Mass and Moles Precision: The Measure of All Things


Mass and Moles

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On the morning of the 14th June, 1940,

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several German tank divisions rumbled

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through the streets of Paris.

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The impossible had happened.

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Germany had invaded and France had fallen.

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'But there was one building on the outskirts of Paris that

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'the Nazis never occupied.

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'This chateau has the same status as an independent territory.

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'Its contents are so closely guarded,

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'I have to hand over my passport to gain access.

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'Today, an eminent group of scientists have gathered

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'from all over the world to witness a very special event.

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'Security is tight, with key holders arriving

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'from three different countries.

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'The vault holds one of the most important artefacts in our world.'

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This is a real piece of measurement history.

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Well, I suppose it's not really history at all...

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This is the kilo.

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'Under three layers of protective glass is the kilogram master

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'known as Le Grand K.

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'It's the weight on which all weights have been based since 1889.

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'Its importance is so great that neither the Nazis nor

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'the liberating American forces dared set foot inside here.

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'And the reason we're here today?

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'Well, just to check it's still here.

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'But there's a problem.

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'Tests have revealed that Le Grand K, this scientific celebrity,

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'is losing weight, creating a crisis in the scientific world.

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'It's losing approximately 20 billionths of a gram every year.

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'But why on earth should such a tiny change matter so much?'

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I'm on a journey to investigate the world of measurement,

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and to see how our drive for precision

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has really changed the course of history.

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'Today, we can describe the chaos

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'and complexity of the universe with just seven fundamental units,

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'the building blocks of modern science.

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'And science is obsessed with defining these units

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'with ever-greater precision.

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'In this series, I want to understand why such extreme

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'levels of precision are so important,

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'how we define these units,

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'and how through history each step forward has unleashed

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'a technological revolution.

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'In this programme, we'll explore why being able to measure weight

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'is so important.

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'And how the race to replace the ageing Grand K

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'might hold the key to a new way of understanding our world.'

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This is the story of how we mastered weight.

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"How much do I have?" is a question that has driven trade

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and commerce since the dawn of civilisation.

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And today, weights are still central to all our lives.

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The reason we're so reliant on weights and scales

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is in part down to our own inability to accurately gauge weight.

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We tend to believe our eyes, rather than trusting

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the weight in our hands.

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'And I've come to London's Borough Market to prove the point.'

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Excuse me - wonder whether I could get you to take part

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-in a little experiment?

-Of course, yes.

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So, I've got a series of weights here which I've put in order

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of height and what I'd like you to do is to place

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the heaviest weight here, and the lightest one at your end.

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Have a go. See which one you think is the heaviest.

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That's...

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This little guy, that's the heaviest? OK.

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What about the next heaviest?

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I think this one...that's the lightest.

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-The lightest of all?

-I think...

-OK!

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The really surprising thing is that the one you've put at this end,

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which you think is the lightest, is in fact the heaviest!

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So you thought this one here was the heaviest.

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OK, I'm going to give you both these in your hand - this one is

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actually heavier than that one. Do you believe me?

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Well, it doesn't feel like that.

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No, it doesn't, but let's use the scales.

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So I am going to weigh the one that you thought was the lightest,

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so that comes out about 424 grams.

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OK, let's put your one on.

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You think this one is heavier. It's only 345 grams!

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Isn't that extraordinary? So, even with that knowledge, now try

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and weigh them again, which one is heavier...

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-This one.

-I know! And that's why we need a set of weights

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because we're so bad at perception.

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'Like any good scientist, I carried on with the testing.'

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How's that possible?

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'And my random shoppers, to a man and a woman,

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'all chose the same two weights -

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'and they all chose wrong.'

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OK. Wow!

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Seeing if something is big or small massively

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skews our perception of how heavy it is.

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It is a problem our ancestors

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started first grappling with more than 5,000 years ago.

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Our earliest evidence comes from the Middle East and was driven

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by the emergence of the first cities in Mesopotamia around 3,000 BC.

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As populations grew,

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a way of fairly trading goods was urgently needed.

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People demanded a system of weight that everyone could trust.

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Taking their inspiration from nature, they used grain.

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Uniform in size and shape, grain was available to all.

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The world had its first weights.

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Using simple beam balances, which we continue to use today,

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we started to trade goods based on their weight in grains.

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It wasn't perfect, but with grains varying so little in weight,

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the system worked.

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It made the movement and sale of goods possible,

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enabling humans to live together in bigger cities

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and allowing the first economies to grow.

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Empires were no longer being built solely by armies.

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They were being built by trade.

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As commerce developed across the ancient world,

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a faster means of weighing produce was needed.

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After all, if I wanted to buy something that weighed

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700 grains of barley,

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I don't want to have to count out 700 grains each time.

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So, gradually, a standardised system of weights began to emerge.

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First the Mesopotamians, then the Ancient Egyptians developed

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stones and things made out of metals

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and brass in order to represent different weights of grain.

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It was such an efficient system that it began to be copied

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across the civilised world. So here we have standard

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weights from China.

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These hexagons are standard weights used in Sudan.

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And the amazing thing is that, despite all of these

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different weights and measures, they were all related back

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to the weight of a grain,

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because everyone trusted how much a grain would weigh.

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'By Roman times, millions of tonnes of produce were being

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'traded around the world every day.'

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The ability to compare the weights

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or masses of two different kinds of goods

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so that you could work out how to exchange between them,

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that's the key to economic success.

