

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New imaging technology vastly improved our understanding of materials.

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Deeper insight enabled scientists to manipulate substances

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and push them to new capabilities,

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such as creating a metal that behaved like a plastic,

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a super-plastic metal.

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Here, a foot-square panel of metal is being heated

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and it'll be blown up by air pressure.

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Pressure is now coming on.

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An ordinary soft metal would already be thinning, ready to burst.

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Vacuum on.

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Stage two, it's now being sucked down into the box

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and still without any sign of bursting.

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This metal's an alloy of seven parts of zinc to two of aluminium,

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but it's not the composition that's important.

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It's the crystalline structure inside the metal which, in some way,

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makes it behave like bubblegum, which allows it to get thinner

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and thinner, the metal spreading and extending evenly.

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This behaviour is now totally unlike that of a metal,

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even of a soft, hot metal.

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What is it in the metal that causes it to behave like this?

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Nobody really knows, though it must be something to do with the abnormally

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small size of the crystal grains that are found in super-plastic metals.

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They're 100 times smaller than those in ordinary metal.

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They seem to move over each other as easily as grains of sand,

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but if you can press a pulley wheel in metal

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as easily as if it were made of plastic, you're onto a winner.

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These unusual new materials sometimes turned out

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to have unanticipated commercial benefits.

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A material doesn't have to be brand new to be surprising.

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Sometimes, it's just a matter of looking at

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a familiar substance in a different way.

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As simple a process as altering something's temperature

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can radically change its properties,

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and it was by cooling a metal that researchers made one of the biggest

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discoveries in material science - the discovery of super conductivity.

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This magnet's strength comes from

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an electric current

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that will run forever without any source of power.

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The phenomenon - zero electrical resistance, super conductivity.

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Super conductivity is beyond question the most significant

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technological innovation since the invention of the wheel.

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Now, that may sound facetious, but if you think of it,

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I think the statement can be defended.

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The wheel provided us with frictionless transport of matter,

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and super conductivity provides us

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with frictionless transport of electricity.

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Super conductors proved to be extraordinary materials.

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They behave normally at room temperature,

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but when they're made very cold,

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their properties change.

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At temperatures lower than minus 140 degrees Celsius,

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they emit a powerful magnetic force,

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and they also conduct electricity almost perfectly.

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Scientists were convinced that they were on the brink

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of a great leap for progress.

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I wanted to say I did something with my life,

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and when this thing came,

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for me, it was my chance

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to really try and make an impact on things.

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I had the feeling that we were very close to a breakthrough,

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so I could enjoy my beer in the evening.

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Scientists thought that super conducting transmission lines

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could revolutionise our power supply.

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Conventional cables lose around 10% of the electricity

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they carry because of resistance,

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the natural opposition a material poses to the passage of electrons.

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Zero resistance in a super conducting wire

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would mean no loss of energy.

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Niobium titanium rods are packed into copper canisters,

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and these are then drawn down to long thin rods,

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rather like making Blackpool rock.

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As well as transforming energy, super conducting engines

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could power our battleships, and their strong magnetic fields

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could give medical science new ways to look inside our bodies.

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It's something like an X-ray, but far more effective,

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and also much less damaging to the patient.

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Some scientists even thought they could revolutionise

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our transport systems by using superconductors to power a train.

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At the Massachusetts Institute Of Technology,

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they're developing something that could literally help superconductivity take off.

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A train filled with liquid helium

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that flies on superconducting magnets.

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This is a 25th scale model, built to demonstrate electromagnetic flight.

0:25:290:25:33

This Magneplane vehicle contains

0:25:330:25:35

three saddle-shaped superconducting magnets

0:25:350:25:38

and another one is here.

0:25:380:25:41

And a third one...

0:25:420:25:44

As long as the test vehicle was kept cold enough,

0:25:440:25:46

it could sustain a magnetic field that would lift it

0:25:460:25:50

and hold it up off the track.

0:25:500:25:52

It's not enough to lift the vehicle,

0:25:520:25:54

we also need to propel it to move it along.

