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The alchemists were a mysterious group of medieval scientists | 0:00:00 | 0:00:04 | |
who believed their knowledge of chemistry gave them magical powers. | 0:00:04 | 0:00:08 | |
They could summon fire, produce mystical potions. | 0:00:08 | 0:00:12 | |
They even tried to turn metals into gold. | 0:00:12 | 0:00:17 | |
Their magnificent feats enthralled kings and commoners alike. | 0:00:18 | 0:00:23 | |
But they never revealed their secrets. | 0:00:23 | 0:00:26 | |
By pushing the frontiers of science, | 0:00:26 | 0:00:28 | |
modern chemists can perform equally impressive feats, | 0:00:28 | 0:00:30 | |
and we're happy to tell you everything. | 0:00:30 | 0:00:33 | |
APPLAUSE | 0:00:54 | 0:00:56 | |
Chemistry gives us an understanding of the world | 0:01:04 | 0:01:07 | |
that the other sciences just don't. | 0:01:07 | 0:01:10 | |
It's all about how one substance interacts with another | 0:01:10 | 0:01:14 | |
to give us something new. | 0:01:14 | 0:01:16 | |
Thank you. Take this Christmas tree here, for instance. | 0:01:16 | 0:01:21 | |
A nice, solid structure, but watch what happens when I do this. | 0:01:21 | 0:01:27 | |
Whoa! | 0:01:29 | 0:01:31 | |
APPLAUSE | 0:01:35 | 0:01:36 | |
Well, we certainly saw that a change took place there. | 0:01:43 | 0:01:47 | |
That was a flash of light, I felt a blast of heat, | 0:01:47 | 0:01:51 | |
heard a whoosh of sound and then nothing was left at all. | 0:01:51 | 0:01:55 | |
Trying to understand what happens | 0:01:55 | 0:01:57 | |
when one thing changes into another is chemistry. | 0:01:57 | 0:02:01 | |
My name is Dr Peter Wothers, and I am a chemist. | 0:02:01 | 0:02:05 | |
APPLAUSE | 0:02:05 | 0:02:06 | |
Now, the ancient Greeks thought that everything around them | 0:02:09 | 0:02:13 | |
was made up of just four elements. | 0:02:13 | 0:02:15 | |
Air, water, earth and fire. | 0:02:15 | 0:02:18 | |
We see these here. | 0:02:18 | 0:02:20 | |
In the next three lectures, we're going to look at what air, | 0:02:20 | 0:02:23 | |
water and earth are really made up of. | 0:02:23 | 0:02:26 | |
But don't worry, there will be plenty of fire in all of the lectures. | 0:02:26 | 0:02:31 | |
But this brings me to one important point. | 0:02:31 | 0:02:34 | |
Please do not try these experiments at home. | 0:02:34 | 0:02:38 | |
By understanding the elements around us, | 0:02:38 | 0:02:41 | |
the modern building blocks of science, | 0:02:41 | 0:02:43 | |
we need to look at the world in a different way, | 0:02:43 | 0:02:46 | |
we need to see these elements through the eyes of a chemist. | 0:02:46 | 0:02:50 | |
By understanding these elements, | 0:02:50 | 0:02:51 | |
we can make better materials and better medicines for our future. | 0:02:51 | 0:02:55 | |
We're going to start this first lecture looking at the air. | 0:02:55 | 0:02:59 | |
Now, of course, this is something that we rarely think about, | 0:02:59 | 0:03:03 | |
but without it, we'd all be dead. | 0:03:03 | 0:03:05 | |
But just to show you that it really is here around us | 0:03:05 | 0:03:07 | |
pushing down on this, I've got a demonstration, | 0:03:07 | 0:03:10 | |
but I'd like a volunteer from the audience, please. | 0:03:10 | 0:03:13 | |
Right on the corner there, at the back, yes, | 0:03:13 | 0:03:15 | |
would you like to come down to the front, please? | 0:03:15 | 0:03:18 | |
-OK. Now. What's your name, please? -Xavier. -Xavier. OK. | 0:03:21 | 0:03:24 | |
Right. So, see this here? This is just a normal oil drum. | 0:03:24 | 0:03:26 | |
It seems to be covered in a bit of rubbish. | 0:03:26 | 0:03:29 | |
Hold this, give it a good whack. | 0:03:29 | 0:03:33 | |
Go on, bit harder than that. OK. | 0:03:33 | 0:03:35 | |
It really is quite solid, isn't it? On the top as well, maybe. OK. | 0:03:35 | 0:03:38 | |
-Yeah. Do you think it's pretty solid? -Yeah. | 0:03:38 | 0:03:40 | |
Now, watch what happens when we take the air out of this drum. | 0:03:40 | 0:03:45 | |
At the moment, there is of course a scope open at the top here, | 0:03:45 | 0:03:48 | |
there's air inside, air outside, but we're going to put this pump on here | 0:03:48 | 0:03:51 | |
so we're now removing the air from this drum. | 0:03:51 | 0:03:56 | |
OK. And... That's good. I think you should just step back. That's it. | 0:03:56 | 0:04:01 | |
You stand over there. I'll stand over here. | 0:04:01 | 0:04:04 | |
OK, so we're removing the air from the inside of this drum. | 0:04:04 | 0:04:08 | |
To start off with, the air molecules were pushing | 0:04:08 | 0:04:11 | |
against the drum, but they're also pushing from the outside as well. | 0:04:11 | 0:04:16 | |
So what do you think will happen if we remove the air from inside? | 0:04:16 | 0:04:20 | |
-Any ideas? -It will shrink. -It will shrink? | 0:04:20 | 0:04:22 | |
So do you think it will gradually shrink up and get smaller? | 0:04:22 | 0:04:25 | |
Yeah? Well, that's a good idea. That's what we think. | 0:04:25 | 0:04:28 | |
It doesn't seem to be doing very much at the moment, does it? | 0:04:28 | 0:04:31 | |
So, not a lot. | 0:04:31 | 0:04:32 | |
Well, supposedly, these little air molecules | 0:04:32 | 0:04:36 | |
are all pushing down on this can here. We're taking... | 0:04:36 | 0:04:40 | |
BANG! | 0:04:40 | 0:04:41 | |
GASPING | 0:04:41 | 0:04:43 | |
Come and have a look. You feel that. It is very solid, isn't it? | 0:04:52 | 0:04:57 | |
-Yeah. -That was just the air. | 0:04:57 | 0:05:00 | |
So we do forget about it, but it really is pushing down on us. | 0:05:00 | 0:05:03 | |
It's quite a strong force. | 0:05:03 | 0:05:04 | |
It's like there's two full-grown men standing on your shoulders. | 0:05:04 | 0:05:08 | |
We don't notice it because we're used to it, we've adapted to it. | 0:05:08 | 0:05:11 | |
Thank you very much. Give him a round of applause. Thank you. | 0:05:11 | 0:05:14 | |
APPLAUSE | 0:05:14 | 0:05:16 | |
But what about our tree? What happened to the tree? | 0:05:21 | 0:05:25 | |
Well, what would the ancient Greeks have thought if they had seen that? | 0:05:25 | 0:05:28 | |
What would they have made of this strange substance? | 0:05:28 | 0:05:32 | |
Well, this, actually, the Greeks never saw. | 0:05:32 | 0:05:35 | |
This is a substance called guncotton. | 0:05:35 | 0:05:37 | |
It was only discovered around 200 years ago. | 0:05:37 | 0:05:40 | |
It's quite remarkable. | 0:05:40 | 0:05:42 | |
The Greeks would've said that this is changing into fire and air. | 0:05:42 | 0:05:47 | |
Maybe they would've said this is made of fire and air. | 0:05:47 | 0:05:50 | |
Or maybe they would've just said it's magic. | 0:05:50 | 0:05:54 | |
Either way, they would be wrong. | 0:05:54 | 0:05:56 | |
We now know that the air is much more complicated. | 0:05:56 | 0:05:59 | |
It's a mixture of different components. | 0:05:59 | 0:06:03 | |
To show exactly what the air is made up of, again I need a volunteer. | 0:06:03 | 0:06:07 | |
There's a hand very quickly. I saw your hand. | 0:06:07 | 0:06:09 | |
Would you like to come down, please? Thank you. | 0:06:09 | 0:06:12 | |
Can we have a round of applause, please? | 0:06:12 | 0:06:14 | |
-OK, your hand shot up very quickly there. What's your name? -Nadia. | 0:06:15 | 0:06:19 | |