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And so it's the demand for economic comparison that drives weight

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standardisation throughout history.

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By the end of the 13th century, the world had hundreds of different

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weights, and nearly all were based on a fixed number of grains.

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In England, we'd inherited the pound from the Roman Empire.

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It was initially made up of 12 ounces,

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which were equivalent to 437 grains of barley.

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But the problem all rulers faced

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was how to keep weight standardised across a nation.

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It was considered such a big issue that even the Magna Carta,

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the most celebrated legal document in English history,

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tried to deal with it.

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"Let there be one measure of wine throughout our whole realm,

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"and one measure of ale and one measure of corn."

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It all sounded great in theory, but in practice,

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it was virtually impossible to enforce.

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Cheating was such a big problem

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regular trials were held to check merchants' weights and measures.

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Any found to be wrong were immediately destroyed.

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Accurate scales were the only way cheats could be exposed.

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Accuracy was power.

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Scales were not only a great measuring device.

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They also came to symbolise fairness, power,

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the very legal system itself.

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From Ancient Egypt's Feather of Truth to the paintings

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of the great Dutch Masters, scales have featured throughout history.

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As it was written in the Bible, "By weight, measure and number,

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"God made all things."

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Measurement has always been associated in culture with justice

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and law and crime. Because what it does is to establish the equivalence

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between two things that you otherwise could not compare.

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That's what justice means,

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so it's no coincidence that the figure of Justice is shown

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carrying scales, carrying balance pans.

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And for centuries, when you made a weight measurement, you had to

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show your customers what you were doing - partly to avoid

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the possibility of deceit, but also to show how just you were -

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to be just, was precisely to use balance.

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So, with all this moral weightiness flying around, the punishment

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for using false measures could be severe.

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In 1772 BC, the Code of Hammurabi was introduced in Babylonian law,

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which said that any taverner using false weights

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could be served up with a death penalty.

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And in the 18th century, bankers caught cheating

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would have to stand in pillory, and brewers in the dung cart.

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But despite the importance we placed on weight

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and getting it right, it took one remarkable Englishman

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to realise the measurement of weight has a fundamental problem.

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It was the great Sir Isaac Newton who first realised that

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weight changes depending on where and when you are measuring it.

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It was 1665, and Britain was gripped by the Plague,

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so Newton decided to flee his college in Cambridge and

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he came to the safety of his country retreat here at Woolsthorpe Manor.

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And here is the famous apple tree that inspired his observations.

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So much has been written about this apple tree, it really has become

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a symbol for the turning point in our understanding of the universe.

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Newton's eureka moment was witnessed by a friend.

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"After dinner, the weather being warm,

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"we went into the garden and drank tea, under the shade

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"of some apple trees.

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"The notion of gravitation came into his mind.

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"Why should that apple always descend perpendicularly

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"to the ground?"

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Newton realised there must be a force acting on that apple,

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pulling it to the ground, otherwise why wouldn't it just

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float in the air, or move sideways or go upwards?

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He named that force "gravity", after the Latin word

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"gravitas" for heaviness.

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'Newton's law of gravity was to completely change the way

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'we think about weight.'

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We finally understood the subtle but vital difference between weight

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and mass, and it paved the way for modern measurement.

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Now, to show how important Newton's discovery was,

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I've got a piece of metal here

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and an incredibly sensitive set of scales.

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Now, the scales say that this piece of metal weighs 368.7025/4.

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It's kind of flickering between the two, it's so sensitive.

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Now, let's take this piece of metal to the top of this block of flats

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and see how much it weighs up there.

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Now, up here, the metal weighs 368.6 9 grams,

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so I seem to have lost ten milligrams.

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But of course the mass hasn't changed,

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what's changed is the gravity.

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I've got less gravity up here

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than I have got down at the bottom of the block of flats.

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Simply put, mass is measuring

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the amount of stuff there is inside here,

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and that doesn't change whether I'm at sea level or out in space.

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But the weight does.

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In one simple equation,

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Newton's genius revolutionised how we thought about weight and mass.

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'But it would take a real revolution in France to finally create

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the measure of mass that we all use today - the kilogram.

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By the middle of the 18th century, weight measurement,

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like length, was in a total mess and nobody had it worse than the French.

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People were supposed to use the King's measures

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for pounds and ounces.

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But, in reality, every village and town had their own system,

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all slightly different.

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Disputes and arguments were so commonplace that the village took

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to chaining the weights and measures to the wall of the local church.

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Trade was painfully slow and open to corruption,

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and no-one could agree on whose weight was right.

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A new international system of measurement was urgently needed.

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Letters flew between the powers of Europe.

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"Too long have Great Britain and France been at variance

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"with each other, for empty honour or guilty interests.

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"It is time that two free nations should unite their exertions

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"for the promotion of a discovery that must be useful to mankind."

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On the eve of the French Revolution, the great and good

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of the French scientific community approached the doomed Louis XVI for

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permission to create a new system of length, mass and volume measurement.

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'The greatest minds of the day gathered here at the prestigious

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'Academy of Sciences in Paris to brainstorm a solution.

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'They decided to base their new system on something universal

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'and unchanging - the Earth.'

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It was the birth of metrication.

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The first unit they fixed was the metre,

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basing it on one ten millionth of the distance

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between the North Pole and the Equator.

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The next was the kilogram, and the task was given to the

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father of modern chemistry, Antoine Laurent Lavoisier.

