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This fantastic prototype sports car is powered by a remarkable | 0:00:02 | 0:00:06 | |
energy storage device - | 0:00:06 | 0:00:08 | |
a device that we carry around in our pockets and a device that's helped | 0:00:08 | 0:00:12 | |
revolutionise the modern world. | 0:00:12 | 0:00:14 | |
The battery. | 0:00:15 | 0:00:16 | |
In this lecture, I'm going to investigate one of the most | 0:00:18 | 0:00:21 | |
important scientific challenges of our generation. | 0:00:21 | 0:00:25 | |
What's the best way to store energy? | 0:00:25 | 0:00:27 | |
To find out, we are going to try and get into | 0:00:33 | 0:00:36 | |
the Guinness Book Of World Records with a very special battery. | 0:00:36 | 0:00:40 | |
Welcome to my final 80th anniversary Christmas lectures. | 0:01:17 | 0:01:22 | |
I'm Saiful Islam, I'm a professor of chemistry at the University of Bath. | 0:01:22 | 0:01:27 | |
When we talk about energy storage, we're often talking about one thing, | 0:01:28 | 0:01:34 | |
the battery. Try to imagine a world without them - | 0:01:34 | 0:01:38 | |
you'd have no mobile phones, no laptops, | 0:01:38 | 0:01:42 | |
tablet computers or even remotes for your TV. | 0:01:42 | 0:01:46 | |
I think batteries are amazing. | 0:01:47 | 0:01:50 | |
But they can be very, very familiar, | 0:01:50 | 0:01:53 | |
so I wanted to show you an unusual and slightly, in fact, I think, | 0:01:53 | 0:01:58 | |
quite scary, demonstration of what batteries can do. | 0:01:58 | 0:02:01 | |
So I've rigged this up. | 0:02:01 | 0:02:04 | |
This is... | 0:02:04 | 0:02:06 | |
..an arc welder, not something I thought I'd be doing. | 0:02:07 | 0:02:12 | |
It uses electricity to cut through solid metal. | 0:02:12 | 0:02:16 | |
It's one of the most energy-intensive processes you can think of. | 0:02:16 | 0:02:20 | |
The actual tip here can reach 20,000 Celsius, | 0:02:20 | 0:02:25 | |
and that extractor fan there is going to take up the fumes. | 0:02:25 | 0:02:31 | |
But the welder is hooked up to just a couple of ordinary car batteries | 0:02:31 | 0:02:36 | |
and come with me and I'll show you what they look like. | 0:02:36 | 0:02:39 | |
So right here are two ordinary car batteries and we've hooked them up | 0:02:42 | 0:02:47 | |
but we've put them out here because there is a small chance | 0:02:47 | 0:02:51 | |
they might explode. | 0:02:51 | 0:02:53 | |
So let's try and set things up. | 0:02:53 | 0:02:57 | |
So, I'm no welder, I'm just a humble chemist, | 0:02:57 | 0:03:01 | |
but I'll be happy to give it a go. | 0:03:01 | 0:03:03 | |
So this is my hand in glove. | 0:03:03 | 0:03:06 | |
So it is really important at this stage, right, before I get down here... | 0:03:08 | 0:03:12 | |
So if you can put your goggles on now. | 0:03:12 | 0:03:14 | |
I tried something earlier. | 0:03:21 | 0:03:23 | |
It wasn't a fantastic effort. | 0:03:24 | 0:03:25 | |
Right. | 0:03:43 | 0:03:45 | |
Let's see if that's better than my first attempt. | 0:03:46 | 0:03:49 | |
Well, let's have a look. | 0:03:49 | 0:03:51 | |
So if you look here, I tried to do RI twice. | 0:03:51 | 0:03:57 | |
I don't think I'll give up my day job and become a welder. | 0:03:57 | 0:04:01 | |
So I'd say that's my abstract period and that's my sort of dodgy period. | 0:04:01 | 0:04:07 | |
So, anyway, I hope the sparks were flying there. | 0:04:07 | 0:04:10 | |
So that is a very intensive process. | 0:04:12 | 0:04:15 | |
But remember, that was done from the energy from a couple of | 0:04:15 | 0:04:19 | |
car batteries. Storing energy is more important now than at any time | 0:04:19 | 0:04:26 | |
in human history. It affects all aspects of our lives. | 0:04:26 | 0:04:31 | |
So how many of you | 0:04:31 | 0:04:33 | |
have got phones in your pockets? | 0:04:33 | 0:04:35 | |
I imagine most of you. | 0:04:35 | 0:04:38 | |
So why don't you get them out? | 0:04:38 | 0:04:40 | |
Let's have a look at them. | 0:04:40 | 0:04:41 | |
OK, and you can turn them on. | 0:04:42 | 0:04:45 | |
So a simple question - how many of them are fully-charged? | 0:04:46 | 0:04:51 | |
Who's got them fully-charged? | 0:04:51 | 0:04:52 | |
Not that many. How many are less than half-charged? | 0:04:54 | 0:04:59 | |
Right. | 0:04:59 | 0:05:00 | |
And how many of you have actually run out of battery altogether? | 0:05:00 | 0:05:04 | |
Just a few of you. | 0:05:06 | 0:05:07 | |
So our phones often struggle to last a single day. | 0:05:09 | 0:05:13 | |
Over the next hour, I'm going to try and do something truly amazing - | 0:05:14 | 0:05:20 | |
I'm going to look at how we might supercharge a mobile phone | 0:05:20 | 0:05:25 | |
and get it to last a whole year without plugging into the mains. | 0:05:25 | 0:05:31 | |
So I'm sure all of you, and I know I would, would love one of those. | 0:05:31 | 0:05:35 | |
So how much energy would that take? | 0:05:35 | 0:05:37 | |
Look at this energy meter over here. | 0:05:38 | 0:05:41 | |
OK, so... | 0:05:45 | 0:05:46 | |
This meter uses units we can all understand - | 0:05:48 | 0:05:51 | |
AA batteries. | 0:05:51 | 0:05:53 | |
Our target for the year is about 800 AA batteries, which you will see, | 0:05:53 | 0:06:00 | |
vroom, 800. | 0:06:00 | 0:06:02 | |
So, to give you a better feel of what that looks like, | 0:06:04 | 0:06:06 | |
I've got this large container and I'm going to go up the... | 0:06:06 | 0:06:09 | |
..ladder to pour them in. | 0:06:11 | 0:06:13 | |
Oh, they are down there. | 0:06:13 | 0:06:15 | |
Erm, I think I need a volunteer to help out. | 0:06:15 | 0:06:18 | |
Any volunteers to help out? | 0:06:18 | 0:06:20 | |
So do you want to come round? Yes, come over. | 0:06:20 | 0:06:23 | |
Can I take your name? | 0:06:27 | 0:06:28 | |
Asheen? | 0:06:30 | 0:06:31 | |
This is Asheen, he's going to help me put those batteries in there. | 0:06:31 | 0:06:35 | |
So if you could pass me one bucket at a time. | 0:06:35 | 0:06:38 | |
So this is what the 800 AA batteries look like if you wanted to power | 0:06:38 | 0:06:43 | |
your mobile phone for a whole year. | 0:06:43 | 0:06:45 | |
OK. Do you want to give me another bucket there? | 0:06:49 | 0:06:52 | |
So, that's... | 0:06:52 | 0:06:53 | |
..two. | 0:06:54 | 0:06:56 | |
So this is... | 0:06:56 | 0:06:57 | |
Just two more to go. | 0:07:01 | 0:07:02 | |
And the last one. | 0:07:11 | 0:07:12 | |
Let's see. So you can see, it's already really gone up | 0:07:12 | 0:07:15 | |
to a high height. And then, the last lot. | 0:07:15 | 0:07:18 | |
So it's already gone to the top. | 0:07:21 | 0:07:23 | |
So that's what you would need to power your phone for a year. | 0:07:23 | 0:07:28 | |
Can you imagine trying to carry that around in your pocket? | 0:07:28 | 0:07:31 | |
You'd need some very large pockets there. | 0:07:31 | 0:07:34 | |
Thank you, thank you very much. | 0:07:34 | 0:07:37 | |
Let's thank him. | 0:07:37 | 0:07:40 | |
So you can see already it's going to be a tough challenge. | 0:07:40 | 0:07:43 | |
The key is storing more energy in a smaller size and a lighter weight. | 0:07:43 | 0:07:49 | |
We want to increase something we call energy density. | 0:07:49 | 0:07:54 | |
But first, it always helps to know our scientific history. | 0:07:54 | 0:07:59 | |
Who made the first chemical battery? | 0:07:59 | 0:08:03 | |
So one of the earliest batteries is right here in the vaults | 0:08:04 | 0:08:08 | |
of the Royal Institution and we can show it to you right now. | 0:08:08 | 0:08:12 | |
So this is our museum curator, Charlotte, and she'll be holding it. | 0:08:16 | 0:08:20 | |
I'm not allowed to touch it because it's very precious. | 0:08:20 | 0:08:23 | |
Here is a voltaic pile. | 0:08:24 | 0:08:27 | |