Nadia. OK, excellent. Now, have you made air before? | 0:06:19 | 0:06:23 | |
Oh, having to think about that one. | 0:06:23 | 0:06:25 | |
-Have you made air before, mixed it up? -No. -Exactly. | 0:06:25 | 0:06:29 | |
Of course, the alchemist would never have done this, either. | 0:06:29 | 0:06:31 | |
They didn't know what was in the air. Do you know what's in the air? | 0:06:31 | 0:06:34 | |
-No. -No. No? Oh, come on, have a guess. Do you know any of the gases? | 0:06:34 | 0:06:38 | |
-Oxygen. -Very good, you see, oxygen. Do you know any other ones? | 0:06:38 | 0:06:42 | |
-Carbon dioxide. -Carbon dioxide, exactly. | 0:06:42 | 0:06:44 | |
So we're going to see how many of the different gases are in air. | 0:06:44 | 0:06:47 | |
Would you like to come over here? | 0:06:47 | 0:06:48 | |
So these are some gas cylinders, | 0:06:48 | 0:06:50 | |
and we've got the different proportions of the air | 0:06:50 | 0:06:53 | |
you're going to add to this cylinder of water here. | 0:06:53 | 0:06:55 | |
OK. Now, the first one is the most common gas. | 0:06:55 | 0:06:58 | |
It's not oxygen, and it's not carbon dioxide. Does anybody else know? | 0:06:58 | 0:07:01 | |
-Do you want to shout it out? -Nitrogen. | 0:07:01 | 0:07:03 | |
Nitrogen. Yes, exactly. So the most common gas is nitrogen, | 0:07:03 | 0:07:06 | |
and this is what we have here, | 0:07:06 | 0:07:08 | |
so I'd like you to turn the tap for me, please. This tap here. | 0:07:08 | 0:07:10 | |
This is going to let some nitrogen in. | 0:07:10 | 0:07:13 | |
Now, we're aiming to get to this mark here. | 0:07:13 | 0:07:17 | |
This is 78%. If we get up to here, it's 100%. That'd be 78% nitrogen. | 0:07:17 | 0:07:22 | |
So, there's a lot of nitrogen in the air, isn't there? | 0:07:22 | 0:07:25 | |
There's all this. Look at this. You've got to stop it. | 0:07:25 | 0:07:27 | |
You've got to get this red mark here on the black mark, | 0:07:27 | 0:07:31 | |
so you've got to get this just right. | 0:07:31 | 0:07:32 | |
This is our nitrogen, and this is going to be 78%. | 0:07:32 | 0:07:37 | |
-Oh, stop, stop, stop, stop, stop, stop, stop! You've gone past. -Sorry! | 0:07:38 | 0:07:43 | |
Oh, dear, what a disaster. That's OK. Look, there we are. | 0:07:43 | 0:07:47 | |
There we are. Spot on. | 0:07:47 | 0:07:49 | |
78%. Well done, that's fantastic. Excellent. OK. | 0:07:49 | 0:07:53 | |
Now then, the next ingredient, what's the next ingredient? | 0:07:53 | 0:07:56 | |
-Nitrogen? Oh, sorry. -We've done nitrogen. What's the next one? | 0:07:56 | 0:08:00 | |
-Carbon dioxide. -No. You like your carbon dioxide. -Oxygen. -It's oxygen. | 0:08:00 | 0:08:03 | |
You're absolutely right. Very important one. | 0:08:03 | 0:08:06 | |
Right. So this is our oxygen. OK? You're absolutely right there. | 0:08:06 | 0:08:10 | |
-You ready to go again? -Yeah. -Not yet, not yet. | 0:08:10 | 0:08:12 | |
We've got to go to 21%. | 0:08:12 | 0:08:15 | |
Now, 21%, that takes us to about here, | 0:08:15 | 0:08:19 | |
I think. OK, that's 21-ish. Yes. So you're aiming for here, OK? | 0:08:19 | 0:08:24 | |
Go on, then. | 0:08:24 | 0:08:26 | |
That's it. Very good. | 0:08:26 | 0:08:28 | |
So there's quite a lot of oxygen as well. | 0:08:30 | 0:08:33 | |
I can see the concentration now. That's what we need. Very good. | 0:08:33 | 0:08:37 | |
Oh, look at that. Just about spot on again. | 0:08:37 | 0:08:41 | |
Remarkable. OK. Very good. | 0:08:41 | 0:08:44 | |
Now, then. Now, we're coming to the third most abundant gas. | 0:08:44 | 0:08:48 | |
So far, we've got 78% nitrogen, we've got 21% oxygen. | 0:08:48 | 0:08:54 | |
We've almost run out of everything else. That's only 1% left. | 0:08:54 | 0:08:59 | |
Does anyone know the third most abundant gas? | 0:08:59 | 0:09:02 | |
You haven't mentioned this one yet. Does anybody know? Shout it out. | 0:09:02 | 0:09:05 | |
SHOUTING | 0:09:05 | 0:09:07 | |
All sorts of different replies there, but it is, in fact, argon. | 0:09:07 | 0:09:11 | |
I think some people said argon. Pat yourself on the back there. | 0:09:11 | 0:09:14 | |
It is argon. Right. | 0:09:14 | 0:09:15 | |
This is a tricky one now, but you're getting very good. | 0:09:15 | 0:09:17 | |
All right. Argon. This is just 1%, so that's about there. | 0:09:17 | 0:09:21 | |
-Can you see that? -Yeah. -About here, here it is, OK? | 0:09:21 | 0:09:24 | |
-OK. -Go on, then. Go on. | 0:09:24 | 0:09:28 | |
Oh, wrong one. The audience are watching. The argon one. | 0:09:28 | 0:09:31 | |
That's it. Give it a go. | 0:09:31 | 0:09:34 | |
Brilliant. | 0:09:34 | 0:09:35 | |
There we are. Look at that. That is very good indeed. Now, then. | 0:09:35 | 0:09:39 | |
APPLAUSE | 0:09:39 | 0:09:40 | |
-We're coming to your favourite gas. Which one's that? -Carbon dioxide. | 0:09:43 | 0:09:46 | |
Carbon dioxide, exactly. But there's not a lot of carbon dioxide. | 0:09:46 | 0:09:49 | |
In fact, it's 0.037% carbon dioxide. | 0:09:49 | 0:09:54 | |
Unless we did this 200 years ago, it would've been quite a bit less. | 0:09:54 | 0:09:57 | |
We've increased the amount, but anyway... | 0:09:57 | 0:09:58 | |
So carbon dioxide, we just need a quick burst from that, so quick burst. That's it. That'll do. | 0:09:58 | 0:10:03 | |
That's your carbon dioxide. | 0:10:03 | 0:10:04 | |
Hardly any at all, but nonetheless, very important. | 0:10:04 | 0:10:07 | |
All the plants need that. So that's our carbon dioxide. | 0:10:07 | 0:10:11 | |
You still haven't made perfect air yet. | 0:10:11 | 0:10:13 | |
We could breathe this, that would be OK, but there are some other gases, | 0:10:13 | 0:10:16 | |
and these are some rather rare gases | 0:10:16 | 0:10:17 | |
but we've put all of these in this little syringe here. | 0:10:17 | 0:10:20 | |
Would you like to just add your last bit of gas, | 0:10:20 | 0:10:24 | |
so just push the plunger down and watch for the bubble. | 0:10:24 | 0:10:27 | |
That it is, there we are. | 0:10:27 | 0:10:29 | |
There, excellent. That's the last gases. | 0:10:29 | 0:10:32 | |
This is neon, helium, krypton, and xenon. | 0:10:32 | 0:10:35 | |
They make up just a tiny proportion of the gas. | 0:10:35 | 0:10:38 | |
You did very well there. | 0:10:38 | 0:10:39 | |
Thank you very much. Give her a big round of applause. | 0:10:39 | 0:10:42 | |
APPLAUSE | 0:10:42 | 0:10:48 | |
OK, so now then we know that air isn't just one element, | 0:10:49 | 0:10:54 | |
but a mixture of many. | 0:10:54 | 0:10:55 | |
Before we look at these different elements from air in more detail, | 0:10:55 | 0:11:00 | |
we want to see all of the elements that occur in nature. | 0:11:00 | 0:11:03 | |
Now this is where you come in. | 0:11:03 | 0:11:04 | |
You've got your cards here for different elements | 0:11:04 | 0:11:07 | |
so, if you're a member of the periodic table, get ready, | 0:11:07 | 0:11:09 | |
but to help us with this, would you please welcome, | 0:11:09 | 0:11:12 | |
straight from the West End, the cast of the musical Loserville? | 0:11:12 | 0:11:16 | |
APPLAUSE | 0:11:16 | 0:11:22 | |