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By day, he was a wealthy tax collector. By night,

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he was the greatest chemist in the land.

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The French visionaries behind the metric system

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wanted all the new measurements to be linked,

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so they came up with an elegant solution.

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The new kilogram was to be equal to the weight of one perfect

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cubic decimetre of water...

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a litre.

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The idea was very simple.

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Anybody with a metre ruler and some water could create their own kilo.

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But making a kilo based on the weight of a cubic decimetre

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of water turned out to be much more difficult than they thought.

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Now, I've got two perfect decimetres of water here.

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The trouble is, these don't weigh the same amount.

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The colder water weighs 998 grams, whilst the hotter water

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is 957 grams.

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'Because the hotter water is, the less dense it is.'

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And that's the trouble, the weight depends on the temperature.

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Not only that, it will depend on what impurities are inside the

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water, what the atmospheric pressure is, how far I am above sea level.

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There's a real problem with trying to define the kilo

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based on the weight of water.

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Lavoisier came close to solving the problem of how to accurately

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weigh water.

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But his brilliant career met an abrupt end

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at the hands of the guillotine on the 8th May 1794.

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His tax-collecting day job was his downfall.

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Next to take up the kilo challenge were scientists

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Louis Lefevre-Gineau and Giovanni Fabbronni.

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Four years later, they finally perfected how to measure

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a cubit decimetre of distilled water.

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A master metal kilogram could finally be cast.

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And on the 22nd June, 1799,

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they presented their prototype kilogram to the nation.

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Called the "kilogram des archives",

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it was made out of the new wonder metal, platinum.

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Soon, kilogram clones, as well as copies of the metre bar,

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were being sent to villages and towns across the nation

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to bring uniformity to the French Empire.

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Their vision was brilliant.

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But there was a flaw.

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The trouble was that pure platinum, although resistant to air and water,

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is actually rather soft and prone to damage.

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And that meant bits were easily knocked off,

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gradually rendering the hundreds of cloned kilos inaccurate.

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'The Academy's grand idea was slowly being eroded.

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'It would take nearly 70 years to realise a new,

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'more stable master kilo. And then a set of clones would be needed.'

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London metallurgists Johnson Matthey were given the order to

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produce 250 kilograms of platinum mixed with strength-giving iridium.

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It was a big order, worth £2.2 million at today's prices.

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The man in charge of production, George Mathey,

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the world's leading expert in casting platinum, offered to

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make the kilos at his state-of-the-art furnaces

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at Hatton Garden.

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But French pride intervened, insisting it happened here,

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at the Conservatoire in Paris.

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It was a disaster. The platinum got contaminated by iron,

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rendering the whole consignment useless.

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It was a huge embarrassment, both for French pride and their pockets.

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'But it wasn't the death of the kilo, or the metric system.

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'With international trade booming, the benefits of having one

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'common measurement system were clear for all to see.

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'And in 1875, diplomats from 17 countries met here in Paris

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'and agreed to formally adopt the metric system.'

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With great zeal, a new kilogram master was commissioned.

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The order once again went to Johnson Matthey,

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and this time George Matthey was finally allowed

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to cast the most accurate platinum and iridium kilo ever made.

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Christened "Le Grand K", it was consigned to a specially-made vault

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at a newly established international centre of measurement outside Paris.

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And here it is - the Bureau Internationale des Poids et Mesures.

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The BIPM. In English,

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the International Bureau of Weights and Measures.

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And this is really international territory.

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It's kind of a mark of how important measurement

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is to the world that we've created a UN of measurement.

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'From the beginning, the BIPM's mission was to make sure

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'measurements were consistent throughout the world.

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'This is the building that was once home

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'to all the world's master measurements.'

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Today, most have been retired,

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replaced by new definitions based on the universal and unchanging

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laws of nature, like the speed of light...

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..and the movement of atoms.

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Le Grand K is in fact the only artefact that is still in use.

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A measurement dinosaur.

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Today, here at the BIPM, they're still making clones of that Grand K.

0:26:060:26:11

Fabrice here is polishing this until it exactly matches

0:26:110:26:14

the mass of the Grand K sitting in the vault downstairs.

0:26:140:26:19

'Over half the countries in the world have one of these clones.'

0:26:200:26:23

The next one he's working on is clone number 103 -

0:26:230:26:27

that's going to go to... Well, we're not actually allowed to know

0:26:270:26:30

where it's going to go.

0:26:300:26:32

'Without Le Grand K, our entire global system of mass

0:26:320:26:36

'and weight measurement would crumble.'

0:26:360:26:38

Unfortunately, "crumble" is a little bit of a touchy word

0:26:400:26:44

inside this building because that's what's happening to Le Grand K.

0:26:440:26:47

I mean, it's not literally crumbling,

0:26:470:26:49

but despite the kid-glove treatment it's received

0:26:490:26:52

over the last 150 years, it's believed that it has changed

0:26:520:26:55

by the equivalent of one grain of sand during its lifetime.

0:26:550:26:59

'And that's bad news,

0:26:590:27:02

'because it no longer matches the weight of the world's clones.

0:27:020:27:06

'A new way to define mass is urgently needed.'

0:27:060:27:10

Now the race is on to replace the definition of the kilo with

0:27:120:27:16

something more fitting for the 21st century -

0:27:160:27:19

something based on a universal constant that can be measured

0:27:190:27:22

wherever you are in the universe.

0:27:220:27:24

We've done it for length - that's now tied to the speed of light...