It was made by Alessandro Volta in Italy and given to Michael Faraday | 0:08:28 | 0:08:34 | |
nearly 200 years ago. | 0:08:34 | 0:08:36 | |
So what is it made of? | 0:08:36 | 0:08:38 | |
So you can see, | 0:08:38 | 0:08:39 | |
it's got these kind of metal slabs and they are the metal electrodes, | 0:08:39 | 0:08:45 | |
so zinc and copper. | 0:08:45 | 0:08:48 | |
Between them, I don't know whether you can see on the camera, | 0:08:48 | 0:08:50 | |
there's kind of cloth, a bit of cloth there, | 0:08:50 | 0:08:53 | |
and that would have been soaked with salt water. | 0:08:53 | 0:08:56 | |
It might look crude, but it did store a small electrical charge. | 0:08:56 | 0:09:02 | |
So you'd probably need 1,000 of these to power your current | 0:09:02 | 0:09:06 | |
modern mobile phone. | 0:09:06 | 0:09:08 | |
But this was a key moment in the history of science. | 0:09:09 | 0:09:13 | |
It was one of the first times anyone had been able to store electricity. | 0:09:13 | 0:09:19 | |
It gave birth to a whole new field called electrochemistry. | 0:09:19 | 0:09:23 | |
So thank you, Charlotte, thank you. | 0:09:23 | 0:09:24 | |
So the voltaic pile I've just shown you and all batteries basically work | 0:09:33 | 0:09:38 | |
on the same principle. | 0:09:38 | 0:09:40 | |
A good way of explaining batteries | 0:09:40 | 0:09:43 | |
is with a very complex piece of machinery. | 0:09:43 | 0:09:46 | |
A lemon. | 0:09:48 | 0:09:50 | |
And here, we're going to actually... | 0:09:50 | 0:09:54 | |
Something I prepared earlier. | 0:09:54 | 0:09:55 | |
We've got basically how a lemon battery works. | 0:09:57 | 0:10:01 | |
As before, with that voltaic pile, you've got a metal electrode, | 0:10:03 | 0:10:08 | |
in this case, a copper nail. | 0:10:08 | 0:10:10 | |
And we've got at the end of this one, you can see a magnesium strip, | 0:10:10 | 0:10:16 | |
which is the other electrode. | 0:10:16 | 0:10:18 | |
So let's have a look at this voltmeter. | 0:10:18 | 0:10:20 | |
So if you look at the value at the moment, it should be reading zero. | 0:10:20 | 0:10:25 | |
So if I plug this in, it should, hopefully, give us a voltage. | 0:10:25 | 0:10:30 | |
So you can see that | 0:10:33 | 0:10:35 | |
and it's gone up to 1.42, 1.43 volts. | 0:10:35 | 0:10:39 | |
Actually, 1.44. | 0:10:39 | 0:10:40 | |
So actually it's showing a voltage. | 0:10:40 | 0:10:43 | |
But these are the Christmas lectures. | 0:10:43 | 0:10:47 | |
One lemon is not enough. | 0:10:47 | 0:10:50 | |
So I wanted to go large. | 0:10:50 | 0:10:52 | |
I told the Royal Institution I wanted to go very large, | 0:10:52 | 0:10:56 | |
and it's so large it won't even squeeze into this lecture theatre. | 0:10:56 | 0:11:00 | |
So follow me and I'm going to show you what it looks like. | 0:11:00 | 0:11:03 | |
So this here is the biggest lemon battery the world has ever seen. | 0:11:07 | 0:11:12 | |
It's gigantic. | 0:11:12 | 0:11:14 | |
Look at it. Over 1,000 lemons. | 0:11:14 | 0:11:17 | |
In fact, we cut them in half and sliced them | 0:11:17 | 0:11:20 | |
to make 2,016 lemon slices, so this is cutting-edge technology. | 0:11:20 | 0:11:26 | |
LAUGHTER | 0:11:26 | 0:11:27 | |
Let me get a closer look at one of these batteries, OK. | 0:11:27 | 0:11:31 | |
Joe, do you want to get closer to one of these batteries? | 0:11:31 | 0:11:34 | |
So look - this is exactly one of the batteries that I showed you inside, | 0:11:34 | 0:11:38 | |
with the electrodes and clips. | 0:11:38 | 0:11:41 | |
So let me meet the adjudicator from the Guinness Book Of World Records, | 0:11:42 | 0:11:46 | |
Craig, Craig Glenday, great to meet you. | 0:11:46 | 0:11:49 | |
So let's move over to the voltmeter. | 0:11:49 | 0:11:53 | |
So as you know, there were some issues with some of the lemons, | 0:11:53 | 0:11:57 | |
so we weren't sure if we were going to quite reach the target. | 0:11:57 | 0:11:59 | |
But what's the target we need to get to, to break a world record? | 0:11:59 | 0:12:02 | |
To achieve the official Guinness World Records title, | 0:12:02 | 0:12:05 | |
you must exceed 1,000 on the meter. | 0:12:05 | 0:12:07 | |
So we are looking for 1,000 or more to be successful. | 0:12:07 | 0:12:10 | |
OK, so, I'm going to do the connection | 0:12:10 | 0:12:14 | |
and it rests on whether I can connect them up properly | 0:12:14 | 0:12:17 | |
and we're going to pass that total. | 0:12:17 | 0:12:20 | |
But I need a very large... | 0:12:20 | 0:12:23 | |
..countdown from the audience so I can hear it from here. | 0:12:24 | 0:12:28 | |
So give me a countdown. | 0:12:28 | 0:12:30 | |
AUDIENCE: Three, two, one. | 0:12:30 | 0:12:34 | |
So what does it read, Craig? | 0:12:37 | 0:12:39 | |
I'm very pleased to say it reads 1,275, | 0:12:39 | 0:12:42 | |
so you've more than broken the Guinness World Records title. | 0:12:42 | 0:12:45 | |
-Congratulations. -Great! | 0:12:45 | 0:12:47 | |
We've done it! We've got a world record! | 0:12:53 | 0:12:56 | |
Yay! | 0:12:58 | 0:12:59 | |
That was exciting. It was actually very nerve-racking and it was quite | 0:13:16 | 0:13:20 | |
close to the edge, just before this lecture. | 0:13:20 | 0:13:22 | |
So this may be the biggest lemon battery in the world. | 0:13:22 | 0:13:27 | |
But could it power our phone for a year? | 0:13:27 | 0:13:31 | |
We have a scientific term for that. | 0:13:31 | 0:13:33 | |
No way, Jose. | 0:13:33 | 0:13:35 | |
To really understand how that lemon battery worked, | 0:13:37 | 0:13:41 | |
we need to get at the atomic level, | 0:13:41 | 0:13:43 | |
we need to understand the chemistry. | 0:13:43 | 0:13:45 | |
And this, right in front of you, | 0:13:45 | 0:13:48 | |
is a scaled up version of that lemon battery. | 0:13:48 | 0:13:51 | |
So let me explain what we have here. | 0:13:51 | 0:13:53 | |
So this is the magnesium strip, that's one of the electrodes. | 0:13:53 | 0:13:58 | |
And here we have a very oversized nail, | 0:13:58 | 0:14:01 | |
the copper nail that was in there. | 0:14:01 | 0:14:04 | |
And in between that is a representation of the lemon juice, | 0:14:04 | 0:14:08 | |
the electrolytes, in between those two electrodes. | 0:14:08 | 0:14:12 | |
So that is the battery. | 0:14:12 | 0:14:14 | |
So what's going around the side? | 0:14:14 | 0:14:15 | |
So around here is... | 0:14:15 | 0:14:18 | |
..the wire, the external circuit, | 0:14:20 | 0:14:22 | |
where the electrons should pass through. | 0:14:22 | 0:14:25 | |
OK. So that is basically the battery and the external circuit. | 0:14:25 | 0:14:29 | |
So I need a volunteer, please. | 0:14:29 | 0:14:32 | |
And I think we have one already arranged, so, Isaac, | 0:14:32 | 0:14:35 | |
do you want to come down? | 0:14:35 | 0:14:37 | |
OK. | 0:14:39 | 0:14:40 | |
So, Isaac, do you want to come round to the front here? | 0:14:40 | 0:14:43 | |
So, we've got... | 0:14:43 | 0:14:45 | |
..a board for you to wear. | 0:14:46 | 0:14:48 | |
I know it's not a very fetching board, | 0:14:48 | 0:14:50 | |
but it tells us exactly what you are for this evening. | 0:14:50 | 0:14:54 | |
So you are, for this evening only, you're going to be a magnesium atom. | 0:14:54 | 0:15:02 | |
OK? So what does a magnesium atom have? | 0:15:02 | 0:15:04 | |
-It has... -Is it electrons? | 0:15:04 | 0:15:06 | |
Electrons, it does. | 0:15:06 | 0:15:08 | |
So if you stay around just to the side here, right to the side there. | 0:15:08 | 0:15:13 | |
So you're going to hold these two electrons. | 0:15:13 | 0:15:16 | |
So get those two hands ready. | 0:15:16 | 0:15:18 | |
The thing about these electrons, | 0:15:19 | 0:15:21 | |
they do wander off, they're very mobile. | 0:15:21 | 0:15:23 | |
So let's have a look. So if you hold that. | 0:15:23 | 0:15:25 | |