# There's antimony, arsenic, aluminium, selenium | 0:11:26 | 0:11:29 | |
# And hydrogen and oxygen and nitrogen and rhenium | 0:11:29 | 0:11:31 | |
# And nickel, neodymium, neptunium, germanium | 0:11:31 | 0:11:34 | |
# Iron, americium, ruthenium, uranium | 0:11:34 | 0:11:35 | |
# Europium, zirconium, lutetium, vanadium | 0:11:35 | 0:11:37 | |
# And lanthanum and osmium and astatine and radium | 0:11:37 | 0:11:40 | |
# And gold and protactinium and indium and gallium | 0:11:40 | 0:11:43 | |
# And iodine and thorium and thulium and thallium | 0:11:43 | 0:11:47 | |
# There's yttrium, ytterbium, actinium, rubidium | 0:11:47 | 0:11:50 | |
# And boron, gadolinium, niobium, iridium | 0:11:50 | 0:11:52 | |
# And strontium and silicon and silver and samarium | 0:11:52 | 0:11:54 | |
# And bismuth, bromine, lithium, beryllium, and barium... # | 0:11:54 | 0:11:57 | |
Barium - very good! | 0:11:57 | 0:11:58 | |
# There's holmium and helium and hafnium and erbium | 0:12:02 | 0:12:05 | |
# And phosphorus and francium and fluorine and terbium | 0:12:05 | 0:12:07 | |
# And manganese and mercury, molybdenum, magnesium | 0:12:07 | 0:12:09 | |
# Dysprosium and scandium and cerium and cesium | 0:12:09 | 0:12:11 | |
# And lead, praseodymium and platinum, plutonium | 0:12:11 | 0:12:14 | |
# Palladium, promethium, potassium, polonium | 0:12:14 | 0:12:16 | |
# And tantalum, technetium, titanium, tellurium, | 0:12:16 | 0:12:19 | |
# And cadmium and calcium and chromium and curium | 0:12:19 | 0:12:22 | |
# There's sulphur, californium and fermium, berkelium | 0:12:23 | 0:12:25 | |
# And also mendelevium, einsteinium, nobelium | 0:12:25 | 0:12:28 | |
# And argon, krypton, neon, radon, xenon, zinc and rhodium | 0:12:28 | 0:12:30 | |
# And chlorine, carbon, cobalt, copper, tungsten, tin and sodium | 0:12:30 | 0:12:33 | |
# These were the only ones they found back when this song was written | 0:12:35 | 0:12:40 | |
# There are another 60 - now we'll show you where they're sitting... # | 0:12:41 | 0:12:45 | |
Stand up, as well? Excellent! | 0:12:45 | 0:12:48 | |
APPLAUSE | 0:12:48 | 0:12:52 | |
You did very well. My whole periodic table should be standing now | 0:12:53 | 0:12:57 | |
but would you please give a round of applause for the cast of Loserville? | 0:12:57 | 0:13:00 | |
-Thank you very much. -APPLAUSE | 0:13:00 | 0:13:05 | |
OK, well, that was certainly chaotic | 0:13:05 | 0:13:08 | |
but you did fantastically well there. | 0:13:08 | 0:13:09 | |
If you'd like to take your seats. | 0:13:09 | 0:13:12 | |
Now, what about this sort of random order? | 0:13:12 | 0:13:14 | |
You were springing up all over the place. Was it really a random order? | 0:13:14 | 0:13:18 | |
Well, actually, it's not. | 0:13:18 | 0:13:20 | |
There is some logic behind this, but to understand the logic | 0:13:20 | 0:13:23 | |
we need to look right into the heart of the atom. | 0:13:23 | 0:13:26 | |
So atoms, as far as the chemists are concerned at least, | 0:13:26 | 0:13:30 | |
are made up of three different particles. | 0:13:30 | 0:13:32 | |
In the heart of the nucleus, there are positively charged protons | 0:13:32 | 0:13:36 | |
and neutral neutrons. We can see these on the screen. | 0:13:36 | 0:13:40 | |
So the red ones are the protons, the blue ones are the neutrons. | 0:13:40 | 0:13:43 | |
But then circling around, we have these electrons. | 0:13:43 | 0:13:46 | |
It's the protons and the neutrons that give an element its mass, | 0:13:46 | 0:13:50 | |
make it quite heavy, so if you pick something up and say it's heavy, | 0:13:50 | 0:13:53 | |
well, that's because of the protons and neutrons. | 0:13:53 | 0:13:55 | |
But it's these electrons that are right around the outside, | 0:13:55 | 0:13:58 | |
and whenever you touch anything, what you're touching there is electrons. | 0:13:58 | 0:14:01 | |
I bet you've never thought of this before, but if we shake hands we're shaking electrons there. | 0:14:01 | 0:14:05 | |
OK, that's our electrons touching each other there. Anyway, right! | 0:14:05 | 0:14:09 | |
So, here we have our atom. | 0:14:09 | 0:14:11 | |
We now understand what atoms are made of | 0:14:11 | 0:14:13 | |
but what's that got to do with the periodic table? | 0:14:13 | 0:14:15 | |
Well, what makes an element unique is the number of protons in the atom. | 0:14:15 | 0:14:20 | |
We don't really care about the neutrons | 0:14:20 | 0:14:22 | |
and if it's a neutral atom, | 0:14:22 | 0:14:24 | |
of course the number of protons are balanced by the number of electrons. | 0:14:24 | 0:14:27 | |
Hydrogen, where are you? If you'd like to stand up, hydrogen. | 0:14:27 | 0:14:30 | |
You are the first element, | 0:14:30 | 0:14:32 | |
in fact the most abundant element in the universe. | 0:14:32 | 0:14:35 | |
You've got one proton. That's what makes you hydrogen. | 0:14:35 | 0:14:39 | |
One proton and one electron for the neutral atom. Sometimes neutrons but we don't care about those. | 0:14:39 | 0:14:43 | |
The next element, on the same row, we go all the way round to here | 0:14:43 | 0:14:46 | |
and we find helium. You have two protons - that's what makes you you. | 0:14:46 | 0:14:51 | |
Then we come back over here to the periodic table. You're very good. | 0:14:51 | 0:14:56 | |
Lithium, you've got three protons and that's what makes you you, and so on. | 0:14:56 | 0:14:59 | |
That's what we do when we go from one element to the next. | 0:14:59 | 0:15:01 | |
We increase the number of protons by one and the number of electrons | 0:15:01 | 0:15:04 | |
in the neutral atom, and maybe throw in a few neutrons. | 0:15:04 | 0:15:07 | |
Now, the question is, though, we've got 118 elements | 0:15:07 | 0:15:11 | |
but we've got literally tens of millions of different compounds | 0:15:11 | 0:15:16 | |
so how can we get such complexity out of just these 118 elements? | 0:15:16 | 0:15:22 | |
In fact, in this cup of coffee alone, | 0:15:22 | 0:15:25 | |
over 2,000 different compounds have been detected so far - | 0:15:25 | 0:15:29 | |
so loads of compounds, only 118 elements. | 0:15:29 | 0:15:34 | |
There's a nice analogy between letters and words with these elements and their compounds | 0:15:34 | 0:15:40 | |
so I could be saying hundreds of thousands of different words now | 0:15:40 | 0:15:43 | |
but these are all made up of the same 26 letters of the alphabet. | 0:15:43 | 0:15:47 | |
Words like "I" and "a" are made up with a single letter. | 0:15:47 | 0:15:52 | |
There are some words that have two of the same letter. | 0:15:52 | 0:15:55 | |
Aa is a type of Hawaiian lava. | 0:15:55 | 0:15:58 | |
What a silly word that is. But then there's another Hawaiian word. | 0:15:58 | 0:16:01 | |
This is aaa, or something like that, | 0:16:01 | 0:16:04 | |
which is an insect also found in Hawaii. | 0:16:04 | 0:16:07 | |
Our elements have the same sort of thing. | 0:16:09 | 0:16:10 | |
The letters then correspond to the elements, | 0:16:10 | 0:16:13 | |
and there are some elements that just stay by themselves, like these letters. | 0:16:13 | 0:16:17 | |
Helium, can you put your card up, please? Where are you? There you are. And neon, and argon. | 0:16:17 | 0:16:22 | |
All of you, you just stay by yourselves, | 0:16:22 | 0:16:24 | |
just single letters if you like. Single elements. | 0:16:24 | 0:16:26 | |
Then we have other elements that go around in pairs. Where's nitrogen? Put your card up. | 0:16:26 | 0:16:31 | |