0:27:270:27:30

..for time - that's related to the movement of electrons in the atom.

0:27:320:27:35

Now we want to do it for the kilo.

0:27:370:27:39

It's a head-to-head race between two international teams.

0:27:420:27:46

Each one taking a radically different approach to solving

0:27:480:27:51

the kilo crisis.

0:27:510:27:53

In America, Team Watt Balance are combining the power

0:27:540:27:58

of electricity with scales whose principles date back 5,000 years.

0:27:580:28:04

Their dream? To redefine the kilo based on energy.

0:28:060:28:10

6,000 kilometres away in Germany, Team Silicon Sphere

0:28:120:28:16

are trying to count every single atom in a perfect ball of silicon.

0:28:160:28:21

It's an immense task - like covering the Earth in sand

0:28:250:28:28

and trying to count every single granule.

0:28:280:28:31

As the best minds in measurement science fight it out,

0:28:330:28:38

Le Grand K's long and illustrious career could soon be over,

0:28:380:28:42

but its legacy has been staggering.

0:28:420:28:45

From the moment it was adopted, the movement and sale of goods

0:28:530:28:57

became much easier and more efficient.

0:28:570:29:00

The scientific community jumped on the new metric system,

0:29:020:29:06

loving its simplicity and the ease they could split or multiply

0:29:060:29:10

the metre and the kilogram by ten.

0:29:100:29:12

But from the very beginning of its life in the 18th century,

0:29:200:29:23

the public remained less convinced.

0:29:230:29:25

People were just not interested in revolutionising their everyday

0:29:280:29:32

life - what they did when they went shopping, how they exchanged

0:29:320:29:36

and bought - in the name of revolutionary purity.

0:29:360:29:40

The kilo continues to divide opinion.

0:29:420:29:44

In the UK, it was only adopted in the 1960s

0:29:480:29:51

and its arrival was met with outright hostility.

0:29:510:29:55

All we ask is the freedom of choice to record in the native

0:29:570:30:01

and still legal measures of this country instead of these

0:30:010:30:05

cock-eyed kilograms, which make no sense at all.

0:30:050:30:07

But despite the opposition, today all but three nations -

0:30:070:30:12

the United States, Liberia and Myanmar -

0:30:120:30:15

have embraced the kilo and the metric system.

0:30:150:30:17

While the world was moving towards a unified weight measurement

0:30:290:30:33

system, the actual technology of weighing was now lagging behind.

0:30:330:30:37

Variations on ancient Mesopotamian and Egyptian beam balances

0:30:400:30:43

remained our scales of choice right up to the 19th century.

0:30:430:30:48

The problem was they took so long to use.

0:30:500:30:54

In the UK, weighing was made much worse by the Turnpike Act of 1752.

0:30:550:31:01

Eager to tax the movement of goods, the government ordered all towns

0:31:030:31:08

to "erect a crane machine or engine for the weighing carts and wagons."

0:31:080:31:14

At each location, carts had to be unloaded, weighed,

0:31:150:31:19

reloaded and weighed once again.

0:31:190:31:22

And to the add to the daily misery, every key road demanded tolls, too.

0:31:240:31:29

All payable on the weight you were carrying.

0:31:290:31:32

With the birth of the Industrial Revolution, things had to change.

0:31:350:31:39

Factories to forges now needed raw materials

0:31:390:31:43

in unprecedented quantities.

0:31:430:31:46

And they had to be weighed, bought and transported

0:31:460:31:48

with ever-increasing speed and precision.

0:31:480:31:52

A faster, more efficient means of weighing was desperately needed.

0:31:570:32:02

The solution was the weighbridge.

0:32:030:32:06

A technological triumph, the weighbridge,

0:32:090:32:11

with its balance scale hidden beneath the floor, would play

0:32:110:32:15

a key role in driving our industrial revolution onwards.

0:32:150:32:19

Now, loads could be weighed in seconds as they rolled on

0:32:220:32:25

and off the bridge.

0:32:250:32:27

But it would take electricity to drive the next big

0:32:290:32:32

breakthrough in weighing.

0:32:320:32:35

Inventor Charles Wheatstone

0:32:380:32:40

championed the use of electricity in the 1840s.

0:32:400:32:44

Experimenting with simple electrical circuits,

0:32:460:32:49

he devised a way of measuring electrical resistance.

0:32:490:32:53

But it wasn't until a century later that people realised this

0:32:530:32:57

very same technology could be used to measure weight.

0:32:570:33:01

Today, the need for speedy mass measurement drives our world.

0:33:080:33:12

This train is delivering coal to Rugeley Power Station,

0:33:170:33:21

and, as it runs over the track, it's being weighed by load cells,

0:33:210:33:25

which are underneath the track.

0:33:250:33:26

And if we come in here, we can see how much we've weighed so far.

0:33:260:33:31

-So, hi, Andy.

-Hi.

0:33:350:33:37

So, this is the first carriage that's gone over,

0:33:370:33:40

so we've got 100 tonnes.

0:33:400:33:42

-Yeah.

-So it's much more efficient than weighing by hand.

0:33:420:33:46

Oh, yeah, very much so.

0:33:460:33:47

We can measure at 70 kilometres per hour,

0:33:470:33:50

so we're talking less than a second per wagon, probably.

0:33:500:33:53

Wow, that's extraordinary.

0:33:530:33:55

So how's this piece of track actually weighing the train?