Just to make it more difficult for you, I know you are not a juggler, | 0:15:27 | 0:15:30 | |
you're going to hold those two electrons like that. | 0:15:30 | 0:15:32 | |
So this is the magnesium atom with two electrons. | 0:15:32 | 0:15:36 | |
So electrons are the smallest particles of the atom. | 0:15:36 | 0:15:41 | |
They act as carriers of electrical charge. | 0:15:41 | 0:15:45 | |
So when we talk about electricity, we are really talking about | 0:15:45 | 0:15:49 | |
electrons moving. | 0:15:49 | 0:15:51 | |
So what happens when we connect the wire? | 0:15:51 | 0:15:53 | |
So you can see already that there is a clip there, | 0:15:53 | 0:15:56 | |
already connected to that electrode so there's one clip here | 0:15:56 | 0:16:01 | |
representing our other connection. | 0:16:01 | 0:16:06 | |
So I'm going to connect that to the magnesium electrode and I'm going to | 0:16:06 | 0:16:11 | |
connect it to the circuit in a second. | 0:16:11 | 0:16:13 | |
And before that, can you get ready with your electron? | 0:16:13 | 0:16:16 | |
So if you hold it there but don't let it roll it yet. | 0:16:16 | 0:16:19 | |
So just hold it there and when I connect them, | 0:16:19 | 0:16:22 | |
just give it a little nudge, a little push around that circuit, OK. | 0:16:22 | 0:16:26 | |
So let me make the connection now and then give it a little nudge, yeah. | 0:16:26 | 0:16:30 | |
So this electron moving is electricity and actually, | 0:16:30 | 0:16:33 | |
it would power that lamp. There you are. | 0:16:33 | 0:16:36 | |
Here's another electron. | 0:16:36 | 0:16:37 | |
There you are. So those electrons, ie, | 0:16:39 | 0:16:41 | |
these large balls representing them are actually powering a device. | 0:16:41 | 0:16:46 | |
And that's how the start of that process works. | 0:16:46 | 0:16:50 | |
But there's another driving force - | 0:16:50 | 0:16:52 | |
that magnesium atom has just lost two negatively charged electrons. | 0:16:52 | 0:16:57 | |
So what happens there? | 0:16:57 | 0:16:58 | |
It becomes... | 0:16:58 | 0:16:59 | |
..a magnesium ion. | 0:17:02 | 0:17:04 | |
Yes. And there is a driving force that pushes that ion | 0:17:04 | 0:17:09 | |
across the pool, the electrolyte. | 0:17:09 | 0:17:10 | |
So do you want to go through that pool, but very carefully, because it's full of balls. | 0:17:10 | 0:17:14 | |
Right to the other side. | 0:17:14 | 0:17:16 | |
So, if you come to the side here. | 0:17:16 | 0:17:18 | |
Great. So you're an ion now. | 0:17:20 | 0:17:22 | |
How you feeling? Positive? | 0:17:22 | 0:17:24 | |
Great. | 0:17:24 | 0:17:25 | |
LAUGHTER | 0:17:25 | 0:17:27 | |
So that's basically how that lemon battery worked. | 0:17:27 | 0:17:32 | |
What happens here, | 0:17:32 | 0:17:33 | |
there are some further chemical reactions to balance the charges. | 0:17:33 | 0:17:37 | |
But this is not rechargeable. | 0:17:38 | 0:17:39 | |
What happens is that, once we've used up all the metal, | 0:17:39 | 0:17:43 | |
it goes from that side to this side and if it uses up all that metal, | 0:17:43 | 0:17:48 | |
you actually don't produce any more electricity. | 0:17:48 | 0:17:51 | |
So this is not a rechargeable battery | 0:17:51 | 0:17:54 | |
like the ones that you find in your phones. | 0:17:54 | 0:17:56 | |
Thank you, Isaac, for helping out. | 0:17:56 | 0:17:58 | |
And thank you very much. OK. Do you want to go back to your place? | 0:18:00 | 0:18:03 | |
Almost all of the rechargeable batteries | 0:18:12 | 0:18:14 | |
in your phones and laptops rely on a single rare | 0:18:14 | 0:18:18 | |
and extraordinary metal. | 0:18:18 | 0:18:20 | |
As part of our 80th celebrations, | 0:18:20 | 0:18:22 | |
we are inviting Christmas lecturers past to help out. | 0:18:22 | 0:18:27 | |
To introduce you to the properties of this material, | 0:18:27 | 0:18:31 | |
please welcome the 2012 Christmas Lecturer | 0:18:31 | 0:18:33 | |
and fellow chemist, Dr Peter Wothers. | 0:18:33 | 0:18:36 | |
-Hi there, Peter. -Hi there. | 0:18:39 | 0:18:41 | |
Peter, I'm so glad you could join us. | 0:18:46 | 0:18:48 | |
It's great to be back. | 0:18:48 | 0:18:49 | |
So, tell us about your lectures back four years ago, 2012. | 0:18:49 | 0:18:53 | |
So we were looking at the chemistry of the elements, | 0:18:53 | 0:18:55 | |
so all the different elements around us and how important they are | 0:18:55 | 0:18:58 | |
-in our everyday lives. -I really enjoyed watching them. | 0:18:58 | 0:19:02 | |
So what was your favourite demonstration amongst the lectures? | 0:19:02 | 0:19:05 | |
I think my favourite one was actually when we burnt a diamond | 0:19:05 | 0:19:09 | |
in oxygen gas. | 0:19:09 | 0:19:11 | |
So Harry Kroto, Nobel Prize winner, came down and helped out and it was | 0:19:11 | 0:19:15 | |
just absolutely fantastic to see this tiny little diamond in the gas | 0:19:15 | 0:19:19 | |
there just glowing beautifully like a little star trapped in a jar. | 0:19:19 | 0:19:23 | |
-It is quite stunning to see, isn't it? -That's right, yes. | 0:19:23 | 0:19:25 | |
There are no flames coming from this, so this is just, | 0:19:25 | 0:19:29 | |
again, the heat of the reaction as the carbon combines with the oxygen | 0:19:29 | 0:19:34 | |
that's present flowing through here forming carbon dioxide. | 0:19:34 | 0:19:38 | |
That is absolutely stunning. | 0:19:38 | 0:19:40 | |
Just look at that, it's glowing all by itself, | 0:19:40 | 0:19:42 | |
it's absolutely brilliant. | 0:19:42 | 0:19:44 | |
So I've got you on for a specific reason - | 0:19:44 | 0:19:46 | |
I've mentioned this strange material. | 0:19:46 | 0:19:50 | |
Can you tell us a bit more about it? | 0:19:50 | 0:19:52 | |
Yes, so, this is one of the elements and it's a metal | 0:19:52 | 0:19:55 | |
and I've got a little sample in the jar here. | 0:19:55 | 0:19:58 | |
This metal is actually incredibly reactive, | 0:20:00 | 0:20:03 | |
much more reactive than a lump of iron would be. | 0:20:03 | 0:20:06 | |
It's in fact so reactive that it reacts with air and with water, | 0:20:06 | 0:20:10 | |
as we shall see in a minute. | 0:20:10 | 0:20:12 | |
So this is... | 0:20:12 | 0:20:14 | |
Let me just take a piece out. This is in the form of foil. | 0:20:15 | 0:20:18 | |
And you can see it's just a nice, | 0:20:22 | 0:20:24 | |
shiny metal there and it's the element lithium. | 0:20:24 | 0:20:29 | |
And this is actually in fact so light that it will float on water, | 0:20:29 | 0:20:34 | |
-which is rather nice. -Let's have a see. | 0:20:34 | 0:20:36 | |
-OK, but you might want to step back a little bit. -I will do. | 0:20:36 | 0:20:38 | |
OK, there we go. | 0:20:38 | 0:20:40 | |
And that's because it's instantly reacting with the water. | 0:20:40 | 0:20:44 | |
The lithium metal is turning into lithium ions, | 0:20:45 | 0:20:48 | |
which are dissolving in the water there and also giving out | 0:20:48 | 0:20:51 | |
hydrogen gas and forming an alkaline hydroxide solution. | 0:20:51 | 0:20:54 | |
-It's gone already. -It's great. | 0:20:57 | 0:20:59 | |
Well, thank you, Peter, for telling us about this strange material, | 0:20:59 | 0:21:04 | |
the lithium metal, and with an elegant demonstration. | 0:21:04 | 0:21:07 | |
-Let's thank Peter Wothers once again. -Thank you. | 0:21:07 | 0:21:10 | |
So why keep such a reactive metal in our pockets? | 0:21:21 | 0:21:26 | |
What makes lithium so good? | 0:21:26 | 0:21:29 | |
To illustrate this I've got a pair of lead acid batteries here. | 0:21:29 | 0:21:33 | |
How much work can they do? | 0:21:33 | 0:21:36 | |
Well, we've decided to show them a slightly different way. | 0:21:36 | 0:21:40 | |
We've calculated how far they would turn a famous London landmark. | 0:21:40 | 0:21:44 | |