Oxygen, fluorine, all of you go around in pairs. | 0:16:31 | 0:16:33 | |
Chlorine, you go around in pairs as well, so you go around in pairs | 0:16:33 | 0:16:37 | |
and occasionally oxygen - just stand up again, oxygen - occasionally | 0:16:37 | 0:16:41 | |
you have three oxygen atoms that make up a molecule of ozone. | 0:16:41 | 0:16:44 | |
OK, thank you very much, elements. | 0:16:44 | 0:16:46 | |
But most of the periodic table, | 0:16:46 | 0:16:48 | |
you are loads of these single atoms together, joined together to form | 0:16:48 | 0:16:52 | |
big masses of metal or non-metals, or whatever you are, if you're solid. | 0:16:52 | 0:16:57 | |
So this would be like a word like "aaaaa" going on for ever, | 0:16:57 | 0:17:00 | |
with so many letters we couldn't count them. | 0:17:00 | 0:17:02 | |
That's not how we usually find the elements. | 0:17:02 | 0:17:04 | |
How we usually find them | 0:17:04 | 0:17:05 | |
is combined with one another to form compounds | 0:17:05 | 0:17:09 | |
so if the letters correspond to our elements, | 0:17:09 | 0:17:13 | |
the words that we use, | 0:17:13 | 0:17:15 | |
these correspond to different combinations of the elements - these are the compounds. | 0:17:15 | 0:17:19 | |
So, the elements want to combine with one another to form different | 0:17:19 | 0:17:24 | |
molecules and we are going to try an experiment now to show this, | 0:17:24 | 0:17:27 | |
to show the combination of two elements | 0:17:27 | 0:17:30 | |
and this is the element oxygen, one of the elements from the air. | 0:17:30 | 0:17:33 | |
Oxygen, where are you again? | 0:17:33 | 0:17:34 | |
There's oxygen. And between phosphorus. Phosphorus. | 0:17:34 | 0:17:37 | |
Can you please stand up, phosphorus. | 0:17:37 | 0:17:39 | |
-OK, now, do you know how you were first discovered, phosphorus? -No. | 0:17:39 | 0:17:45 | |
OK, well, we'll give you a bit of a clue. What's your symbol? | 0:17:45 | 0:17:48 | |
P. | 0:17:48 | 0:17:49 | |
P. Any idea? No? Does anyone else know? | 0:17:49 | 0:17:53 | |
OK, there's a chap right at the back there. | 0:17:53 | 0:17:55 | |
-So where do you think phosphorus was first discovered? -From wee. | 0:17:55 | 0:17:59 | |
From wee, yes, exactly. | 0:17:59 | 0:18:01 | |
OK, so thank you, phosphorus. You can take a seat now. | 0:18:01 | 0:18:04 | |
I've got some urine here - it's only mine so it's not too bad. | 0:18:04 | 0:18:08 | |
AUDIENCE: Eurgh! | 0:18:08 | 0:18:10 | |
It's all right! Smells quite nice. | 0:18:10 | 0:18:12 | |
Do you want a sniff? Oh, you do! OK! | 0:18:12 | 0:18:14 | |
LAUGHTER | 0:18:14 | 0:18:18 | |
It's fine! | 0:18:18 | 0:18:21 | |
Don't worry - it's only apple juice, really! | 0:18:21 | 0:18:23 | |
But...OK, | 0:18:23 | 0:18:25 | |
but back in 1669, | 0:18:25 | 0:18:29 | |
the German alchemist Hennig Brand did take his own urine | 0:18:29 | 0:18:33 | |
and he heated this up and this amazing substance came out. | 0:18:33 | 0:18:38 | |
This was phosphorus. How come phosphorus was discovered so early? | 0:18:38 | 0:18:41 | |
Not just because it was disgusting, | 0:18:41 | 0:18:44 | |
but also because once you found it you couldn't miss it. | 0:18:44 | 0:18:46 | |
It just screams out to you, "Here I am!" | 0:18:46 | 0:18:50 | |
OK, let's try this. | 0:18:50 | 0:18:51 | |
We've got some phosphorus in this flask here | 0:18:51 | 0:18:54 | |
and I'm just going to let the air into this. | 0:18:54 | 0:18:56 | |
We've removed the air and heated up the phosphorus, | 0:18:56 | 0:18:59 | |
and watch what happens here. | 0:18:59 | 0:19:00 | |
Maybe we can have the lights down just a little bit here. | 0:19:00 | 0:19:03 | |
So, as soon as the air comes in, it combines with the phosphorus. | 0:19:05 | 0:19:11 | |
This is phosphorus reacting with air, | 0:19:15 | 0:19:19 | |
and this amazed the alchemists. | 0:19:19 | 0:19:23 | |
When they saw this, they were truly stunned. | 0:19:23 | 0:19:25 | |
In fact, they were so impressed by this amazing light | 0:19:25 | 0:19:29 | |
that the reaction has given out, they named this element phosphorus, | 0:19:29 | 0:19:33 | |
which means "the light giver". | 0:19:33 | 0:19:37 | |
This discovery was commemorated with a painting by Joseph Wright of Derby, that's on the screen here. | 0:19:37 | 0:19:45 | |
It has a really catchy title. | 0:19:45 | 0:19:47 | |
It's called "the alchemist in search of the philosopher's stone | 0:19:47 | 0:19:51 | |
"discovers phosphorus and prays for the successful conclusion | 0:19:51 | 0:19:54 | |
"of his operation, as was the custom of the ancient chemical astrologers". | 0:19:54 | 0:20:00 | |
Snappy, but it sort of says what it is, and you can see this, | 0:20:00 | 0:20:04 | |
this amazing look in the alchemist's eyes as he's made this fantastic discovery. | 0:20:04 | 0:20:09 | |
This was far brighter than any of their lamps or candles at the time. | 0:20:09 | 0:20:13 | |
I have a description here. This is from a book from 1692. | 0:20:13 | 0:20:17 | |
It describes phosphorus. | 0:20:17 | 0:20:19 | |
It says you need to store it underwater because it reacts with the air, | 0:20:19 | 0:20:22 | |
but it also says here, | 0:20:22 | 0:20:23 | |
"If the Privy Parts be therewith rubb'd, they will be inflamed and burning a good while after." | 0:20:23 | 0:20:30 | |
Now there's one that you really shouldn't try at home! | 0:20:31 | 0:20:35 | |
Please don't go smearing phosphorus on your privy parts. It's not fun. | 0:20:35 | 0:20:41 | |
Anyway, but the alchemists made this discovery. They found phosphorus. | 0:20:41 | 0:20:46 | |
They knew it was reacting with the air | 0:20:46 | 0:20:49 | |
but they didn't understand fully what was going on | 0:20:49 | 0:20:51 | |
because they didn't know what the air was made of. | 0:20:51 | 0:20:54 | |
Chemists now know that it's a mixture of gases | 0:20:56 | 0:20:59 | |
and a mixture of different elements that makes up the air. | 0:20:59 | 0:21:01 | |
Now, we're going to have a look again at the different gases that are in the air. | 0:21:01 | 0:21:05 | |
In fact, first of all, can we have all the elements that are gases? | 0:21:05 | 0:21:09 | |
So, all the gaseous atoms. Can you stand up, please? | 0:21:09 | 0:21:11 | |
So, where are all the atoms that are gases? We have hydrogen over here. | 0:21:11 | 0:21:15 | |
Well, it's a good job there's not too much of you in the air | 0:21:15 | 0:21:18 | |
because that would make it very flammable, so if you sit down. | 0:21:18 | 0:21:21 | |
It would all explode if there was too much hydrogen | 0:21:21 | 0:21:23 | |
and that wouldn't be very good at all. Who else? | 0:21:23 | 0:21:25 | |
Nitrogen and oxygen, we know you're the major components, | 0:21:25 | 0:21:28 | |
but we've also got fluorine and chlorine. | 0:21:28 | 0:21:30 | |
Fluorine and chlorine, you are incredibly reactive, | 0:21:30 | 0:21:32 | |
which also makes you incredibly toxic so it's a very good thing | 0:21:32 | 0:21:36 | |
that you're not in the air as well so perhaps you can sit down as well, please. | 0:21:36 | 0:21:39 | |
Look where the gases that we do find in the air are. | 0:21:39 | 0:21:42 | |
We've got nitrogen and oxygen, we've seen you, but then we've got | 0:21:42 | 0:21:45 | |