0:25:540:25:57

For this purpose,

0:25:570:25:59

we have wires across the centre of this guideway which form meanders...

0:25:590:26:04

These wires could create magnetic waves to push the vehicle along.

0:26:040:26:10

What looked like a fantasy in 1974 became a reality within ten years

0:26:330:26:39

when the first Maglev trains broke all the records.

0:26:390:26:42

Here, the superconducting magnets, cooled by liquid helium,

0:26:450:26:48

are in the experimental train.

0:26:480:26:51

As it gathers speed, they lift it off the track.

0:26:510:26:55

It's not the only Maglev train in the world,

0:26:590:27:01

but this Japanese superconducting prototype is certainly the fastest.

0:27:010:27:05

In fact, it's claimed a world record 321 mph.

0:27:050:27:10

Although superconductivity grabbed the world's attention,

0:27:120:27:16

it was received with a note of realism.

0:27:160:27:19

For the products of superconductivity to become real,

0:27:190:27:22

it must bridge the gap from the laboratory to the marketplace.

0:27:220:27:26

It must make the transition

0:27:260:27:29

from a scientific phenomenon to an everyday reality.

0:27:290:27:32

From a specialty item to a commodity.

0:27:320:27:35

Today, superconductors do have some specialist applications.

0:27:380:27:43

1,600 of them power the large Hadron Collider.

0:27:430:27:47

But the extremely low temperatures they need to function

0:27:490:27:53

means they've not yet bridged that gap to commodity status.

0:27:530:27:58

Greater insight into the internal structure of materials

0:27:580:28:03

enabled us to manipulate them as never before.

0:28:030:28:05

But the ultimate proof that scientists could understand them

0:28:050:28:09

right down at the atomic level would only come

0:28:090:28:12

if they could recreate that structure in the lab.

0:28:120:28:15

And what more desirable a material to recreate than diamond!

0:28:150:28:18

# The French are glad to die for love... #

0:28:210:28:26

The brilliance of a diamond is what makes it so highly prized.

0:28:260:28:31

But scientists love it because of its amazing properties.

0:28:310:28:36

As well as being the hardest known naturally occurring material,

0:28:360:28:40

it is the most transparent and least compressible.

0:28:400:28:43

# ..Jewels

0:28:440:28:47

# A kiss of the hand may be quite continental

0:28:470:28:51

# But diamonds are a girl's best friend... #

0:28:510:28:56

The idea of creating Earth's hardest substance in a laboratory seemed incredible.

0:28:570:29:03

But in 1955, scientists at General Electric in the USA did just that.

0:29:030:29:10

Using an ultra-high pressure and high temperature machine,

0:29:120:29:16

they transformed a mixture of metal and carbon into diamond.

0:29:160:29:21

The stones were perfect

0:29:230:29:25

for industrial applications like cutting and polishing.

0:29:250:29:27

But their small size and lack of sparkle

0:29:290:29:32

gave them little appeal to the gem business.

0:29:320:29:35

Over time, the process was refined,

0:29:380:29:40

yet one thing still set synthetic diamonds apart.

0:29:400:29:45

Their colour.

0:29:460:29:48

Any synthetic diamond you grow

0:29:480:29:50

will have a lot of nitrogen in the structure.

0:29:500:29:52

This nitrogen is incorporated

0:29:520:29:54

into single substitutional nitrogen atoms.

0:29:540:29:57

Isolated nitrogen atoms dotted around the diamond lattice.

0:29:570:30:00

The consequence of having nitrogen there is that it gives the diamond

0:30:000:30:04

a not very attractive brown colour.

0:30:040:30:06

In 2000, Horizon visited a Russian researcher

0:30:090:30:12

who claimed to have solved the mystery

0:30:120:30:15

of making perfectly clear synthetic diamonds.

0:30:150:30:18

To get colourless diamonds,

0:30:190:30:22

what we had to do was get rid of the nitrogen,

0:30:220:30:25

which gives them the yellow colour.