So on this screen, you should see... | 0:21:44 | 0:21:48 | |
This is just a time-lapse photography of the London Eye. | 0:21:48 | 0:21:52 | |
Those lead acid batteries can actually turn the London Eye | 0:21:52 | 0:21:55 | |
a certain amount. So let's see how much that could be. | 0:21:55 | 0:21:59 | |
So we can see, | 0:22:00 | 0:22:02 | |
it's only about 6%, OK. | 0:22:02 | 0:22:06 | |
That would be around 27 metres of those pods moving round. | 0:22:06 | 0:22:12 | |
These are lithium ion batteries | 0:22:12 | 0:22:16 | |
of the same weight as our lead acid ones there. | 0:22:16 | 0:22:20 | |
So let's see what they would do to this London Eye. | 0:22:20 | 0:22:24 | |
So let's have a look. They would go round... | 0:22:24 | 0:22:26 | |
..25%. | 0:22:29 | 0:22:31 | |
So it moves the pods over 100 metres. | 0:22:31 | 0:22:35 | |
And that's because a lithium battery stores a lot more energy | 0:22:35 | 0:22:39 | |
than any older lead acid battery of the same weight. | 0:22:39 | 0:22:42 | |
It's what we call a higher energy density. | 0:22:42 | 0:22:46 | |
And this has big implications. | 0:22:47 | 0:22:50 | |
It's a great pleasure to welcome the 1987 Christmas Lecturer and previous | 0:22:50 | 0:22:55 | |
director of the Royal Institution, Professor Sir John Meurig Thomas. | 0:22:55 | 0:23:01 | |
APPLAUSE | 0:23:01 | 0:23:02 | |
Thank you very much. | 0:23:06 | 0:23:08 | |
Thank you. | 0:23:08 | 0:23:09 | |
Your lectures were some time ago. | 0:23:15 | 0:23:16 | |
What was the subject that you covered back then? | 0:23:16 | 0:23:19 | |
Crystals and lasers and I dealt mainly with crystalline materials. | 0:23:19 | 0:23:24 | |
Crystalline platinum in particular, not crystalline lithium. | 0:23:24 | 0:23:29 | |
Well, related to that, I've got you on for a specific reason, | 0:23:29 | 0:23:32 | |
holding a very interesting device. Tell us about what you are holding. | 0:23:32 | 0:23:35 | |
Well, this is a mobile phone manufactured in Texas in 1983. | 0:23:35 | 0:23:40 | |
It cost £4,000. | 0:23:40 | 0:23:43 | |
It's about 5lbs in weight. | 0:23:43 | 0:23:46 | |
It could allow you to speak for 30 minutes, | 0:23:46 | 0:23:49 | |
but you needed ten hours to charge it. | 0:23:49 | 0:23:54 | |
So I didn't buy one, I didn't buy one. | 0:23:54 | 0:23:56 | |
OK. So, Sir John, I think we've got some footage | 0:23:56 | 0:24:00 | |
from a previous lecture. | 0:24:00 | 0:24:01 | |
It's Professor David Pye of Queen Mary College, as it then was. | 0:24:01 | 0:24:06 | |
Find the phone under your seat there, it's ringing. | 0:24:06 | 0:24:09 | |
OK. Would you like to press the orange button please? | 0:24:09 | 0:24:13 | |
Take the call, then use it as an ordinary phone. | 0:24:13 | 0:24:16 | |
Hold it up to your ear. | 0:24:17 | 0:24:19 | |
Hello. Can you hear me on the phone? | 0:24:20 | 0:24:23 | |
-Very clearly. -Good. | 0:24:23 | 0:24:25 | |
Can you tell me your name please? | 0:24:25 | 0:24:26 | |
Charles. | 0:24:26 | 0:24:29 | |
Great. Sir John, it's been a real pleasure and I'm glad you could | 0:24:30 | 0:24:33 | |
join us to describe that particular device. | 0:24:33 | 0:24:37 | |
So thank you very much. | 0:24:37 | 0:24:38 | |
It's a delight to be here. | 0:24:38 | 0:24:40 | |
Thank you. | 0:24:40 | 0:24:41 | |
Lithium ion batteries first came on the market in the early 1990s. | 0:24:49 | 0:24:54 | |
Probably way before most of you were born, actually. | 0:24:55 | 0:24:59 | |
They've helped power a worldwide portable revolution. | 0:24:59 | 0:25:04 | |
They've changed all our lives. | 0:25:04 | 0:25:07 | |
So why are lithium ion batteries so much better at storing energy? | 0:25:07 | 0:25:11 | |
To understand that, we need to get back to chemistry, | 0:25:11 | 0:25:15 | |
which is where I like to be. | 0:25:15 | 0:25:17 | |
So lithium has the smallest atoms or ions of any metal | 0:25:17 | 0:25:23 | |
in the periodic table. | 0:25:23 | 0:25:25 | |
So this is just a lithium atom, | 0:25:25 | 0:25:29 | |
but how does it compare to another atom in the periodic table? | 0:25:29 | 0:25:33 | |
So I'm going to hand it over to a couple of people here. | 0:25:33 | 0:25:35 | |
Can you just hold those? | 0:25:35 | 0:25:37 | |
So this is sort of a relative scale. | 0:25:37 | 0:25:42 | |
You've got lithium | 0:25:42 | 0:25:44 | |
and you've got the potassium. | 0:25:44 | 0:25:47 | |
And if you can hold those, you can see quite clearly | 0:25:47 | 0:25:50 | |
that lithium is a lot smaller | 0:25:50 | 0:25:53 | |
and the more ions you can pack into a battery or into a space, | 0:25:53 | 0:25:59 | |
the more energy you can store. | 0:25:59 | 0:26:01 | |
In fact, you can cram more lithium ions, the small lithium ions, | 0:26:01 | 0:26:05 | |
into the same space than any other metal. | 0:26:05 | 0:26:09 | |
So this gives lithium batteries their high energy density. | 0:26:09 | 0:26:14 | |
Because lithium ions are so tiny, | 0:26:15 | 0:26:17 | |
it's very difficult to see them using experiment alone. | 0:26:17 | 0:26:21 | |
So, as a chemist, I'm lucky that my research can use | 0:26:22 | 0:26:27 | |
modern supercomputers to model what is happening inside batteries | 0:26:27 | 0:26:32 | |
at the atomic level. | 0:26:32 | 0:26:34 | |
In fact, at parties, | 0:26:34 | 0:26:36 | |
when I get invited, that is, | 0:26:36 | 0:26:38 | |
when people ask me what I do, I sometimes say, "I model." | 0:26:38 | 0:26:43 | |
And this is a computer model of the atomic structure of that lithium, | 0:26:44 | 0:26:50 | |
of a lithium battery material. | 0:26:50 | 0:26:52 | |
So this is a lithium cobalt oxide electrode. | 0:26:52 | 0:26:55 | |
The cobalts are in purple, the oxygens are in red. | 0:26:55 | 0:26:59 | |
We can see the lithium ions zipping through between the channels. | 0:26:59 | 0:27:03 | |
So it's a very sheet-like structure and the important stuff is happening | 0:27:03 | 0:27:09 | |
between the sheets, so we can see the lithium ion just zipping through. | 0:27:09 | 0:27:13 | |
So they just indicate very fast ion motion. | 0:27:13 | 0:27:18 | |
So when you charge up your phone tonight, | 0:27:18 | 0:27:20 | |
probably Snapchatting to late in the evening, | 0:27:20 | 0:27:25 | |
when you see those red and green symbols, they just indicate | 0:27:25 | 0:27:29 | |
that tiny lithium ions are moving through a battery material. | 0:27:29 | 0:27:33 | |
Those tiny lithium ions are moving through those sheets. | 0:27:33 | 0:27:36 | |
But as you may have seen in the news recently, | 0:27:38 | 0:27:41 | |
batteries sometimes go wrong. | 0:27:41 | 0:27:45 | |
They overheat and it's usually due to short circuiting | 0:27:45 | 0:27:48 | |
and I should stress that this is a very rare event, | 0:27:48 | 0:27:51 | |
considering the billions of cells that have been sold | 0:27:51 | 0:27:54 | |
practically every week. | 0:27:54 | 0:27:57 | |
So we've set up a demonstration and this one is so dangerous | 0:27:57 | 0:28:01 | |
that we couldn't actually do it in the lecture theatre. | 0:28:01 | 0:28:03 | |
So we're doing it outside and we've set it up on the roof. | 0:28:03 | 0:28:08 | |
So what you see there is a lithium battery pack. | 0:28:08 | 0:28:12 | |
It's within a Perspex box, and right above it | 0:28:12 | 0:28:15 | |
you can just about see a tube and at the top of the tube, | 0:28:15 | 0:28:21 | |
you will see a giant nail. | 0:28:21 | 0:28:24 | |
And it's going to go straight down into that lithium ion battery. | 0:28:24 | 0:28:28 | |
And this is a serious point, do not attempt this at home. | 0:28:28 | 0:28:33 | |
OK. It's going to be pulled by that small string there, | 0:28:33 | 0:28:36 | |