all of you sitting here - well, standing here - with the white cards. | 0:21:45 | 0:21:49 | |
You are the so-called noble gases. Why are you all sitting together? | 0:21:49 | 0:21:54 | |
This is not a coincidence, it's because you all have very similar | 0:21:54 | 0:21:58 | |
chemical properties and there's this amazing pattern when we arrange | 0:21:58 | 0:22:02 | |
the elements in a certain way, that every so often | 0:22:02 | 0:22:05 | |
elements with the same chemical properties are found grouped together. | 0:22:05 | 0:22:10 | |
So if we just have our periodic tables up, please. | 0:22:10 | 0:22:13 | |
That's it, fantastic, very good. | 0:22:13 | 0:22:15 | |
We can see these coloured patterns here. | 0:22:15 | 0:22:17 | |
What a beautiful display this is. Excellent. | 0:22:17 | 0:22:20 | |
All of you with the purple cards here, you are group one. | 0:22:20 | 0:22:22 | |
You're all really reactive metals, you explode with water. | 0:22:22 | 0:22:26 | |
Really violently, OK? | 0:22:26 | 0:22:28 | |
You all have similar properties, you're all grouped together. | 0:22:28 | 0:22:31 | |
If we come over here, all you with the green cards for instance, | 0:22:31 | 0:22:34 | |
you're called the halogens. | 0:22:34 | 0:22:36 | |
You're really poisonous, rather unpleasant substances, | 0:22:36 | 0:22:38 | |
but you combine with these over here with the alkali metals, | 0:22:38 | 0:22:41 | |
and you form salts very violently indeed. | 0:22:41 | 0:22:44 | |
OK, at ease, periodic table. | 0:22:44 | 0:22:46 | |
We're going to look, though, at our noble gases. | 0:22:46 | 0:22:50 | |
So, if everyone sits down, but I'd like the noble gases now to come down to the front. | 0:22:50 | 0:22:55 | |
We've got some samples for you. A balloon of krypton. | 0:22:55 | 0:23:00 | |
Hold the string and hold it out. Beautiful. | 0:23:00 | 0:23:02 | |
OK. Xenon, again, hold the string, there we are. | 0:23:02 | 0:23:06 | |
And then we come... Ah! We have a slight problem with radon, I'm afraid. | 0:23:06 | 0:23:11 | |
Radon is incredibly radioactive | 0:23:11 | 0:23:13 | |
so health and safety wouldn't let us give you a balloon full of radon. | 0:23:13 | 0:23:17 | |
You would go home glowing, so we'll just put this one on you there. | 0:23:17 | 0:23:22 | |
That's great. | 0:23:22 | 0:23:23 | |
And ununoctium, I'm afraid ununoctium hasn't even got a name | 0:23:25 | 0:23:29 | |
and this is because there's so few atoms of ununoctium that were made, | 0:23:29 | 0:23:34 | |
or we're not even sure if they were made, | 0:23:34 | 0:23:36 | |
but we couldn't fill a balloon full of you. But you got a balloon anyway! | 0:23:36 | 0:23:39 | |
LAUGHTER | 0:23:39 | 0:23:44 | |
OK, so, mm-hmm, right. | 0:23:44 | 0:23:47 | |
Now, you've all got your balloons | 0:23:47 | 0:23:49 | |
and after a countdown from three, I'd like you to release your balloons. | 0:23:49 | 0:23:52 | |
Keep hold of the strings, though, and we'll see what happens. | 0:23:52 | 0:23:56 | |
So three, two, one, go. | 0:23:56 | 0:23:57 | |
Ah! Look at that. Now, what do we see here? | 0:23:58 | 0:24:01 | |
We all know that helium balloons float | 0:24:01 | 0:24:03 | |
so you've got a nice light element there, helium. What about this neon? | 0:24:03 | 0:24:07 | |
Neon, hmm, it's about the same. You've dropped your string. | 0:24:07 | 0:24:12 | |
Keep hold of the string. It's about the same sort of density as air. | 0:24:12 | 0:24:16 | |
It's the balloon that's making it sink. Argon is getting pretty, er... Whoops! More dense there. | 0:24:16 | 0:24:22 | |
Keep hold, thank you. Krypton is really quite heavy. | 0:24:22 | 0:24:26 | |
And xenon, hmm, you wouldn't want to go to a party with that, would you? | 0:24:26 | 0:24:31 | |
You would be dragging this along the floor! | 0:24:31 | 0:24:33 | |
It's a very expensive gas - it's about £100, this balloon, | 0:24:33 | 0:24:36 | |
but yes, it's very heavy indeed. What does this tell us, though? | 0:24:36 | 0:24:40 | |
Each of these balloons actually has the same number of atoms | 0:24:40 | 0:24:45 | |
because equal volumes contain the same number of particles. | 0:24:45 | 0:24:48 | |
It tells us that the atoms of helium are much lighter than the atoms of xenon | 0:24:48 | 0:24:55 | |
and that's because of the subatomic particles that make up these atoms. | 0:24:55 | 0:24:58 | |
The helium just has two protons and two neutrons | 0:24:58 | 0:25:02 | |
all the way down to ununoctium - you have 118 protons and loads of neutrons. | 0:25:02 | 0:25:06 | |
I think you've done fantastically well. | 0:25:06 | 0:25:08 | |
Would you like to return to your seats? Thank you. | 0:25:08 | 0:25:10 | |
APPLAUSE | 0:25:10 | 0:25:13 | |
We've seen that we've got different densities of these gases, | 0:25:13 | 0:25:16 | |
they have different masses, | 0:25:16 | 0:25:18 | |
but they also have very similar properties | 0:25:18 | 0:25:20 | |
and each of these elements is a gas | 0:25:20 | 0:25:23 | |
and we've filled these signs up with these gases. | 0:25:23 | 0:25:27 | |
We can see that you're all colourless. | 0:25:27 | 0:25:28 | |
You're also all odourless gases, which is a good thing. | 0:25:28 | 0:25:32 | |
You don't smell at all, but not very exciting to look at, | 0:25:32 | 0:25:35 | |
until you pass a few thousand volts through you. Watch what happens then. | 0:25:35 | 0:25:39 | |
They all become much prettier. | 0:25:39 | 0:25:42 | |
This is the normal neon signs that we see. | 0:25:42 | 0:25:46 | |
This sign here is filled with neon gas, but when it gets excited | 0:25:46 | 0:25:50 | |
with the electricity there, the electrons are leaping up, | 0:25:50 | 0:25:52 | |
and as they come back down we get this fantastic red colour. | 0:25:52 | 0:25:56 | |
Each element has its own unique colour | 0:25:56 | 0:25:59 | |
so we can see, then, that some of these gases have uses. | 0:25:59 | 0:26:02 | |
Neon is used in neon signs. | 0:26:02 | 0:26:04 | |
But some of them have even more important uses, and I went to the | 0:26:04 | 0:26:10 | |
University of Sheffield to have a look at one of the uses for helium. | 0:26:10 | 0:26:14 | |
So what's in this little bag here that I've got then, Jim? | 0:26:16 | 0:26:20 | |
What you've got in there is essentially a bag with some helium atoms, | 0:26:20 | 0:26:24 | |
which are magnetically aligned or polarised. | 0:26:24 | 0:26:28 | |
They are contained within the bag. | 0:26:28 | 0:26:30 | |
If we were to actually image the bag, you'd see | 0:26:30 | 0:26:32 | |
just the boundaries of the bag and the air space inside the bag | 0:26:32 | 0:26:36 | |
filled with the gas and nothing on the outside and, similarly, | 0:26:36 | 0:26:40 | |
when you breathe it in we will see the gas inside your lungs. | 0:26:40 | 0:26:43 | |
The scanner is actually a giant magnet with radio detectors | 0:26:43 | 0:26:47 | |
which detect the specially prepared helium atoms as they return | 0:26:47 | 0:26:51 | |
to their natural state within this magnet. | 0:26:51 | 0:26:53 | |
This allows Jim to build up a picture of where the gases are in my lungs. | 0:26:53 | 0:26:59 | |
-Your scan is here. -Those are my lungs? | 0:26:59 | 0:27:01 | |
There's your bronchus, trachea, and your two bronchi, | 0:27:03 | 0:27:06 | |