0:30:250:30:27

A clue for getting rid of the nitrogen

0:30:340:30:37

came from an American experiment 20 years before.

0:30:370:30:41

It suggested that the nitrogen atoms could be chemically attracted away

0:30:410:30:45

from a growing diamond by using a nitrogen 'getter'.

0:30:450:30:48

The nitrogen 'getter' Fiegelson chose was aluminium.

0:30:520:30:56

Fiegelson found that by putting aluminium in the growth cell,

0:31:010:31:04

it melted into the metal solvent

0:31:040:31:07

and the nitrogen atoms were irresistibly drawn towards it,

0:31:070:31:11

leaving the carbon atoms free to form as pure and colourless diamond.

0:31:110:31:15

When we got our first good diamonds, we were absolutely overwhelmed.

0:31:200:31:26

They have the same characteristics as real diamonds.

0:31:310:31:35

The same hardness, same conductivity, the same sparkle.

0:31:350:31:39

Although he can't make many,

0:31:410:31:43

his diamonds can now be both clear and colourless.

0:31:430:31:46

Within a short time, synthetic stones like these

0:31:520:31:55

posed a serious threat to the diamond industry.

0:31:550:31:59

One of the major players, De Beers,

0:31:590:32:01

was determined to find a way of protecting their valuable material.

0:32:010:32:06

So, at a discreet facility

0:32:100:32:12

on the outskirts of London,

0:32:120:32:13

De Beers created the Gem Defensive Program.

0:32:130:32:17

At vast cost, the new scientific division was set up

0:32:210:32:25

to develop techniques to distinguish between natural and synthetic diamonds.

0:32:250:32:30

Clearly, we knew that some day, synthetic gems

0:32:300:32:33

would be made available on the consumer market.

0:32:330:32:36

The crucial thing for us was to make sure that first, the industry,

0:32:360:32:39

but more importantly, the consumer,

0:32:390:32:42

had every means possible to ensure we could detect

0:32:420:32:46

the synthetic from the genuine article.

0:32:460:32:50

The problem they faced

0:32:500:32:52

was that synthetics were now very high quality.

0:32:520:32:56

It forced them to study down to the diamond's atomic structure

0:32:560:32:59

to detect even the tiniest differences.

0:32:590:33:04

De Beers developed a machine that used ultraviolet light

0:33:040:33:07

to reveal the difference between natural and synthetic diamonds.

0:33:070:33:12

Under ultraviolet light,

0:33:120:33:15

both natural and synthetic diamonds will glow to some degree.

0:33:150:33:19

This is called fluorescence.

0:33:190:33:21

But it is the patterns that are revealed by this glowing fluorescence

0:33:210:33:25

that can tell the two apart.

0:33:250:33:28

It's immediately obvious

0:33:290:33:30

from the strong blocky, blue fluorescence patterns

0:33:300:33:34

that this is a synthetic.

0:33:340:33:37

You wouldn't get these strong shapes of blue fluorescence from a natural.

0:33:370:33:42

Under the UV light, natural diamonds look very different,

0:33:440:33:48

producing a consistent, yet very faint blue glow.

0:33:480:33:52

De Beers are confident in the ability of their equipment

0:33:540:33:58

to detect these new colourless diamonds

0:33:580:34:01

and have sent their detection kit to gem labs around the world.

0:34:010:34:05

But the question is,

0:34:060:34:08

will that be enough to protect them in the long run?

0:34:080:34:10

As it turns out,

0:34:130:34:15

synthetic diamonds have never become as popular as the natural form.

0:34:150:34:19

Once material scientists found a way

0:34:200:34:23

of definitively identifying natural diamonds,

0:34:230:34:25

consumers opted for the genuine article,

0:34:250:34:29

proving that science can't always determine

0:34:290:34:32

whether a material will have value.

0:34:320:34:35

Diamond is a material made of pure carbon.

0:34:420:34:46

And surprisingly, it is not the only one.

0:34:460:34:49

Graphite, used in pencils, is also a pure carbon crystal.