that's going to release the rod | 0:28:36 | 0:28:37 | |
and that nail's going to go straight down. | 0:28:37 | 0:28:39 | |
So I think we need a countdown here, all right? | 0:28:39 | 0:28:42 | |
Another countdown. | 0:28:42 | 0:28:44 | |
ALL: Three, two, one. | 0:28:44 | 0:28:46 | |
So what you are seeing there is the reaction right on that | 0:28:56 | 0:28:59 | |
lithium ion battery. | 0:28:59 | 0:29:00 | |
So, as you can see, that is an intense reaction, | 0:29:04 | 0:29:07 | |
just from that nail going right through that lithium ion battery. | 0:29:07 | 0:29:10 | |
So what's happening there? | 0:29:10 | 0:29:12 | |
So what's happening is that the nail connects the two electrodes | 0:29:13 | 0:29:17 | |
and short-circuits the battery, which makes it overheat. | 0:29:17 | 0:29:22 | |
And this mimics the short-circuiting caused by bad battery design. | 0:29:22 | 0:29:26 | |
But it's not the lithium that explodes. | 0:29:28 | 0:29:31 | |
It's actually something else. | 0:29:31 | 0:29:35 | |
It's the liquid electrolyte that sits between | 0:29:35 | 0:29:38 | |
the two electrodes. | 0:29:38 | 0:29:40 | |
And that electrolyte is made up of a lithium salt in a solvent, | 0:29:40 | 0:29:45 | |
and that solvent is highly flammable. | 0:29:45 | 0:29:48 | |
Get it too hot and it simply erupts out of the casing. | 0:29:48 | 0:29:52 | |
So we're going to see a demonstration of this right now. | 0:29:52 | 0:29:56 | |
Natasha, I think we're ready, so give us a demonstration. | 0:29:56 | 0:29:59 | |
Great. | 0:30:03 | 0:30:04 | |
Thank you. | 0:30:09 | 0:30:10 | |
OK, so that's a very violent reaction. | 0:30:14 | 0:30:17 | |
So this overheating is sometimes called thermal runaway. | 0:30:17 | 0:30:21 | |
Which is a very rare event. | 0:30:23 | 0:30:25 | |
Obviously, as long as you don't drive a nail through your battery | 0:30:25 | 0:30:29 | |
or phone. So, let's get back to our original question. | 0:30:29 | 0:30:33 | |
Can we power our phone for a whole year | 0:30:33 | 0:30:37 | |
without plugging in to the mains? | 0:30:37 | 0:30:39 | |
Well, we've been working very hard behind the scenes, and guess what? | 0:30:39 | 0:30:45 | |
We've done it. | 0:30:47 | 0:30:49 | |
Here it is. We've done the maths and this would definitely run your phone | 0:30:49 | 0:30:55 | |
for a whole year. Inside, as you can see, | 0:30:55 | 0:30:58 | |
are several lithium ion batteries, | 0:30:58 | 0:31:01 | |
the size of car batteries wired together. | 0:31:01 | 0:31:03 | |
I need a volunteer here. | 0:31:05 | 0:31:08 | |
Yes. Yes, front row, come on over. | 0:31:08 | 0:31:11 | |
So, this is on a sort of rucksack. | 0:31:18 | 0:31:22 | |
Oh, yes, can I take your name? | 0:31:22 | 0:31:24 | |
-Adam. -Adam, sorry. | 0:31:24 | 0:31:26 | |
Adam, well, Adam, you're going to try and lift that up. | 0:31:26 | 0:31:29 | |
So why don't you come round and give it a good pull up. | 0:31:29 | 0:31:33 | |
You're probably stronger than I am, so can you try and lift that up? | 0:31:33 | 0:31:36 | |
-This? -Yeah. | 0:31:36 | 0:31:37 | |
That is heavy, isn't it? | 0:31:38 | 0:31:39 | |
Would you like to carry that with your mobile phone? | 0:31:41 | 0:31:43 | |
-No. -Right, well, you've given that a good attempt, | 0:31:43 | 0:31:46 | |
so come over on this side here. | 0:31:46 | 0:31:48 | |
In fact, do you know how much that weighs? | 0:31:48 | 0:31:50 | |
You probably could tell - that weighs 30 kilos. | 0:31:50 | 0:31:55 | |
Actually, I can barely lift it as well. | 0:31:55 | 0:31:57 | |
So you're not going to put that very soon into your pocket, | 0:31:57 | 0:32:00 | |
unless you've got very large pockets. | 0:32:00 | 0:32:03 | |
So to make this work, we need somebody else to help out. | 0:32:03 | 0:32:07 | |
Please welcome Britain's strongest woman Andrea Thompson. | 0:32:07 | 0:32:11 | |
Thank you. | 0:32:16 | 0:32:17 | |
Thank you, Andrea, for joining us. | 0:32:21 | 0:32:23 | |
Thanks for having me. | 0:32:23 | 0:32:25 | |
You are Britain's strongest woman. | 0:32:25 | 0:32:27 | |
What did you have to do to get that accolade? | 0:32:27 | 0:32:30 | |
Well, I had to pick up 220 kilos in my hands, pull a truck, | 0:32:31 | 0:32:37 | |
a three-tonne truck | 0:32:37 | 0:32:39 | |
and lift a series of atlas stones from 80-120 kilos. | 0:32:39 | 0:32:43 | |
A three-tonne truck? | 0:32:43 | 0:32:45 | |
-Yes. -So how far did you move with that? | 0:32:45 | 0:32:48 | |
20 metres. | 0:32:48 | 0:32:49 | |
-20 metres? -Yeah. It was tough. -Oh, right! | 0:32:49 | 0:32:52 | |
Well, let's see what you can do with this. | 0:32:52 | 0:32:54 | |
As you can see, we've got some straps here, so I wonder if you | 0:32:55 | 0:32:58 | |
could pick that up and see if you can put that on your back. | 0:32:58 | 0:33:01 | |
-OK. -Let's give it a go. | 0:33:01 | 0:33:03 | |
So that's 30 kilos, remember. | 0:33:03 | 0:33:05 | |
It's a bit of a tight strap. | 0:33:10 | 0:33:11 | |
-There you are. -Thank you. | 0:33:14 | 0:33:15 | |
-Does that fit now? -That's fine. | 0:33:15 | 0:33:17 | |
Oh, yes! | 0:33:18 | 0:33:19 | |
That looks quite snug. | 0:33:20 | 0:33:22 | |
Yes! | 0:33:22 | 0:33:23 | |
That might be a solution for Andrea, | 0:33:31 | 0:33:32 | |
but I don't think it's practical for everyone else. | 0:33:32 | 0:33:35 | |
So, you can see, it's a possible solution, | 0:33:35 | 0:33:37 | |
but not quite a practical one. | 0:33:37 | 0:33:40 | |
You're going to carry that around for a whole year next to your phone. | 0:33:40 | 0:33:43 | |
Let's thank Adam, once again. | 0:33:44 | 0:33:47 | |
And we're going to thank Andrea. Thank you. Can you do us a favour? | 0:33:47 | 0:33:51 | |
-Can you take that off with you? -Of course I will. -Thank you. Thank you. | 0:33:51 | 0:33:55 | |
So can we do better? | 0:34:04 | 0:34:06 | |
Can we help our phones last longer on a single charge? | 0:34:06 | 0:34:10 | |
So we've talked about more powerful batteries, but obviously, | 0:34:11 | 0:34:15 | |
if your phone uses less, | 0:34:15 | 0:34:18 | |
then obviously it would last longer. | 0:34:18 | 0:34:20 | |
So which function on your phone uses the most energy? | 0:34:20 | 0:34:24 | |
Well, to answer this question, we need to smash open | 0:34:24 | 0:34:28 | |
someone's smartphone. | 0:34:28 | 0:34:30 | |
Actually, at this point, I would love to use my daughter's, | 0:34:33 | 0:34:36 | |
but I couldn't possibly do that. | 0:34:36 | 0:34:38 | |
So, any volunteers to have their phone smashed? | 0:34:38 | 0:34:40 | |
Yes. Give us your phone. | 0:34:40 | 0:34:43 | |
OK. Right, let's put it there. | 0:34:43 | 0:34:45 | |
So. | 0:34:45 | 0:34:46 | |
We need a countdown for this, OK. | 0:34:47 | 0:34:50 | |
So, three, two, one. | 0:34:50 | 0:34:54 | |
No, no, no. | 0:34:54 | 0:34:56 | |
No, of course I couldn't do that. | 0:34:57 | 0:34:59 | |
Don't worry, we've got our own set up here. | 0:35:01 | 0:35:04 | |
So this is obviously something again we've prepared earlier. | 0:35:04 | 0:35:08 | |
It has a voltmeter there and a typical mobile phone. | 0:35:08 | 0:35:11 | |
Mobile phones do lots of things, OK. | 0:35:13 | 0:35:15 | |
And this just actually gives an indication of the energy | 0:35:15 | 0:35:21 | |
used by the different functions | 0:35:21 | 0:35:24 | |
within that mobile phone. | 0:35:24 | 0:35:26 | |
And the numbers are really a relative number, | 0:35:26 | 0:35:30 | |
so don't worry about the units exactly, | 0:35:30 | 0:35:32 | |
but just look at the relative values. | 0:35:32 | 0:35:34 | |
So at the moment, you can see the relative values are fairly low, OK. | 0:35:34 | 0:35:40 | |
And that's the phone on idle. | 0:35:40 | 0:35:43 | |
So now... | 0:35:43 | 0:35:44 | |