main feeding bronchi coming off the bronchus. | 0:27:06 | 0:27:08 | |
These are your blood vessels. | 0:27:08 | 0:27:10 | |
So the amazing thing about this is that we are only seeing | 0:27:10 | 0:27:14 | |
-the air inside my lungs, aren't we? -Exactly. | 0:27:14 | 0:27:17 | |
You're just visualising the air spaces there. | 0:27:17 | 0:27:20 | |
It's very exciting to be looking at my own lungs! | 0:27:20 | 0:27:23 | |
It's nice to know they're not too bad, even though | 0:27:23 | 0:27:26 | |
I know I've got a bit of a cough at the moment. | 0:27:26 | 0:27:28 | |
-Nonetheless, they're reasonably healthy, you think? -They look pretty healthy. -That's all right, then. | 0:27:28 | 0:27:33 | |
So this is pretty cutting-edge science here. | 0:27:33 | 0:27:35 | |
We're actually using this form of helium, helium three, | 0:27:35 | 0:27:39 | |
to image the workings, how our lung works. | 0:27:39 | 0:27:42 | |
And actually on the screen we can see here, these are two lungs. | 0:27:42 | 0:27:46 | |
This is a lung of a patient who has asthma on the left-hand side here. | 0:27:46 | 0:27:50 | |
You can see some black regions. | 0:27:50 | 0:27:52 | |
But after they've taken their inhaler, the lungs have opened up, | 0:27:52 | 0:27:56 | |
the airways have opened up, and the helium has gone into those regions. | 0:27:56 | 0:28:00 | |
We can see all the places where the air is now reaching. | 0:28:00 | 0:28:03 | |
So this just shows the medicine in action. | 0:28:03 | 0:28:06 | |
OK, now, it's not just helium that has exciting properties. | 0:28:06 | 0:28:11 | |
If we go right the way down to the bottom of the periodic table here, | 0:28:11 | 0:28:15 | |
the heavy stable element xenon, | 0:28:15 | 0:28:17 | |
this has some truly remarkable properties as well. | 0:28:17 | 0:28:20 | |
-We have a tank here and we've filled this with some xenon, I understand. -A little, yes. | 0:28:20 | 0:28:24 | |
A little xenon so we just keep putting a little bit more in there | 0:28:24 | 0:28:28 | |
and I have a very delicate, very fragile foil boat. | 0:28:28 | 0:28:34 | |
I'm going to see if we can actually balance this, | 0:28:36 | 0:28:39 | |
if we can float this on the xenon in this tank. | 0:28:39 | 0:28:44 | |
-Try this one. -Shall we try this one first? | 0:28:44 | 0:28:46 | |
Yes, we'll try our new boat. Just slide this over. | 0:28:46 | 0:28:50 | |
And try our new boat. | 0:28:55 | 0:28:59 | |
Ah! That's it. Look at that. | 0:28:59 | 0:29:02 | |
-That really is... -APPLAUSE | 0:29:02 | 0:29:05 | |
..floating on the xenon. | 0:29:05 | 0:29:08 | |
There are no strings. It's a little bit fragile here. | 0:29:10 | 0:29:14 | |
I think I need a volunteer to just come and very carefully help me | 0:29:14 | 0:29:18 | |
add some weight into this. | 0:29:18 | 0:29:20 | |
We'll have somebody from, er, the... Yes, right on the end. | 0:29:20 | 0:29:25 | |
Would you like to come down? Thank you. | 0:29:25 | 0:29:28 | |
OK, thank you very much. Give her a round of applause. | 0:29:30 | 0:29:33 | |
If you'd like to come round here. | 0:29:33 | 0:29:36 | |
I'm just trying to keep my boat level here. | 0:29:36 | 0:29:39 | |
-Just add a little bit more xenon. What's your name, please? -Bethany. | 0:29:39 | 0:29:43 | |
Bethany, excellent. | 0:29:43 | 0:29:44 | |
Now, you are going to be probably the first person in the world | 0:29:44 | 0:29:47 | |
ever to try this - we haven't even practised this. | 0:29:47 | 0:29:50 | |
Have a look at this. What do you think this is? Hold it. | 0:29:50 | 0:29:54 | |
-Foil. -It's foil. Does it feel like normal foil? -No. | 0:29:54 | 0:29:58 | |
No, it feels strange, doesn't it? That's because it's pure solid gold. | 0:29:58 | 0:30:02 | |
Right? | 0:30:02 | 0:30:03 | |
This is pure solid gold so let's just screw it up a little bit | 0:30:03 | 0:30:06 | |
and I'd like you to put this in here. | 0:30:06 | 0:30:08 | |
Just see if you can put it in that corner. | 0:30:08 | 0:30:09 | |
That corner is a little bit unstable at the moment. That's it. Oh, look at that! | 0:30:09 | 0:30:13 | |
Now you have made this thing float perfectly. That's pretty amazing. | 0:30:13 | 0:30:16 | |
Add some more. Will you sink it? | 0:30:16 | 0:30:19 | |
Not quite. Oh, there it goes. | 0:30:20 | 0:30:21 | |
Fantastic! A world first. | 0:30:21 | 0:30:24 | |
Thank you very much, excellent. | 0:30:24 | 0:30:26 | |
APPLAUSE | 0:30:26 | 0:30:31 | |
OK, xenon is very dense and I'm very pleased that worked, but it also has | 0:30:31 | 0:30:36 | |
some really remarkable properties that can be used in medicine. | 0:30:36 | 0:30:41 | |
Now, while I was at the University of Sheffield, | 0:30:41 | 0:30:44 | |
we took a chance to experience what it's like to breathe in | 0:30:44 | 0:30:48 | |
some xenon and it has very strange effects on the body | 0:30:48 | 0:30:51 | |
but it can be very useful as well, so let's just see what happens here. | 0:30:51 | 0:30:55 | |
If you take a deep breath in, Peter. Breathe out. | 0:30:55 | 0:31:00 | |
Deep breath in. | 0:31:00 | 0:31:01 | |
Breathe out, and now breathe from the bag. OK. | 0:31:03 | 0:31:07 | |
Breathe in, breathe in, breathe in, breathe in, breathe in, breathe in, | 0:31:07 | 0:31:10 | |
breathe in, breathe in, breathe in, breathe in, breathe in, breathe in. | 0:31:10 | 0:31:15 | |
OK, and hold your breath. | 0:31:15 | 0:31:17 | |
It will be interesting if you talk as you breathe out, | 0:31:20 | 0:31:22 | |
we'll see if we can hear the, er... | 0:31:22 | 0:31:25 | |
-DEEP VOICE: -That's amazing. I feel really relaxed | 0:31:27 | 0:31:29 | |
and I can hear that my voice has changed. | 0:31:29 | 0:31:32 | |
It's gone quite deep now but I feel very happy and relaxed | 0:31:32 | 0:31:37 | |
and calm. Oh, it's wearing off now. | 0:31:37 | 0:31:39 | |
Wow, so that's xenon, these individual atoms of xenon, | 0:31:39 | 0:31:45 | |
-interacting with my brain in some way, isn't it? -Mmm. | 0:31:45 | 0:31:48 | |
So it's going into my bloodstream and interacting with my brain | 0:31:48 | 0:31:51 | |
-and making me feel slightly light-headed. -Mmm. -And that's... | 0:31:51 | 0:31:54 | |
At higher concentrations, that acts as an anaesthetic | 0:31:54 | 0:31:57 | |
and I would just pass out, is that right? | 0:31:57 | 0:31:59 | |
People do use it as an anaesthetic in a clinical setting, | 0:31:59 | 0:32:01 | |
but clearly at higher concentrations than these. | 0:32:01 | 0:32:04 | |
If we'd have retuned the scanner slightly, we'd have actually seen | 0:32:04 | 0:32:07 | |
the xenon atoms dissolved in your blood as well. | 0:32:07 | 0:32:10 | |
That's where we're going with this at the moment. | 0:32:10 | 0:32:12 | |
We'd love to actually be able to pick up the xenon | 0:32:12 | 0:32:14 | |
dissolved in the brain and image the xenon in the brain. | 0:32:14 | 0:32:17 | |
That might give us some insight into how these | 0:32:17 | 0:32:19 | |
anaesthetics are actually working in the neural system. | 0:32:19 | 0:32:23 | |
-Incredible. -Yeah. | 0:32:23 | 0:32:25 | |
Now, that was certainly very strange when I was breathing in this gas | 0:32:25 | 0:32:29 | |
and the latest research that Jim is doing allows the individual atoms | 0:32:29 | 0:32:33 | |