0:33:590:34:02

Well, underneath the track are several of these.

0:34:020:34:05

They're called load cells. And, actually,

0:34:050:34:08

it's this little system of wires on the rod which is doing the weighing.

0:34:080:34:11

But as soon as something runs over the track,

0:34:110:34:14

it compresses the rod and the wires get shorter and fatter.

0:34:140:34:18

The resistance goes down,

0:34:180:34:20

and I get more electrical current running through it.

0:34:200:34:23

And suddenly I'm getting a reading.

0:34:230:34:25

What's amazing is there's a direct mathematical relationship between

0:34:250:34:28

the increase in electrical current and the weight going over the wires.

0:34:280:34:33

So we're using electricity to weigh the train.

0:34:330:34:36

In fact, this thing is so sensitive that even if I step on it,

0:34:360:34:39

I actually can get how much I weigh.

0:34:390:34:42

So let's see.

0:34:420:34:44

So how much do I weigh, Andy?

0:34:450:34:47

84.

0:34:470:34:49

-84 kilos?!

-Yeah.

0:34:490:34:51

I don't weigh 84 kilos. Must be the weight of this...

0:34:510:34:54

Today, load cells are used the world over.

0:34:590:35:04

We've come a long way since the days of the beam balance.

0:35:070:35:11

Now, everywhere, from roadside weigh stations

0:35:110:35:14

to supermarket checkouts, use them.

0:35:140:35:16

Measuring mass with electricity has changed our world.

0:35:160:35:21

We can now weigh, transport

0:35:210:35:23

and deliver billions of tonnes-worth of produce with a speed and accuracy

0:35:230:35:28

our Victorian forefathers would never have dreamt possible.

0:35:280:35:32

Precision mass measurement is key to world commerce.

0:35:320:35:37

Now, it's the turn of the very small to push the limits

0:35:410:35:45

of mass measurement.

0:35:450:35:47

Here in America, I've come to meet a team who've come up with

0:35:490:35:53

a unique approach to measuring some of the smallest living

0:35:530:35:56

things on Earth...cells.

0:35:560:35:59

'Project leader Scott Manalis

0:36:080:36:10

'is using mass to monitor the growth of cells.

0:36:100:36:14

'His work could one day revolutionise our fight

0:36:140:36:18

'against cancer.

0:36:180:36:19

'In his lab, he has built the world's smallest weighing station.

0:36:210:36:26

'Here, inside a microchip just millimetres in size,

0:36:280:36:32

'cells are captured and passed over a sensor.'

0:36:320:36:35

The long, thin section highlighted here,

0:36:370:36:40

acts a bit like a diving board.

0:36:400:36:43

When a cell passes over it,

0:36:430:36:45

it vibrates just like a diving board moves after a diver jumps off it.

0:36:450:36:50

The speed of the vibration

0:36:500:36:52

is directly linked to the weight of the cell.

0:36:520:36:56

So, using simple maths,

0:36:560:36:58

Scott can measure the cell with incredible accuracy.

0:36:580:37:01

This cell is the equivalent of like a white blood cell,

0:37:010:37:04

-in terms of its size.

-OK.

0:37:040:37:06

And it weights 100 picograms.

0:37:060:37:08

-Picograms, so that's ten...

-To the minus 12.

0:37:080:37:11

All right, OK. So that's a lot of zeros.

0:37:110:37:14

So this is incredibly small.

0:37:140:37:16

So the cell doesn't weigh very much.

0:37:160:37:18

And the precision with which we can weight it with is

0:37:180:37:21

four orders of magnitude below that.

0:37:210:37:23

-Wow, that's incredible.

-So that's ten femtograms...

0:37:230:37:26

So a part in a thousand.

0:37:260:37:28

-One part in 10,000.

-10,000!

0:37:280:37:31

We care a lot about these things.

0:37:310:37:33

'We're soon in the domain of extreme numbers,

0:37:350:37:38

'but what's amazing is Scott's measuring the weight

0:37:380:37:41

'of a single cell to within a thousand trillionth of a gram.

0:37:410:37:46

'His work is revolutionising our understanding of how cells grow.

0:37:460:37:51

'And by measuring how cells respond to a drug, it could lead to

0:37:510:37:56

'personalised and far more effective cancer treatment.'

0:37:560:38:00

It's absolutely amazing, the limits we are now pushing mass measurement.

0:38:040:38:09

But scientists are frustrated.

0:38:090:38:11

And it's because we're still trying to tie mass back to that

0:38:110:38:16

ageing lump of metal in Paris, Le Grand K.

0:38:160:38:20

And with Le Grand K's weight unstable, there's a real

0:38:200:38:24

urgency to find a new even more accurate way to define mass.

0:38:240:38:30

Now, a race is being fought across two continents to retire Le Grand K.

0:38:310:38:35

'20 miles north of Washington is one of the world's most

0:38:490:38:53

'accurate sets of scales.'

0:38:530:38:55

This whole area is a car-free zone, and that's because the scales

0:38:570:39:01

that are being used here are so sensitive that even the magnetic

0:39:010:39:05

field caused by the metal inside the cars can affect the measurements.

0:39:050:39:09

Welcome to Team Watt Balance.

0:39:090:39:11

'Most things in this strange-looking building are made of wood,

0:39:140:39:18

'and clad in vinyl to minimise the effects of magnetism.

0:39:180:39:24

'Everything from the power lines to the plumbing pipes

0:39:240:39:28

'are encased in shielded plastic ducts.