..I think we're just turning it on. | 0:35:45 | 0:35:47 | |
And you can see straight away, just by turning it on, | 0:35:47 | 0:35:51 | |
the energy usage has gone up. | 0:35:51 | 0:35:54 | |
So if you look at the photo function, it whacks up. | 0:35:54 | 0:35:58 | |
Look at that. Taking photos, you can see the energy usage | 0:35:58 | 0:36:05 | |
sometimes touches numbers as high as 400. | 0:36:05 | 0:36:08 | |
And then you've got to use the internet to transmit that photo. | 0:36:08 | 0:36:15 | |
So this is the Wi-Fi. | 0:36:15 | 0:36:17 | |
So Wi-Fi drops down a bit, but still, | 0:36:17 | 0:36:20 | |
you've got relative energy usage. | 0:36:20 | 0:36:23 | |
And then lastly, I think we'll go on to Twitter and go to the | 0:36:23 | 0:36:29 | |
RI website and I think you'll see a very dodgy photo. | 0:36:29 | 0:36:35 | |
There you are. So again, | 0:36:35 | 0:36:37 | |
you can see the different functions are using different relative amounts | 0:36:37 | 0:36:41 | |
of energy. So taking photos and having your screen lit up | 0:36:41 | 0:36:45 | |
uses your battery up quickly. | 0:36:45 | 0:36:47 | |
But if you really want to save battery life, | 0:36:47 | 0:36:50 | |
then GPS is worth turning off, too. | 0:36:50 | 0:36:53 | |
Saving battery life is OK, but can only get you so far. | 0:36:55 | 0:36:59 | |
To stand a chance of powering our phone for a year, | 0:37:00 | 0:37:04 | |
we're going to need a new battery design. | 0:37:04 | 0:37:08 | |
So hundreds of research labs around the world, | 0:37:09 | 0:37:13 | |
including our research lab, | 0:37:13 | 0:37:16 | |
are searching for the next big battery discovery. | 0:37:16 | 0:37:19 | |
There are lots of new designs out there, | 0:37:19 | 0:37:23 | |
and I'd like to tell you about one of the most exciting examples, | 0:37:23 | 0:37:27 | |
actually theoretically, the best battery. | 0:37:27 | 0:37:31 | |
Can you please welcome Dr Lee Johnson | 0:37:31 | 0:37:34 | |
from Peter Bruce's group to operate this battery for me. | 0:37:34 | 0:37:37 | |
Thank you. | 0:37:41 | 0:37:42 | |
So this unusual battery uses just lithium metal reacting with oxygen | 0:37:48 | 0:37:55 | |
from the air. So it's a lithium oxygen battery. | 0:37:55 | 0:37:59 | |
This makes it very lightweight and very energy dense. | 0:37:59 | 0:38:03 | |
So what you have here, this is a vacuum chamber and inside it is | 0:38:03 | 0:38:08 | |
actually the lithium battery cell. | 0:38:08 | 0:38:10 | |
It's not powering these lights at the moment, OK. | 0:38:10 | 0:38:14 | |
The battery itself is made up of what we call a chemical sandwich. | 0:38:16 | 0:38:21 | |
So let me show you what that sandwich looks like. | 0:38:21 | 0:38:24 | |
Here it is. This is about half a gram of lithium metal, OK. | 0:38:24 | 0:38:31 | |
And that's within that very cell, only half a gram of lithium metal. | 0:38:31 | 0:38:35 | |
The other... | 0:38:36 | 0:38:37 | |
..part of that sandwich is just this kind of carbon mesh. | 0:38:39 | 0:38:43 | |
And this carbon mesh has a very high surface area, | 0:38:45 | 0:38:49 | |
and what that allows is the oxygen to react with the metal. | 0:38:49 | 0:38:53 | |
So if you let the air in, | 0:38:53 | 0:38:55 | |
we should see hopefully the lights go on from that reaction. | 0:38:55 | 0:38:59 | |
-Are you ready? -Tell us what you're going to be doing here. | 0:38:59 | 0:39:02 | |
OK, so there's a vacuum in here. And I'm going to open this valve, | 0:39:02 | 0:39:04 | |
and that's going to let the air into this chamber. | 0:39:04 | 0:39:06 | |
And hopefully what you'll see is the pressure go up here, | 0:39:06 | 0:39:10 | |
and you'll see these lights come on. | 0:39:10 | 0:39:12 | |
-So, are we ready? -OK. -Yeah. | 0:39:12 | 0:39:13 | |
OK. So you'll hear a hiss. | 0:39:13 | 0:39:15 | |
And we should see it start to light up now. | 0:39:20 | 0:39:23 | |
-OK. -So there you see, you can see it going. | 0:39:23 | 0:39:26 | |
So this is being produced by this lithium oxygen battery. | 0:39:30 | 0:39:34 | |
And that was only half a gram of lithium. | 0:39:39 | 0:39:42 | |
So this stores a high amount of chemical energy, | 0:39:42 | 0:39:46 | |
at least three times more energy than today's lithium ion batteries | 0:39:46 | 0:39:51 | |
in your mobile phones. | 0:39:51 | 0:39:53 | |
So these batteries are exciting. | 0:39:53 | 0:39:56 | |
They do need more research, | 0:39:56 | 0:39:58 | |
but they're probably at least a decade away for practical devices | 0:39:58 | 0:40:03 | |
in your phone. | 0:40:03 | 0:40:05 | |
So let's thank Dr Lee Johnson again. Thank you. | 0:40:05 | 0:40:08 | |
So, so far in this lecture, | 0:40:17 | 0:40:19 | |
we've mostly been looking into how to power our phone for a year. | 0:40:19 | 0:40:23 | |
I'm going to move away from that for a moment, | 0:40:25 | 0:40:27 | |
because I want to talk about some other ways energy storage | 0:40:27 | 0:40:31 | |
affects our lives. | 0:40:31 | 0:40:33 | |
One important area is the huge growth in renewable energy, | 0:40:33 | 0:40:38 | |
such as wind and solar. | 0:40:38 | 0:40:41 | |
Last year, the UK generated a quarter of our electricity | 0:40:42 | 0:40:46 | |
from renewables - solar, wind and wave power. | 0:40:46 | 0:40:50 | |
But what happens when the wind isn't blowing and the sun isn't shining? | 0:40:50 | 0:40:55 | |
So currently, there is no single solution. | 0:40:55 | 0:40:59 | |
Batteries will play a part, but we need something | 0:41:00 | 0:41:04 | |
on a much bigger scale. | 0:41:04 | 0:41:06 | |
There are a number of options. | 0:41:07 | 0:41:09 | |
People have tried pumping water into raised reservoirs when | 0:41:09 | 0:41:14 | |
energy's plentiful and releasing it to give us power at a later date. | 0:41:14 | 0:41:19 | |
This is sometimes called pumped hydro. | 0:41:19 | 0:41:23 | |
But there's one fascinating form of large-scale energy storage | 0:41:23 | 0:41:26 | |
I'd like to tell you about. It's called magnetic energy storage. | 0:41:26 | 0:41:31 | |
This is a strip of powerful magnets. | 0:41:32 | 0:41:36 | |
So you can see here, it forms this track round here. | 0:41:36 | 0:41:39 | |
And what we have here is some superconductors | 0:41:41 | 0:41:45 | |
in that liquid nitrogen. | 0:41:45 | 0:41:47 | |
These superconductors actually only work at very low temperatures. | 0:41:47 | 0:41:51 | |
So could you place that on this powerful strip of magnets? | 0:41:51 | 0:41:55 | |
And let's see it levitating around. | 0:41:55 | 0:41:58 | |
So let's give it another nudge there. Yes, it goes. | 0:42:01 | 0:42:04 | |
CROWD MURMURS EXCITEDLY | 0:42:04 | 0:42:05 | |
Yes. Yes, that's much better. | 0:42:05 | 0:42:07 | |
There it... Oh! | 0:42:10 | 0:42:11 | |
Yes! | 0:42:13 | 0:42:14 | |
Yes. | 0:42:18 | 0:42:20 | |
A superconductor is a material that shows powerful magnetic behaviour. | 0:42:20 | 0:42:24 | |
The reason this vehicle floats is because inside the superconductor | 0:42:24 | 0:42:29 | |
is an electric current that meets no resistance. | 0:42:29 | 0:42:34 | |
And if you make a ring out of this superconductor, | 0:42:34 | 0:42:36 | |
it forms a never-ending electrical circuit. | 0:42:36 | 0:42:40 | |
So this circuit can store large amounts of electricity to be used | 0:42:40 | 0:42:44 | |
later on. OK, so a round of applause there. | 0:42:44 | 0:42:47 | |
There's one other crucial area of our lives that better energy storage | 0:43:03 | 0:43:08 | |
could completely revolutionise - | 0:43:08 | 0:43:11 | |
the cars we drive. | 0:43:11 | 0:43:13 | |
We saw that sporty electric car at the beginning of the lecture. | 0:43:13 | 0:43:18 | |
Thanks to advances in lithium batteries, we're at the dawn | 0:43:18 | 0:43:22 | |