0:34:510:34:56

Scientists believed that these were the only two naturally occurring forms,

0:34:570:35:02

until 1992, when they were stunned to find a third type.

0:35:020:35:08

And it was found by accident.

0:35:080:35:11

This story of discovery and revolution in chemistry

0:35:150:35:19

begins with astronomy.

0:35:190:35:21

The death of stars and the birth of planets.

0:35:210:35:23

Dying stars are pumping out carbon atoms into the interstellar medium.

0:35:250:35:29

The carbon in our body originated in space.

0:35:290:35:32

We now know that it was ejected from some star a long, long time ago

0:35:320:35:36

and was reprocessed and ended up on the Earth's biosphere.

0:35:360:35:40

What's absolutely fascinating and certainly something that excited me

0:35:400:35:44

when I first discovered it is that every one of us is made of carbon

0:35:440:35:47

and therefore, every one of us is made of stardust.

0:35:470:35:50

Ten years ago, Harry Kroto was studying stardust.

0:35:500:35:55

One thing we're not so sure about is, what is the form of that dust?

0:35:550:35:58

What's the structure?

0:35:580:36:00

How does the carbon nucleate to form these little wodges that go on to grow into planets?

0:36:000:36:04

Harry Kroto thought if he could create his own stardust here on Earth,

0:36:070:36:12

he might be able to learn more about its carbon structure

0:36:120:36:15

and even work out how planets formed.

0:36:150:36:19

He wanted to vaporise pieces of graphite

0:36:250:36:27

and then watch how the atoms came together.

0:36:270:36:31

So when he was granted access to a high-powered laser in Texas,

0:36:320:36:36

he jumped at the chance.

0:36:360:36:38

I was so excited, I pinched some money out of my wife's bank account,

0:36:420:36:45

got the cheapest ticket I could, and was there within three days.

0:36:450:36:49

I was keen on doing the experiment myself.

0:36:520:36:55

I was absolutely over the moon that I could do it.

0:36:550:36:58

What followed, none of them will forget.

0:37:050:37:09

Harry worked with the students,

0:37:130:37:15

doing run after run of graphite vaporised by laser.

0:37:150:37:18

It was practical, creative science at its best.

0:37:230:37:26

They saw evidence of Harry's long chains of carbon atoms captured fleetingly by the laser.

0:37:340:37:38

They also saw something else.

0:37:380:37:42

Harry Kroto and his team

0:37:440:37:45

repeatedly noticed clusters of 60 carbon atoms.

0:37:450:37:49

Again and again, 60 was the cluster that carbon preferred.

0:37:530:37:57

Why did carbon atoms form such a stable cluster?

0:37:570:38:00

What was special about the magic number 60?

0:38:020:38:05

The team tried to imagine what 60 carbon atoms would look like

0:38:120:38:18

if they were in a stable structure.

0:38:180:38:20

After trying every possible combination,

0:38:200:38:23

they settled on one shape that seemed to work.

0:38:230:38:27

It looked like they had discovered a new form of carbon.

0:38:280:38:32

One that was round.

0:38:340:38:36

The team turned to mathematicians for help.

0:38:440:38:46

We couldn't be the first people in the universe

0:38:490:38:51

to have discovered this structure.

0:38:510:38:53

They ought to know about the mathematics department.

0:38:530:38:56

So I called up Bill Beech and said,

0:38:560:38:57

"Sorry to bother you,

0:38:570:38:59

"but we have this hot new structure for a carbon molecule

0:38:590:39:02

"and it has 12 pentagons and 20 hexagons.

0:39:020:39:05

"I wonder if you could bother asking one of you students

0:39:050:39:08

"to find out what this polyhedral object is and give us a call back."

0:39:080:39:12

He did call back.

0:39:120:39:14

Bob Curl answered the phone and the mathematics chairman said,

0:39:140:39:17

"I could explain this to you in a number of ways,

0:39:170:39:20

"but what you've got there is a soccer ball."