of xenon to be followed around the brain, even. | 0:32:33 | 0:32:36 | |
Now, I'd like you to welcome three incredibly important guests | 0:32:36 | 0:32:40 | |
to the RI. Would you please welcome Dave, Sarah and Riley Joyce? | 0:32:40 | 0:32:45 | |
APPLAUSE | 0:32:45 | 0:32:49 | |
Good to see you. | 0:32:49 | 0:32:51 | |
Thank you very much. Hello. Thank you. | 0:32:51 | 0:32:54 | |
Ah! He's very shy in front of the cameras here. | 0:32:54 | 0:32:58 | |
I was wondering if... Could you tell me your middle name? | 0:32:58 | 0:33:00 | |
What's your full name? Can you tell me your full name? | 0:33:00 | 0:33:03 | |
A bit shy. He's a bit shy, but what is his full name, then, please? | 0:33:03 | 0:33:07 | |
-It's Riley Xenon Joyce. -I think this is great. | 0:33:07 | 0:33:11 | |
I would love to have an element for a middle name, I must say. | 0:33:11 | 0:33:14 | |
So why is Riley's middle name Xenon, then? | 0:33:14 | 0:33:18 | |
Well, Riley was the first baby in the world to receive xenon, | 0:33:18 | 0:33:22 | |
and he received it at St Michael's in Bristol, | 0:33:22 | 0:33:26 | |
due to when he was born he didn't have a pulse | 0:33:26 | 0:33:29 | |
and they had to resuscitate him so he was starved of oxygen. | 0:33:29 | 0:33:33 | |
This could have caused complications if he didn't get this treatment at the time, | 0:33:33 | 0:33:38 | |
so this was acting as an anaesthetic. | 0:33:38 | 0:33:40 | |
Would it just gently put him to sleep and allow the metabolism to slow down? | 0:33:40 | 0:33:45 | |
It has given his brain time to recover and he had it alongside | 0:33:45 | 0:33:49 | |
the head-cooling treatment, which works on the same principle. | 0:33:49 | 0:33:53 | |
I must say that he's very shy at the moment in front of everybody | 0:33:53 | 0:33:56 | |
but earlier he was running around all over the place | 0:33:56 | 0:33:59 | |
-so he's clearly perfectly healthy now, isn't he? Is that right? -He is. | 0:33:59 | 0:34:03 | |
In March this year he had his two-year check-up | 0:34:03 | 0:34:07 | |
and he was discharged as a perfectly normal, healthy child. | 0:34:07 | 0:34:11 | |
When he was born, he was given a 50% chance of having permanent brain damage | 0:34:11 | 0:34:15 | |
so to come from there to where we are now is incredible. | 0:34:15 | 0:34:19 | |
That is absolutely fantastic. | 0:34:19 | 0:34:21 | |
So would you please thank them for coming in? | 0:34:21 | 0:34:24 | |
APPLAUSE | 0:34:24 | 0:34:29 | |
If we just have our periodic table up for a moment. | 0:34:32 | 0:34:35 | |
Have our periodic table up. | 0:34:35 | 0:34:38 | |
We've seen that we have our noble gases here. | 0:34:38 | 0:34:40 | |
You're all individual atoms, | 0:34:40 | 0:34:42 | |
you don't really want to combine with the others, | 0:34:42 | 0:34:45 | |
but this isn't the same throughout the periodic table as a whole. | 0:34:45 | 0:34:48 | |
We're trying to understand what makes some of the gases in the air so special, | 0:34:48 | 0:34:51 | |
but in order to understand these, how they're bonding with each other, | 0:34:51 | 0:34:54 | |
we need to look across the periodic table as a whole. | 0:34:54 | 0:34:58 | |
I have a sample of one of the elements here. | 0:34:58 | 0:35:00 | |
This is the element potassium. Potassium, can you stand up? | 0:35:00 | 0:35:03 | |
There you are. | 0:35:03 | 0:35:04 | |
So you're in this first group, the same group as lithium, sodium, potassium. Thank you. | 0:35:04 | 0:35:08 | |
You're a solid, and in here we have the solid potassium. | 0:35:08 | 0:35:12 | |
Potassium is a metal, and we've got this in the flask. | 0:35:14 | 0:35:18 | |
At ease, periodic table. Thank you. Cards down. Very good. | 0:35:18 | 0:35:21 | |
We've got a little piece of potassium here, and we've taken the air out of this flask. | 0:35:21 | 0:35:28 | |
And I'm just going to gently warm the flask up. | 0:35:30 | 0:35:34 | |
So potassium is a metal. | 0:35:36 | 0:35:39 | |
The potassium atoms want to bond to each other | 0:35:39 | 0:35:42 | |
but they don't bond to each other very tightly. | 0:35:42 | 0:35:45 | |
So it is a solid, though, not a gas like our noble gases, | 0:35:45 | 0:35:49 | |
but watch what happens if I just warm it up rather gently. | 0:35:49 | 0:35:52 | |
Potassium is... Oh, look at that. | 0:35:52 | 0:35:56 | |
What's happened here, all of the potassium atoms have separated | 0:35:56 | 0:36:00 | |
from each other and given this fantastic coating over the inside. | 0:36:00 | 0:36:04 | |
In fact, we've made an instant Christmas bauble, which is great! | 0:36:04 | 0:36:09 | |
But this is a Christmas bauble coated with potassium, | 0:36:09 | 0:36:11 | |
which is probably not so great. But anyway, very beautiful, | 0:36:11 | 0:36:15 | |
but we didn't need to put a lot of energy in to pull those apart. | 0:36:15 | 0:36:19 | |
How can we understand this? We're going to go back to... | 0:36:19 | 0:36:21 | |
If we have the periodic table back up, | 0:36:21 | 0:36:23 | |
we're going to go back to the top element in this second row. | 0:36:23 | 0:36:27 | |
This is lithium, | 0:36:27 | 0:36:28 | |
and we're going to move round the periodic table from lithium | 0:36:28 | 0:36:31 | |
through beryllium, all the way - | 0:36:31 | 0:36:33 | |
boron, carbon, nitrogen, oxygen, fluorine, neon - and see how the bonding changes. | 0:36:33 | 0:36:36 | |
We have our elements lined up and bringing down electrons | 0:36:36 | 0:36:39 | |
so can we have the first two lithiums, please? | 0:36:39 | 0:36:41 | |
Could you come down to the front, and you're bringing some electrons with you. | 0:36:41 | 0:36:44 | |
So these are our yellow electrons | 0:36:44 | 0:36:46 | |
and could you put them in the energy level here, please? | 0:36:46 | 0:36:48 | |
That's it, put them in there, | 0:36:48 | 0:36:50 | |
and if you return to your seats, that's great. Thank you very much. | 0:36:50 | 0:36:53 | |
What's happened here, as the electrons have gone into this region here, | 0:36:53 | 0:36:56 | |
into these shelves here, these have pulled the atoms together | 0:36:56 | 0:37:01 | |
and this is because these negatively charged electrons | 0:37:01 | 0:37:05 | |
are helping pull the nuclei together | 0:37:05 | 0:37:07 | |
when they're concentrated in between the two atoms here. | 0:37:07 | 0:37:10 | |
Can we have our next elements? | 0:37:10 | 0:37:12 | |
We have beryllium - could you come down? | 0:37:12 | 0:37:13 | |
Now, on beryllium we see on the screen here the bonds are much stronger. | 0:37:13 | 0:37:16 | |
Let's see why this is. We add your electron here. | 0:37:16 | 0:37:20 | |
That's it, these are moving the atoms closer together, | 0:37:20 | 0:37:22 | |
so even stronger still. | 0:37:22 | 0:37:24 | |
So beryllium has two electrons, creates a stronger bond now. | 0:37:24 | 0:37:28 | |
Lithium, beryllium. The beryllium atoms are held more tightly. | 0:37:28 | 0:37:32 | |
OK, boron, on the screen here, we have three electrons. | 0:37:32 | 0:37:36 | |
Can you come down please, boron? You've got one more electron here than the beryllium had | 0:37:36 | 0:37:40 | |
so you're going to add your electrons. Could you add your electrons in here? | 0:37:40 | 0:37:44 | |
And again, these... Oh! That really did move, that was pretty good. | 0:37:44 | 0:37:48 | |