of the era of the electric car. | 0:43:22 | 0:43:25 | |
But they've got stiff competition. | 0:43:25 | 0:43:29 | |
We've seen that a couple of large lithium batteries could power | 0:43:31 | 0:43:35 | |
the London Eye a quarter turn. | 0:43:35 | 0:43:38 | |
So what would the same weight of petrol do? | 0:43:38 | 0:43:42 | |
So that's a quarter of a turn for the lithium ion battery. | 0:43:42 | 0:43:47 | |
How far would that petrol go? | 0:43:47 | 0:43:51 | |
So let's have a look. | 0:43:51 | 0:43:53 | |
It will go | 0:43:53 | 0:43:54 | |
three revolutions, four, 16, 18, 19, 20. | 0:43:54 | 0:43:59 | |
20 revolutions of the London Eye. | 0:43:59 | 0:44:03 | |
It stores more than 50 times the best lithium ion battery. | 0:44:03 | 0:44:07 | |
So in terms of energy, it's way, way ahead. | 0:44:07 | 0:44:12 | |
But as I'm sure you'll know, petrol has some serious problems. | 0:44:13 | 0:44:17 | |
So, a bit of chemistry here, and I am a chemist. | 0:44:18 | 0:44:21 | |
So, petrol... | 0:44:21 | 0:44:23 | |
..is made up of long chains of hydrogen and carbon, | 0:44:26 | 0:44:30 | |
which we call hydrocarbons. | 0:44:30 | 0:44:33 | |
So these are beautiful | 0:44:37 | 0:44:41 | |
molecular models of... This is octane. | 0:44:41 | 0:44:44 | |
So you can see the black are carbons, | 0:44:44 | 0:44:48 | |
the small white balls are hydrogen. | 0:44:48 | 0:44:51 | |
But there's a problem. | 0:44:51 | 0:44:53 | |
When you burn these, you get pure carbon, that black. | 0:44:54 | 0:44:59 | |
But you also get something else, something you can't see - | 0:44:59 | 0:45:02 | |
carbon dioxide. | 0:45:02 | 0:45:03 | |
And that's this feature there, | 0:45:03 | 0:45:07 | |
so that's carbon dioxide. | 0:45:07 | 0:45:09 | |
So if you take that. | 0:45:09 | 0:45:10 | |
So this is carbon dioxide. | 0:45:11 | 0:45:13 | |
So the carbon has reacted with oxygen, | 0:45:13 | 0:45:16 | |
so the reds are the oxygens and the carbon is in black. | 0:45:16 | 0:45:19 | |
But that's just the molecular model. | 0:45:19 | 0:45:21 | |
We're going to look and see how much energy they produce, | 0:45:23 | 0:45:26 | |
but also some of the pollution they may produce. | 0:45:26 | 0:45:29 | |
So we're going to burn just a bit of petrol. | 0:45:29 | 0:45:32 | |
There's a bit of petrol in that crucible, | 0:45:32 | 0:45:35 | |
and we're going to see the effect of burning that. | 0:45:35 | 0:45:38 | |
OK. So there's some petrol burning. | 0:45:41 | 0:45:43 | |
And what happens when you just put a simple tile over it? | 0:45:44 | 0:45:49 | |
Obviously do not do this at home. | 0:45:54 | 0:45:56 | |
And you can see very quickly how much carbon soot's been produced. | 0:45:56 | 0:46:02 | |
OK. | 0:46:04 | 0:46:05 | |
Thanks. Thanks, Natasha. | 0:46:07 | 0:46:09 | |
So that's the problem with today's cars - | 0:46:10 | 0:46:14 | |
petrol-powered road transport produces a lot of air pollution, | 0:46:14 | 0:46:18 | |
and going electric would be much better for air quality, | 0:46:18 | 0:46:22 | |
and better for the planet. | 0:46:22 | 0:46:23 | |
But first we need to solve a big issue with electric cars - | 0:46:23 | 0:46:27 | |
can we go a long distance without charging? | 0:46:27 | 0:46:31 | |
Some people call this range anxiety. | 0:46:31 | 0:46:34 | |
Did you know, though, that most car journeys in the UK are less | 0:46:35 | 0:46:40 | |
than 30 miles? But obviously it's nice to know that we can go further | 0:46:40 | 0:46:44 | |
if we need to. | 0:46:44 | 0:46:46 | |
And I've always wanted to celebrate New Year in Scotland, | 0:46:46 | 0:46:51 | |
so I wanted to find out if I could drive an electric car from | 0:46:51 | 0:46:55 | |
the Royal Institution here | 0:46:55 | 0:46:57 | |
to Edinburgh on one charge. | 0:46:57 | 0:47:00 | |
So we can see here, | 0:47:01 | 0:47:04 | |
hopefully you can, if you're not geographically challenged, | 0:47:04 | 0:47:07 | |
that here is London. | 0:47:07 | 0:47:09 | |
And to get to Edinburgh, you'd follow the A1 | 0:47:09 | 0:47:12 | |
right up this path here. | 0:47:12 | 0:47:15 | |
So we want to look at different types of electric vehicle | 0:47:16 | 0:47:21 | |
and see how far we could go. | 0:47:21 | 0:47:22 | |
So I need a volunteer to help with this. | 0:47:22 | 0:47:25 | |
So I should get somebody from there, do you want to come down? | 0:47:25 | 0:47:28 | |
Great. | 0:47:28 | 0:47:29 | |
OK. So can I take your name? | 0:47:34 | 0:47:35 | |
-Sam. -Sam, good. Could you come on this side here? | 0:47:35 | 0:47:39 | |
So we've got some different vehicles and I'm going to pass them to you. | 0:47:39 | 0:47:43 | |
Right, so first of all, we've got an electric golf cart. | 0:47:43 | 0:47:50 | |
OK. So what I'd like you to do, you're going to start there. | 0:47:50 | 0:47:54 | |
If you could just gently go up the A1 and when you feel a bit of | 0:47:54 | 0:47:58 | |
magnetic pull, just stop there, OK. | 0:47:58 | 0:48:01 | |
Let's go along there. Yes. | 0:48:01 | 0:48:03 | |
So the second vehicle, the G-Wiz. | 0:48:03 | 0:48:06 | |
Right. That's a G-Wiz vehicle, | 0:48:08 | 0:48:10 | |
that electric vehicle. | 0:48:10 | 0:48:12 | |
Right. See if you can actually feel some magnetic tension again. | 0:48:12 | 0:48:16 | |
There. Does it feel there? Yeah. | 0:48:16 | 0:48:18 | |
That's it. Actually, it doesn't go much further. | 0:48:18 | 0:48:21 | |
That G-Wiz car goes only about 50 miles outside London. | 0:48:21 | 0:48:25 | |
So let's go to the third vehicle. | 0:48:25 | 0:48:27 | |
And this is... | 0:48:28 | 0:48:29 | |
..a Nissan Leaf. This is an all-electric Nissan Leaf. | 0:48:31 | 0:48:34 | |
So if you can go along the A1. | 0:48:34 | 0:48:35 | |
About there. So that's actually about 124 miles outside London. | 0:48:36 | 0:48:41 | |
OK. So there are some actual London buses that are electric powered. | 0:48:41 | 0:48:46 | |
OK, let's have a go. | 0:48:46 | 0:48:47 | |
Let's do up from there and let's see how far you can get. | 0:48:47 | 0:48:51 | |
Is it feeling...? Around there. That's a good one. | 0:48:52 | 0:48:54 | |
So that is about 180 miles, | 0:48:54 | 0:48:56 | |
just a bit further than the Nissan Leaf. | 0:48:56 | 0:48:58 | |
The last one, this is the latest Tesla Model S. | 0:48:58 | 0:49:03 | |
OK. And let's see how far that goes. | 0:49:03 | 0:49:07 | |
So you can start from the London bus, let's see. | 0:49:07 | 0:49:10 | |
Gently go up there. | 0:49:10 | 0:49:11 | |
About there. It doesn't quite get to Edinburgh. | 0:49:11 | 0:49:14 | |
In fact, it's gone just over 300 miles from London. | 0:49:14 | 0:49:19 | |
So thank you again. Thank you. | 0:49:19 | 0:49:21 | |
Thank you. | 0:49:21 | 0:49:22 | |
So as we've seen, I'm not going to get to Edinburgh on one charge. | 0:49:26 | 0:49:31 | |
Petrol cars still have the edge on range. | 0:49:31 | 0:49:35 | |
But batteries are improving, thanks to worldwide research efforts. | 0:49:35 | 0:49:40 | |
So one way electric cars are seriously competing | 0:49:40 | 0:49:43 | |
is in performance. | 0:49:43 | 0:49:45 | |
And if you love fast cars like that sporty electric car I arrived in, | 0:49:45 | 0:49:50 | |
going electric might not be as bad as you think. | 0:49:50 | 0:49:53 | |
I asked the 2014 Christmas Lecturer, Professor Danielle George, | 0:49:53 | 0:50:00 | |
to put this to the test. | 0:50:00 | 0:50:02 | |
Hi, Saiful. Hi, everyone. | 0:50:02 | 0:50:04 | |
I'm here at a closed-off racetrack with two very exciting cars. | 0:50:04 | 0:50:09 | |
One of them is a petrol-powered supercar, | 0:50:09 | 0:50:12 | |
the Bentley Continental Titan, | 0:50:12 | 0:50:14 | |
which has been souped-up to within an inch of its life. | 0:50:14 | 0:50:17 | |