0:39:200:39:23

You can imagine this excitement that you've discovered

0:39:250:39:28

a way of putting 60 carbon atoms together

0:39:280:39:30

and it turns out not only to be beautifully symmetric, but it's a soccer ball too!

0:39:300:39:34

Their paper to 'Nature' was a front cover story.

0:39:420:39:45

A really beautiful picture of C60.

0:39:470:39:50

It almost looks like you are looking at stars in the sky.

0:39:500:39:53

It was just such a fantastic moment.

0:39:530:39:56

But as I took the plane back, I was on such a high that I don't think...

0:39:560:39:59

I think the aeroplane would have flown without the engines running.

0:39:590:40:03

They named their structure Buckminster Fullerene.

0:40:040:40:07

Bucky Balls.

0:40:070:40:09

But Bucky Balls was still only a theory.

0:40:130:40:18

To prove C-60 existed as more than a blip on a graph,

0:40:180:40:22

they needed to synthesise it in the lab.

0:40:220:40:24

Rival research teams raced to be the first

0:40:330:40:36

to create this new form of carbon.

0:40:360:40:38

The most promising lead was a red solution of graphite soot.

0:40:410:40:45

But although the machines reported that C-60 was present,

0:40:460:40:50

nobody could see it.

0:40:500:40:52

Then, two physicists came up with a disarmingly simple answer.

0:40:540:40:59

The way it really happened was, Kratschmer called me from Germany

0:41:020:41:06

and said, "If you just take a little vial of the red material

0:41:060:41:09

"and you put a drop of it on a microscope slide,

0:41:090:41:12

"then you'll see an incredibly beautiful sight."

0:41:120:41:15

So I reproduced the experiment

0:41:150:41:17

by putting a tiny drop of the red liquid on the microscope slide.

0:41:170:41:21

And in just a very few seconds, as a matter of fact,

0:41:240:41:28

I was able to see these beautiful little crystals,

0:41:280:41:31

which were hexagonal platelets of brownish, orange colour.

0:41:310:41:36

'No longer fleeting atoms in a laser,

0:41:360:41:40

'not merely in red solution, now a new solid, pure carbon crystals.'

0:41:400:41:45

We realised by this time that we were surely seeing a crystalline form

0:41:470:41:51

of carbon 60, which was really a genuinely new form of carbon

0:41:510:41:55

and that we were probably the first people on Earth ever to even see this.

0:41:550:42:00

'This is the first ever film of a new carbon, Bucky Balls crystallising before your eyes.'

0:42:000:42:07

As a solid states physicist, it was incredibly nice to be able to say "Ah-ha!

0:42:070:42:11

"Now we've got something that we can really begin to experiment with.

0:42:110:42:16

"We can see it and work with it." And that was the moment of high excitement for me.

0:42:160:42:20

Don Huffman wasn't the only one who was excited.

0:42:270:42:30

C-60 was a promising new material.

0:42:300:42:33

It seemed everyone wanted to work with it.

0:42:330:42:36

Hello. My name is Don Cox. I am currently the project leader...

0:42:390:42:44

Hello. My name is Sergio Goran. I prepare and characterise southern containing fuellerene crystals...

0:42:440:42:51

I'm Mons Toman and I'm exploring the uses of fuellerenes...

0:42:510:42:54

I'm Ravio Parsni and I'm involved in synthesis and characterisation...

0:42:540:42:58

I'm Bill Shriver. I study the selectivity of fuellerene reactions...

0:42:580:43:02

I'm Lon Chen. We're working on the functionisation chemistry of C-60...

0:43:020:43:07

I'm Glen Miller and I'm studying the reactivity and structure of...

0:43:070:43:11

One of our interests is to see what it is you can do with C-60

0:43:110:43:16

once you make it behave differently than it does as a pure material.

0:43:160:43:22

We'd love to be the company that finds a way of putting a fuellerene

0:43:220:43:27

into a can of oil that will improve the performance of engine oils.

0:43:270:43:31

Scientists proposed a wide range of uses for C-60.

0:43:390:43:43

From targeting medicines in the body to acting as electrical conductors in microcircuits.