0:39:280:39:31

'And every single bit of metal that enters the lab, down to this

0:39:310:39:35

'tiny spare part, has to be checked for its levels of magnetism.

0:39:350:39:40

'Stephan Schlamminger's project is one of the longest-running

0:39:520:39:56

'metrology experiments in the world.

0:39:560:39:59

'Its founders have long since retired,

0:39:590:40:02

'but now the team here are close to fulfilling their dream.'

0:40:020:40:05

And this is their brainchild. The watt balance.

0:40:070:40:11

Inside this cage of pure copper is a weighing scale whose

0:40:250:40:30

principles go back to the very first balances 5,000 years ago.

0:40:300:40:35

And it's so sensitive it can measure the kilo

0:40:370:40:40

to eight decimal places.

0:40:400:40:42

So here's our watt balance.

0:40:440:40:46

It is a thing of beauty.

0:40:460:40:48

It really is.

0:40:480:40:49

And you see up here this wheel is like the old-fashioned beam balance.

0:40:490:40:53

That's quite ancient technology, isn't it?

0:40:530:40:55

Yeah, it's thousand-year-old technology up on top,

0:40:550:40:58

but down here you will see the coil that's connected

0:40:580:41:00

to three rods, and this will provide the counterforce

0:41:000:41:03

to the gravitational force that this mass is providing.

0:41:030:41:06

'On one side of the scales,

0:41:060:41:08

'deep inside the mechanism, sits a clone of the Le Grand K.

0:41:080:41:13

'What's so extraordinary about this device is that on the other side,

0:41:130:41:17

'instead of a weight, the team are using electrical force

0:41:170:41:21

'to counterbalance it.'

0:41:210:41:24

The watt balance defines the kilogram by linking

0:41:240:41:27

mechanical power to electrical power.

0:41:270:41:29

-That's why it's called the watt balance.

-Right.

0:41:290:41:31

'Their goal is to measure the amount of electricity needed to

0:41:310:41:34

'perfectly counterbalance the kilo clone

0:41:340:41:38

'and redefine the kilogram, based on electrical power.'

0:41:380:41:42

It sounds straightforward,

0:41:450:41:47

but when you are working with one of the most sensitive

0:41:470:41:50

scales in the world, everything, from car engines to the movement

0:41:500:41:54

of the local deer population outside, can affect its readings.

0:41:540:41:59

Even tiny shifts in gravity, like the phase of the moon

0:42:000:42:03

and the level of ground water, need to be measured

0:42:030:42:07

and taken into account when this experiment is running.

0:42:070:42:10

It seems you're having to keep track of so many different things in order

0:42:130:42:17

-to pin down that kilo.

-That is the art.

0:42:170:42:19

That's the art and science of this! Amazing.

0:42:190:42:23

So we try to measure this kilo to about four parts per 100 million,

0:42:230:42:28

and, in order to do so, we need to measure all these

0:42:280:42:31

auxiliary qualities like voltage, resistance, gravity, metre,

0:42:310:42:36

second, to much better than four parts per hundred million.

0:42:360:42:41

Now, after more than 30 years of perfecting the scale's accuracy,

0:42:420:42:47

Team Watt Balance are very close to achieving their holy grail -

0:42:470:42:51

a new electronic kilogram.

0:42:510:42:54

'I left the watt balance team realising I was witnessing

0:43:060:43:09

'a potentially historic moment in the life of the kilogram.'

0:43:090:43:13

The days of the American kilo making its transatlantic journey

0:43:230:43:27

to Paris to be compared against Le Grand K are probably numbered.

0:43:270:43:32

But the watt balance team have got a rival.

0:43:320:43:35

In Germany, Team Silicon Sphere have got a completely different

0:43:350:43:39

approach to redefining the kilo.

0:43:390:43:41

And it involves counting the number of atoms in a kilogram

0:43:410:43:44

of silicon crystal.

0:43:440:43:46

People often talk about counting the number of grains of sand on a beach.

0:43:490:43:53

But what Team Silicon Sphere are proposing to do

0:43:530:43:56

is in completely different league.

0:43:560:43:58

It's like trying to cover the whole globe in sand

0:43:580:44:02

and counting every grain.

0:44:020:44:04

'But what are these atoms they're trying to count?'

0:44:080:44:12

It was the Ancient Greeks who first came up with the word "atom"

0:44:140:44:17

to define the smallest indivisible particle of matter.

0:44:170:44:21

But it took Englishman John Dalton in the 19th century to shed

0:44:220:44:27

light on what atoms really are.

0:44:270:44:29

At the time, we knew that all matter was made up of different

0:44:310:44:34

elements like carbon and oxygen.

0:44:340:44:37

Dalton's brilliance was a radical theory that each element must

0:44:370:44:42

consist of atoms of a single unique type and mass.

0:44:420:44:46

Dalton would never have dreamt it possible to see

0:44:490:44:52

or count these atoms...

0:44:520:44:54

..but now, in a remote lab in Northern Germany,

0:44:570:45:00

scientists are attempting to do just that.

0:45:000:45:04

'What Dalton didn't realise is the sheer number of atoms inside things.

0:45:110:45:16

'That there are trillion upon trillion inside a single

0:45:160:45:19

'kilo of silicon.

0:45:190:45:22

'And it's by counting these atoms

0:45:230:45:26

'that the silicon sphere team hope to redefine the kilo.