The other is an electric car, the Tesla Model S, | 0:50:17 | 0:50:21 | |
which looks a bit like a posh saloon. | 0:50:21 | 0:50:23 | |
But I'm going to be putting these two cars to the test to see | 0:50:23 | 0:50:26 | |
which one reaches 60mph the quickest. | 0:50:26 | 0:50:29 | |
Very, very exciting. | 0:50:33 | 0:50:34 | |
Three... | 0:50:46 | 0:50:47 | |
ENGINE REVS | 0:50:47 | 0:50:48 | |
Two, one. | 0:50:48 | 0:50:50 | |
HORN BLOWS | 0:50:50 | 0:50:51 | |
Wow! | 0:50:51 | 0:50:53 | |
Oh, my Lord! | 0:50:53 | 0:50:54 | |
Good grief! | 0:51:03 | 0:51:04 | |
That is amazing! | 0:51:06 | 0:51:09 | |
Oh. I'm still shaking! | 0:51:09 | 0:51:11 | |
It is seriously like being on some sort of roller-coaster. | 0:51:14 | 0:51:18 | |
It is so fast, and so quiet. | 0:51:18 | 0:51:20 | |
And I definitely left the Bentley Continental for dust. | 0:51:23 | 0:51:28 | |
Now, an all-electric car similar to this actually holds the record | 0:51:28 | 0:51:32 | |
for the fastest 0-60 time, and there's a reason for that. | 0:51:32 | 0:51:36 | |
A petrol car uses gears, | 0:51:37 | 0:51:40 | |
and so as we increase our speed, | 0:51:40 | 0:51:42 | |
we need to increase the gear that we're using. | 0:51:42 | 0:51:44 | |
And you can really see this on this graph here. | 0:51:44 | 0:51:46 | |
So what we have are both cars plotted here, time and speed. | 0:51:46 | 0:51:50 | |
The red is the electric car, and the black is the petrol car. | 0:51:50 | 0:51:54 | |
And you can see the speed and then the gear change here, | 0:51:54 | 0:51:59 | |
and then the increase in speed again after the gear has changed. | 0:51:59 | 0:52:02 | |
But with an all electric car, | 0:52:02 | 0:52:04 | |
we get peak performance from that electric motor as soon as our foot | 0:52:04 | 0:52:08 | |
hits that pedal. So there's no need for gears. | 0:52:08 | 0:52:11 | |
And the result is one mean, green speed machine. | 0:52:12 | 0:52:17 | |
And this is all possible thanks to better batteries. | 0:52:17 | 0:52:20 | |
Yes. | 0:52:21 | 0:52:22 | |
Thank you, Danielle. I think we'll be seeing a lot more electric cars | 0:52:31 | 0:52:35 | |
on our roads in the future, but maybe not going as fast | 0:52:35 | 0:52:38 | |
as that one, obviously. | 0:52:38 | 0:52:41 | |
For the moment, we're still stuck on petrol. | 0:52:41 | 0:52:44 | |
Is there anything that can beat it in terms of energy density? | 0:52:44 | 0:52:48 | |
Here are our lithium and potassium atoms from earlier. | 0:52:48 | 0:52:52 | |
And this is... I think it's nice to use a couple of volunteers. | 0:52:52 | 0:52:58 | |
If you hold on to those. | 0:52:58 | 0:53:00 | |
So I showed you... Just remind you, that's potassium and that's lithium, | 0:53:00 | 0:53:04 | |
and just to show their relative sizes. | 0:53:04 | 0:53:06 | |
Obviously, that's not the real size of their atoms. | 0:53:06 | 0:53:10 | |
But there's an even smaller atom we can use. | 0:53:10 | 0:53:14 | |
Hydrogen. | 0:53:15 | 0:53:16 | |
Just a single proton. | 0:53:16 | 0:53:18 | |
So I might as well put it right there, so if you just hold that. | 0:53:18 | 0:53:23 | |
So if you see the relative sizes, | 0:53:23 | 0:53:25 | |
this is to scale. | 0:53:25 | 0:53:27 | |
Hydrogen is five times smaller than lithium. | 0:53:27 | 0:53:31 | |
In fact, hydrogen is the smallest and lightest element | 0:53:31 | 0:53:34 | |
in the periodic table. | 0:53:34 | 0:53:36 | |
By weight, hydrogen is the most energy-dense fuel. | 0:53:36 | 0:53:41 | |
I think it's London Eye time again, to see how they compare. | 0:53:41 | 0:53:46 | |
So if you remember... | 0:53:46 | 0:53:47 | |
..30kg of lithium battery turned it a quarter, OK. | 0:53:50 | 0:53:56 | |
The same weight of petrol turned it... | 0:53:56 | 0:53:59 | |
..20 times. | 0:54:00 | 0:54:02 | |
This is the same weight of hydrogen fuel as a liquid. | 0:54:02 | 0:54:07 | |
Let's have a look. | 0:54:07 | 0:54:08 | |
Starts off 20, past 30, past 40. | 0:54:10 | 0:54:15 | |
62 revolutions. | 0:54:15 | 0:54:18 | |
It would power it for three whole days. | 0:54:18 | 0:54:22 | |
There's no doubt hydrogen contains a huge amount of energy, | 0:54:22 | 0:54:27 | |
and I can show you this with another simple demonstration - | 0:54:27 | 0:54:31 | |
a balloon full of hydrogen. | 0:54:31 | 0:54:34 | |
But this demo needs hands over your ears. | 0:54:36 | 0:54:40 | |
OK. | 0:54:43 | 0:54:44 | |
Whoa! Go on, yes! | 0:54:49 | 0:54:52 | |
Yes! | 0:54:52 | 0:54:53 | |
Right, so can we harness the energy from this powerful chemical reaction | 0:54:57 | 0:55:02 | |
more efficiently? | 0:55:02 | 0:55:03 | |
Yes, we can. | 0:55:04 | 0:55:06 | |
Hydrogen is used in things called fuel cells, | 0:55:06 | 0:55:09 | |
that are actually being used to power several London buses | 0:55:09 | 0:55:12 | |
right now. So can I use this super fuel to power my phone? | 0:55:12 | 0:55:16 | |
OK. This is a commercial fuel cell, it's a tiny one, | 0:55:17 | 0:55:22 | |
but you can't quite see inside it. | 0:55:22 | 0:55:24 | |
So we've got a demonstration fuel cell to show how it works | 0:55:24 | 0:55:28 | |
in this Perspex device here. | 0:55:28 | 0:55:31 | |
So what we have here is the oxygen | 0:55:31 | 0:55:34 | |
and the hydrogen. If they react within this fuel cell, | 0:55:34 | 0:55:38 | |
they can produce energy. | 0:55:38 | 0:55:39 | |
Now that can be shown easily by this fan here. | 0:55:39 | 0:55:42 | |
There you are. | 0:55:44 | 0:55:45 | |
A fuel cell is very similar to a battery - | 0:55:50 | 0:55:52 | |
it has two electrodes and an electrolyte. | 0:55:52 | 0:55:55 | |
But there's a big, big difference - | 0:55:55 | 0:55:57 | |
the battery is self-contained. | 0:55:57 | 0:56:00 | |
A fuel cell needs to be fed with hydrogen as a fuel. | 0:56:00 | 0:56:04 | |
So let me drink a typical fuel cell by-product. | 0:56:04 | 0:56:08 | |
It's just water. | 0:56:13 | 0:56:14 | |
So you can't get any cleaner than that. | 0:56:14 | 0:56:16 | |
But can it power my phone? | 0:56:18 | 0:56:21 | |
Shall we plug our phone into our working fuel cell? | 0:56:21 | 0:56:25 | |
OK, so this is a typical phone. | 0:56:25 | 0:56:30 | |
So let's turn on the device. | 0:56:30 | 0:56:32 | |
Hopefully you can now see the charging. | 0:56:35 | 0:56:38 | |
So this could power our phone for a whole year without plugging | 0:56:38 | 0:56:43 | |
in to the mains, but we still need to top it up with hydrogen. | 0:56:43 | 0:56:48 | |
Sadly, hydrogen is not the answer to all our energy problems, not yet. | 0:56:48 | 0:56:53 | |
We have to store it at a temperature of minus 250 degrees Celsius | 0:56:53 | 0:56:58 | |
to keep it a liquid. | 0:56:58 | 0:57:00 | |
This means that hydrogen is costly to store, | 0:57:00 | 0:57:03 | |
takes a lot of energy to produce, and has safety issues. | 0:57:03 | 0:57:08 | |
Finding better ways to store energy is still a vital challenge. | 0:57:08 | 0:57:12 | |
In these lectures, | 0:57:14 | 0:57:15 | |
we've celebrated the 80th anniversary | 0:57:15 | 0:57:18 | |
with Christmas lecturers past. | 0:57:18 | 0:57:20 | |
We've celebrated energy in all its different forms, | 0:57:20 | 0:57:23 | |
and broken a world record. | 0:57:23 | 0:57:27 | |
I've got one final energetic celebration - | 0:57:27 | 0:57:31 | |
I want to go out with a big bang. | 0:57:31 | 0:57:33 | |
Hands over your ears, and goggles on! | 0:57:33 | 0:57:36 | |
We're at the dawn of a new era in clean energy. | 0:58:00 | 0:58:04 | |
The next chapter of fuelling the future is for all of you to write. | 0:58:04 | 0:58:09 | |
So go out and charge ahead. | 0:58:09 | 0:58:12 | |
Thank you, and good night! | 0:58:12 | 0:58:13 | |
Thank you. | 0:58:16 | 0:58:17 |