0:43:430:43:49

But 25 years later, they're still looking for the ultimate money-spinning application.

0:43:520:43:58

In material science, what counts is not just coming up with

0:44:010:44:05

the right use,

0:44:050:44:06

but finding a cost-effective way of realising it too.

0:44:060:44:10

Since the discovery of Bucky Balls, other even more intriguing forms of carbon have been found.

0:44:120:44:19

The latest to excite both the scientific and business communities is graphine.

0:44:190:44:24

It has incredible properties. It's the thinnest material ever known,

0:44:240:44:30

it's more conductive than copper and stronger than diamond,

0:44:300:44:34

meaning it could have huge potential in the electronics and computer industries.

0:44:340:44:40

Graphine really could be the next big thing, but it's still too early to tell.

0:44:430:44:48

It may even go on to join a small number of materials that have come to represent entire eras,

0:44:480:44:54

like the Stone Age, the Bronze Age and the Iron Age.

0:44:540:44:58

When we look back, we could well regard the 20th century as the Silicon Age.

0:44:580:45:04

Silicon was first isolated nearly two centuries ago.

0:45:110:45:16

But its electronic properties were not exploited until the 1940s.

0:45:160:45:20

That's when scientists discovered a feature of silicon

0:45:280:45:31

that would ultimately lead to the electronics revolution.

0:45:310:45:35

By adding small amounts of other minerals, they were able

0:45:370:45:41

to transform silicon from an insulator into a semi-conductor.

0:45:410:45:44

This new material could be made to behave like a switch that could turn on and off.

0:45:460:45:52

Or even amplify an electric signal being passed through it.

0:45:520:45:57

A transistor.

0:45:570:45:59

Transistors were to become the building blocks of something

0:46:020:46:06

that would change our lives forever - computers.

0:46:060:46:09

PLAYS TUNE

0:46:110:46:14

If you listen to the experts, they say that because of this chip,

0:46:140:46:17

startling changes are going to be made in all our lives - the way we live, work and play.

0:46:170:46:23

But how dramatic a revolution is it going to be?

0:46:230:46:25

In the early 1970s, Horizon investigated the potential impact of computers on the workplace.

0:46:300:46:38

'A strip mill is like a 2,000ft-long pastry board,

0:46:400:46:43

'rolling the hot steel progressively thinner.

0:46:430:46:46

'Two computers run this show and they're already recruiting a third.

0:46:460:46:50

'The steel ends up as a coil one tenth of an inch thick.

0:46:540:46:58

'The last human decision is taken here.

0:47:000:47:03

'A bell rings every 80 seconds and the man has to decide whether to press a button or not.

0:47:030:47:09

'If he does, the next slab comes out of the furnace and is sent off down the line.

0:47:090:47:13

'From then on, unless something goes wrong, the men in the other

0:47:130:47:18

'control pulpits perched high above the steel just sit back and watch.

0:47:180:47:23

'How does a man feel about coming to work, only as a back-up to the computer?

0:47:230:47:28

'One problem is isolation.

0:47:280:47:30

'An intercom is a poor substitute for a chat with your mates.

0:47:300:47:34

'And a fish tank is cold company for a sociable man.'

0:47:340:47:37

But while it was initially viewed with suspicion,

0:47:400:47:43

the silicon revolution gathered pace.

0:47:430:47:46

To perform more complicated tasks,

0:47:480:47:50

groups of transistors were placed together on a wafer of pure silicon.

0:47:500:47:55

This became known as the silicon chip.

0:47:550:47:57

A device that promised a brave new world.

0:48:020:48:05

'You're going to see something absolutely amazing,

0:48:080:48:11

'a machine reading to a blind man.

0:48:110:48:13

'A computer will read an ordinary book.

0:48:200:48:24

'It will speak it aloud in its own artificial voice.

0:48:240:48:27

'The first words of the book are, "Why suddenly do so many feel

0:48:350:48:40

'"so strongly about Jimmy Carter, pro and con?"'