0:45:260:45:29

'This is a perfect kilogram sphere of pure silicon.

0:45:350:45:40

'The culmination of 30 years' work.

0:45:420:45:44

'It represents one of the most ambitious challenges ever to

0:45:440:45:48

'be undertaken in measurement history.

0:45:480:45:51

'Like the watt balance, the silicon sphere project

0:45:540:45:58

'started in the 1970s.'

0:45:580:45:59

The goal was to measure the atomic distances -

0:46:030:46:07

the distance between the atoms in a very perfect crystal.

0:46:070:46:12

Silicon was at that time a material which was used for the semiconductor

0:46:120:46:17

industry, and was the first very perfect material for that use.

0:46:170:46:23

Silicon atoms line up in an extremely rigid

0:46:260:46:29

and regular pattern, which in theory makes them easier to count.

0:46:290:46:34

The idea was to create a perfect sphere of silicon,

0:46:370:46:42

measure its dimensions with extreme precision,

0:46:420:46:45

and then calculate the spaces between the atoms

0:46:450:46:49

using a technique called X-ray crystallography.

0:46:490:46:53

'Then, using simple maths,

0:46:540:46:57

'they could work out the total number of atoms in the sphere.'

0:46:570:47:01

The project was supposed to take a couple of years,

0:47:030:47:07

but they faced many challenges.

0:47:070:47:10

The first was how to create a perfect sphere.

0:47:120:47:16

The levels of perfection the team were seeking

0:47:170:47:20

were beyond the capabilities of any machine.

0:47:200:47:23

They scoured the globe and found the only way to create a sphere

0:47:250:47:30

to the level of perfection they needed was to do it by hand.

0:47:300:47:34

And only one man was capable of this.

0:47:370:47:40

Australian lens maker Achim Leisner.

0:47:400:47:43

He literally used his hands to shape the ball to such an incredible

0:47:460:47:50

level of perfection that, if you likened it to the Earth,

0:47:500:47:54

the level of its surface would never vary more than a few metres.

0:47:540:48:00

Using his extraordinary sense of touch, it's said Achim could

0:48:000:48:05

feel silicon's atomic structure with his fingertips.

0:48:050:48:09

You need really...

0:48:090:48:12

a feeling how many atoms you have to remove on that side or

0:48:120:48:15

on the other side of the sphere, so he had atomic feeling in his hands.

0:48:150:48:20

It took months for Achim to perfect his sphere.

0:48:220:48:26

Finally, the task of analysing

0:48:280:48:31

the space between the silicon atoms could begin.

0:48:310:48:34

But, on the cusp of realising their dream, disaster struck.

0:48:350:48:39

There was a flaw in the very make up of the silicon.

0:48:410:48:44

In its natural state, silicon consists of three different

0:48:470:48:51

forms called isotopes.

0:48:510:48:53

Now, each different atom has a different mass.

0:48:530:48:56

Leisner's sphere contained all three different types of these atoms.

0:48:560:49:01

The team needed a pure source of silicon,

0:49:020:49:05

or else the project was over.

0:49:050:49:08

The solution came from an unlikely source.

0:49:080:49:12

A nuclear weapons facility.

0:49:150:49:18

The Cold War was over and a lot of centrifuge in Russia

0:49:200:49:25

were not running for nuclear weapons,

0:49:250:49:30

so we were lucky to rent

0:49:300:49:33

some of this centrifuge to prepare silicon for our purpose.

0:49:330:49:39

A new batch of silicon was sent to Russia

0:49:420:49:44

and spun in the same centrifuge that was formerly used to enrich uranium.

0:49:440:49:49

This forced out the wayward extra isotopes,

0:49:500:49:54

producing pure silicon-28.

0:49:540:49:58

Then Leisner had to start the job of polishing all over again.

0:50:000:50:04

Finally, after many years,

0:50:060:50:08

the scientists once again started counting

0:50:080:50:11

the space between the atoms.

0:50:110:50:13

And, trillions of atoms later, they've nearly completed their task.

0:50:170:50:22

We hope that in two years, we will have all the information

0:50:250:50:29

together for a new definition that means we have a value

0:50:290:50:34

with a very small uncertainty -

0:50:340:50:36

let us say below two times ten to minus eight.

0:50:360:50:40

And that's an accuracy to eight decimal places.

0:50:400:50:44

It's the same level of precision as Team Watt Balance

0:50:460:50:48

in America are striving for.

0:50:480:50:51

At the moment, we are in the pole position to win this race.

0:50:540:51:01

Within a few years, Le Grand K could be retired.

0:51:020:51:05

But the work here could revolutionise

0:51:050:51:08

another of the seven fundamental units we use to describe our world.

0:51:080:51:13

Ein kaffee mit milch, bitte. Danke.

0:51:270:51:30

If the silicon team are successful, then they won't just redefine

0:51:310:51:36

the kilo, they could end up redefining the SI unit most

0:51:360:51:39

feared by chemistry students across the world - the mole.

0:51:390:51:43

'It's a word which comes from Latin meaning "massive heap of material."'

0:51:440:51:49

Now, chemists probably won't like this,

0:51:520:51:54

but consider this cup of coffee.

0:51:540:51:56

There's a certain ratio of milk to coffee, say one part milk,

0:51:560:52:01

to nine parts coffee, which, combined,

0:52:010:52:04

makes one part perfect milky coffee.