0:48:400:48:44

-COMPUTER-GENERATED VOICE:

-Why suddenly do so many feel

0:48:450:48:48

so strongly about Jimmy Carter, pro and con?

0:48:480:48:52

This book attempts to unravel the mysteries of Carter's extraordinary success story,

0:48:520:48:59

as remembered from Jimmy,

0:48:590:49:02

the nominee of the one-nine-seven-six

0:49:020:49:05

Democratic National Convention, as well as to provide "gui-de" lines...

0:49:050:49:10

G-U-I-D-E-L-I-N-E-S, "gui-de" lines...

0:49:120:49:18

for understanding and evaluating the event...

0:49:180:49:22

'A man will talk and a computer obey.'

0:49:230:49:27

Turn right, stop.

0:49:270:49:30

Turn right, stop.

0:49:300:49:31

'A man's voice being understood by a machine.'

0:49:330:49:37

Stop. Forward.

0:49:370:49:39

Run.

0:49:390:49:40

Turn left.

0:49:440:49:46

'At the heart of both these machines are tiny powerful computers

0:49:480:49:52

'built around the new technology of silicon chips.

0:49:520:49:56

'This is the size of a computer today.

0:49:580:50:01

'As powerful as the biggest of only a few years ago,

0:50:010:50:04

'but 1,000 times cheaper.

0:50:040:50:06

'What makes it possible is this.

0:50:060:50:09

'Inside here is a silicon chip, with all the important components

0:50:090:50:15

'of the computer etched onto its tiny surface.

0:50:150:50:19

'It's called a micro-processor.

0:50:210:50:23

'Under an electron microscope, magnified and slowed down, it's possible to see it at work.

0:50:250:50:30

'Electric pulses being directed by switches.

0:50:320:50:35

'By sending the pulses along different channels,

0:50:350:50:38

'a chip can be made to do anything from arithmetic to reading a book.

0:50:380:50:41

'Such chips will totally revolutionise our way of life.

0:50:440:50:48

'They're the reason why Japan is abandoning its ship building

0:50:480:50:51

'and why our children will grow up without jobs to go to.'

0:50:510:50:55

The extent of the revolution became apparent,

0:50:570:51:00

as computers were increasingly integrated into our daily lives.

0:51:000:51:04

'There's a new machine coming into use.

0:51:040:51:07

'It's called a word processor and it's probably a more important step

0:51:070:51:11

'than the invention of the typewriter.

0:51:110:51:14

'It uses no paper, the text can be moved around,

0:51:170:51:21

'edited and instantly corrected.

0:51:210:51:24

'The machine works out line lengths, where to begin a new page,

0:51:240:51:27

'and even corrects simple spelling mistakes.

0:51:270:51:30

'The text is stored in memory chips, controlled by two micro-processors.

0:51:330:51:37

'They rearrange the text by shunting it from one memory block to another.'

0:51:370:51:42

But whilst we cautious Brits were still working out what we thought

0:51:440:51:48

about the silicon revolution, other nations were quick to embrace it.

0:51:480:51:52

'These children are programming their own Space Invaders.

0:51:520:51:57

'This little boy can be no more than eight years old.

0:52:000:52:03

'In the market place at Akihabara in Tokyo,

0:52:030:52:07

'micro-electronics has gone do-it-yourself.

0:52:070:52:10

'This shop goes further still. It's the cheapest place in town to buy integrated circuits, chips.

0:52:130:52:19

'On a Saturday afternoon,

0:52:190:52:21

'they queue up to buy the latest memory chips for a handful of yen.

0:52:210:52:24

'The Silicon Age has gone DIY too.

0:52:240:52:27

'Its very immediacy gives you an indication of just how far

0:52:270:52:30

'micro-electronics has sunk into Japanese culture.

0:52:300:52:34

'A whole generation is growing up in Japan as familiar

0:52:340:52:37

'with building home computers as our children are at building Lego.'

0:52:370:52:41

This willingness to adopt new technology meant Japan

0:52:440:52:48

was at the forefront of the silicon goldrush.