0:52:040:52:08

Now the mole does a similar thing for chemists,

0:52:080:52:11

but replace the coffee and the milk with atoms and molecules.

0:52:110:52:15

Yep, perfect!

0:52:170:52:18

All this leads back to our friend Dalton,

0:52:200:52:23

and his work in the 19th century.

0:52:230:52:25

When he began his investigation into atoms, he discovered that

0:52:250:52:29

atoms from different elements weighed different amounts.

0:52:290:52:33

At the centre of every atom

0:52:330:52:35

is a nucleus containing protons and neutrons.

0:52:350:52:38

Different elements have different numbers of these protons

0:52:380:52:42

and neutrons, which is why they weigh different amounts.

0:52:420:52:46

Throughout the 19th century,

0:52:510:52:54

the greatest chemists of the day feverishly tried to work out

0:52:540:52:57

the atomic weights of all the known elements.

0:52:570:53:00

It led to one of science's greatest ever achievements -

0:53:000:53:03

Dmitri Menedeleev's periodic table.

0:53:030:53:08

And if you look at each element on that table,

0:53:110:53:13

you'll see their atomic mass written just below them.

0:53:130:53:17

It was a huge breakthrough.

0:53:190:53:21

Chemists could finally mix

0:53:210:53:23

and manipulate elements with new-found precision.

0:53:230:53:26

But atoms are far too small to look at and manipulate individually.

0:53:280:53:33

What chemists needed was a way of scaling up atomic weight into

0:53:350:53:40

something more tangible they could weigh.

0:53:400:53:42

And the answer was the mole.

0:53:420:53:45

The mole is really just a big number.

0:53:470:53:50

A huge number, in fact,

0:53:500:53:51

which, when you combine it with the atomic weight of each element,

0:53:510:53:54

allows you to work out how many atoms there are inside something.

0:53:540:53:58

It's the chemist's way of scaling up the microscopic

0:53:580:54:02

world of the atom to our world of the gram.

0:54:020:54:05

It's really the bedrock of modern chemistry, allowing us

0:54:050:54:09

to mix things from drugs to fuel with such precision.

0:54:090:54:13

But it leaves open one big question.

0:54:130:54:15

Exactly how many atoms are there inside a mole?

0:54:150:54:19

The number of atoms that we have in a mole is what

0:54:230:54:26

we call Avogadro's number.

0:54:260:54:28

We can go back to Einstein, for instance, in 1905.

0:54:280:54:31

He came up with one of the first estimates of just how big

0:54:310:54:34

this number is from looking down microscopes at pollen grains and

0:54:340:54:38

from that he was able to get one of our first estimates of the number.

0:54:380:54:42

He got the first number right.

0:54:420:54:44

He got the six right, and he got the 23 zeros right.

0:54:440:54:47

While Einstein's groundbreaking work got close to defining

0:54:500:54:53

the elusive Avogadro's number, it's the silicon sphere team that

0:54:530:54:59

could not only solve the kilo conundrum,

0:54:590:55:02

but also solve the centuries-old question of how many atoms

0:55:020:55:05

there are in a mole...

0:55:050:55:07

..and once and for all define Avogadro's number.

0:55:100:55:14

If this happens,

0:55:140:55:16

it will be a remarkable moment in measurement history.

0:55:160:55:20

In one astonishing experiment,

0:55:200:55:22

two golden units of measurement could be redefined.

0:55:220:55:26

We've come a long way since the days of using barley corn weights.

0:55:260:55:30

Our quest for ever greater precision

0:55:300:55:32

has led us into the very fabric of our universe, allowing us to weigh

0:55:320:55:36

and analyse things with incredible speed, scale and precision.

0:55:360:55:40

In a few years' time, all going well, the BIPM will

0:55:400:55:44

decide between atoms or electrical force to redefine the kilo.

0:55:440:55:48

The winner is kind of irrelevant.

0:55:480:55:51

Both Team Watt Balance

0:55:510:55:53

and Silicon Ball have done what seemed impossible -

0:55:530:55:55

to redefine the kilo based on the unchanging laws of the universe.

0:55:550:56:00

In the pursuit of ever-greater accuracy, these remarkable projects

0:56:010:56:06

have brought together thousands of years of scientific endeavour.

0:56:060:56:10

But our quest for ever greater precision doesn't stop here.

0:56:120:56:17

The last great measurement frontier will be to journey

0:56:220:56:25

inside atoms themselves, to discover what mass really is.

0:56:250:56:31

100 metres under the Swiss-French border,

0:56:420:56:45

at CERN's particle accelerator, scientists think

0:56:450:56:48

they have discovered a particle that gives things mass -

0:56:480:56:52

the Higgs boson.

0:56:520:56:53

And one day, our human desire for ever greater precision

0:56:530:56:58

may even see mass redefined once more,

0:56:580:57:01

and tied to Higgs itself.

0:57:010:57:05

If it happens, who knows what the technological impacts will be?

0:57:070:57:11

And that's the beauty of measurement.

0:57:110:57:13

Every leap in precision leads to new scientific

0:57:130:57:17

and technological advances.

0:57:170:57:19

Measurement has shaped our history,

0:57:190:57:21

and will continue to change our world.

0:57:210:57:24

'Next, we explore the world of energy.

0:57:390:57:42

'And how the measurement of light, heat and electricity

0:57:440:57:48

'have transformed our lives

0:57:480:57:50

'as I continue my journey into measurement.'

0:57:500:57:54

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