0:52:480:52:51

Japanese business raced neck and neck with the US to develop the world's fastest silicon chips.

0:52:530:53:00

'Dominating big computers means toppling the world leader, America's IBM.

0:53:000:53:05

'And in Kawasaki City, Fujitsu are preparing to do just that.

0:53:050:53:09

'Sat in the corner, looking as exciting as a row of filing cabinets, is the machine

0:53:090:53:14

'they hope to do it with, their latest number cruncher - the M380.

0:53:140:53:17

'But for the M380, Fujitsu has moved ahead.

0:53:240:53:28

'These are the latest chips, the much more powerful 64,000 bit,

0:53:280:53:32

'known in the trade as the 64K.'

0:53:320:53:35

64K sounds tiny today, when we have megabytes and terabytes.

0:53:350:53:41

But in 1984, it was extraordinarily powerful.

0:53:410:53:45

In 20 years, silicon had gone from a material in which scientists

0:53:470:53:51

had observed interesting behaviour to one that had given us digital watches, personal computers

0:53:510:53:57

and all manner of technological advances.

0:53:570:54:00

It was our deep understanding of silicon's potential that kick-started

0:54:000:54:04

a vast electronics revolution.

0:54:040:54:07

Ah!

0:54:100:54:12

As I move it around the table top,

0:54:120:54:16

a little cursor, or arrow, on the screen moves in a relative position.

0:54:160:54:21

An operator can change the photographic record,

0:54:210:54:24

using a device similar to an electronic paintbrush.

0:54:240:54:28

This is a highly intelligent car.

0:54:280:54:30

'Go left onto the A3095.'

0:54:310:54:34

Ever smaller transistors that worked faster

0:54:430:54:47

and were cheaper to make cemented silicon's success.

0:54:470:54:50

A few years ago,

0:54:530:54:54

the computers operating this little model

0:54:540:54:57

would have been so big,

0:54:570:54:59

you could hardly have got them inside a double-decker bus.

0:54:590:55:02

By 1989, a million transistors fitted on a single chip.

0:55:060:55:11

In 2005, it was a billion.

0:55:110:55:14

'When you're dealing with figures like this, it isn't an evolution any more, it's a revolution.'

0:55:160:55:22

But there is a physical limit to how small silicon transistors can be made.

0:55:280:55:33

And that means we must find a replacement material

0:55:380:55:42

if we want even smaller, faster and cheaper computing at our fingertips.

0:55:420:55:47

At the cutting edge of semi-conductor science

0:56:090:56:12

is organic electronics, where transistors are made of carbon-based materials 100 times smaller

0:56:120:56:19

than the tiniest silicon switches.

0:56:190:56:21

Experts predict that silicon's dominance may finally be over within the next ten years.

0:56:320:56:37

Scientists have gone to the ends of the Earth

0:56:530:56:58

and even beyond in their bid to find and develop the materials that have dramatically changed our world,

0:56:580:57:05

and the way we all live in it.

0:57:050:57:07

They've explored ocean depths, invented groundbreaking new techniques, and come to understand

0:57:100:57:17

materials at a subatomic level.

0:57:170:57:20

And all the while,

0:57:230:57:26

big business has been watching for the next major breakthrough.

0:57:260:57:30

The potential a material has to change every aspect of our lives means that science and industry

0:57:330:57:40

will never give up in their pursuit of the next big thing.

0:57:400:57:43

With the right application, a material can truly propel us

0:57:430:57:47

out of one age and into the next.

0:57:470:57:49

And it's likely that understanding them at the most fundamental level possible will be crucial

0:57:490:57:56

to finding new ways of exploiting them.

0:57:560:57:58

But beyond that, who knows where the next big breakthrough is going to take us!

0:57:580:58:03

# Cos we are living in a material world

0:58:090:58:14

# And I am a material girl

0:58:140:58:17

# You know that we are living in a material world

0:58:170:58:21

# And I am a material girl

0:58:210:58:24

# (Living in a material) Material! #

0:58:240:58:27

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0:58:290:58:33

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