So you've a very strong bond now for the boron - | 0:37:48 | 0:37:50 | |
much stronger than the beryllium. Very tightly held. | 0:37:50 | 0:37:52 | |
We've got three electrons bonding these boron atoms together. | 0:37:52 | 0:37:55 | |
Can we have carbons now, please? OK, and that last one. | 0:37:55 | 0:38:00 | |
OK, so the atoms move closer together. | 0:38:00 | 0:38:02 | |
Thank you very much, carbons. We've got some very strong bonds indeed now. | 0:38:02 | 0:38:06 | |
In fact carbon there requires most of the energy of all of the elements to try and rip them apart. | 0:38:06 | 0:38:13 | |
If we were trying to remove the same number of atoms apart, | 0:38:13 | 0:38:16 | |
we need more energy for carbon than any other. | 0:38:16 | 0:38:18 | |
This makes carbon incredibly strong. | 0:38:18 | 0:38:21 | |
I have a sample of carbon here to show you and demonstrate this. | 0:38:21 | 0:38:25 | |
This is a diamond, we can see this here. This is a real diamond. | 0:38:25 | 0:38:29 | |
Very, very strong because of these strong bonds. | 0:38:29 | 0:38:31 | |
I nearly dropped it there. But it is also incredibly hard. | 0:38:31 | 0:38:35 | |
So hard, in fact, that I can actually cut this glass. | 0:38:35 | 0:38:40 | |
The glass is incredibly hard, of course, but diamond is even stronger | 0:38:40 | 0:38:45 | |
because of the strong bonds between the carbon atoms. So... | 0:38:45 | 0:38:48 | |
It's definitely cut into the glass. In fact, it looks like it's pretty deep. | 0:38:52 | 0:38:57 | |
There we are. It's cut down this crack where it's been scored with the glass there. | 0:38:59 | 0:39:05 | |
So a diamond, incredibly strong, because of all these bonding electrons | 0:39:05 | 0:39:10 | |
keeping the carbon atoms together. | 0:39:10 | 0:39:12 | |
We've still got further to go along our periodic table. | 0:39:12 | 0:39:14 | |
We've gone to carbon, we're going to keep on going. | 0:39:14 | 0:39:16 | |
So nitrogens, you have five electrons in total, | 0:39:16 | 0:39:19 | |
so let's see where these have to go. We've run out of room here. | 0:39:19 | 0:39:23 | |
You're going to have to put your electrons in these ones | 0:39:23 | 0:39:26 | |
so this is a slightly different thing going on here. | 0:39:26 | 0:39:28 | |
Would you put your electrons in here? That's great. | 0:39:28 | 0:39:30 | |
And these, actually, now are concentrated outside of the middle | 0:39:30 | 0:39:35 | |
and these electrons are pulling the atoms further apart again. | 0:39:35 | 0:39:38 | |
In fact, these do not help the bonding. These are called anti-bonding levels. | 0:39:38 | 0:39:42 | |
Thank you very much, nitrogens. | 0:39:42 | 0:39:44 | |
OK, we have our next element - this is oxygen. | 0:39:44 | 0:39:47 | |
Let's see what happens as we keep going, adding another electron. | 0:39:47 | 0:39:51 | |
Oxygens, you have to put yours in this level here, | 0:39:51 | 0:39:53 | |
and again these are in these anti-bonding levels, pulling our atoms apart. | 0:39:53 | 0:39:57 | |
So oxygen is a weaker bond than nitrogen. | 0:39:57 | 0:40:00 | |
Let's go to our next atom. We've got two fluorines coming. | 0:40:00 | 0:40:03 | |
Let's see what happens when you get together. OK. Add them in. | 0:40:03 | 0:40:06 | |
That's great. Again, a very weak bond now. It's pulled further apart. | 0:40:06 | 0:40:10 | |
Fluorine has one more electron, weakens the bond here | 0:40:10 | 0:40:13 | |
and the fluorines are really weakly held together. | 0:40:13 | 0:40:16 | |
This is the one of the reasons that makes fluorine | 0:40:16 | 0:40:18 | |
so incredibly reactive. It's because of these weak bonds. | 0:40:18 | 0:40:21 | |
Finally, we have our last element, neon. | 0:40:21 | 0:40:24 | |
So, neon has eight outermost electrons, | 0:40:24 | 0:40:27 | |
so it has one more than the fluorines had. | 0:40:27 | 0:40:29 | |
Let's see where these have to go in the remaining level here. | 0:40:29 | 0:40:32 | |
So if you add your electrons into these last anti-bonding levels... | 0:40:32 | 0:40:35 | |
And it pulls the atoms completely apart. | 0:40:35 | 0:40:38 | |
So, this means the atoms do not bond to each other. | 0:40:38 | 0:40:40 | |
Thank you very much indeed for your help there. Thank you. | 0:40:40 | 0:40:44 | |
APPLAUSE | 0:40:44 | 0:40:46 | |
So, if we just see our periodic table again. Just have you up. | 0:40:48 | 0:40:51 | |
That's great. Thank you very much. | 0:40:51 | 0:40:53 | |
We're looking at these ones over here. | 0:40:53 | 0:40:56 | |
We see carbon, very, very strong bonds. | 0:40:56 | 0:40:58 | |
Nitrogen, not as strong as carbon, but still pretty strong. | 0:40:58 | 0:41:01 | |
Fluorine, very weak bonds. Neon not bonded at all. | 0:41:01 | 0:41:04 | |
But oxygen, you're just about the right strength. | 0:41:04 | 0:41:07 | |
You're still reactive because the bonds aren't too incredibly strong | 0:41:07 | 0:41:10 | |
between the oxygen atoms. | 0:41:10 | 0:41:11 | |
Makes you very, very reactive indeed. | 0:41:11 | 0:41:13 | |
Oxygen, you really are the elixir of life. | 0:41:13 | 0:41:17 | |
It's you that keeps us all alive. I'm going to demonstrate this now. | 0:41:17 | 0:41:20 | |
So, at ease, periodic table. Thank you. | 0:41:20 | 0:41:23 | |
So, I have some breakfast cereal here. | 0:41:23 | 0:41:25 | |
This is just normal breakfast cereal. | 0:41:25 | 0:41:27 | |
I'm just going to put some in the bowl. | 0:41:27 | 0:41:29 | |
This is just the sort of thing that you would normally do. | 0:41:29 | 0:41:33 | |
But now instead of adding my milk... Oops. | 0:41:33 | 0:41:36 | |
Instead of adding my milk, I'm going to add some liquid oxygen. | 0:41:36 | 0:41:41 | |
So this is not the sort of thing you normally do. | 0:41:41 | 0:41:43 | |
We've cooled the oxygen down. So this is oxygen gas | 0:41:43 | 0:41:45 | |
that's been cooled down. It has this beautiful blue colour. | 0:41:45 | 0:41:48 | |
I'm just going to pour this onto our Rice Krispies. | 0:41:48 | 0:41:51 | |
OK. Now, I'm also going to add a light. | 0:41:54 | 0:41:58 | |
Just put my goggles on. | 0:41:58 | 0:42:00 | |
This is also something you don't normally do. | 0:42:00 | 0:42:03 | |
An incredible amount of energy is released there. | 0:42:13 | 0:42:18 | |
This is as the Rice Krispies, the breakfast cereal here... | 0:42:18 | 0:42:22 | |
As our breakfast cereal combines with the oxygen from the air. | 0:42:22 | 0:42:27 | |
And believe it or not, this is actually what happens | 0:42:27 | 0:42:30 | |
inside our bodies. Not quite like this. | 0:42:30 | 0:42:33 | |
We don't have flames coming out of our ears. | 0:42:33 | 0:42:37 | |
But nonetheless, it is the reaction between our breakfast cereal | 0:42:37 | 0:42:40 | |
and the oxygen that we're breathing in that gives us | 0:42:40 | 0:42:43 | |
the energy to stay alive. | 0:42:43 | 0:42:45 | |
And we have Laura here to demonstrate this. | 0:42:45 | 0:42:49 | |
She's been specially trained in breathing | 0:42:49 | 0:42:52 | |
with this rather delicate apparatus here. | 0:42:52 | 0:42:55 | |
OK. Would you like to put this on? | 0:42:55 | 0:42:58 | |
Now, what's happening here? | 0:42:58 | 0:43:00 | |
Laura is breathing in. So if you breathe in... | 0:43:00 | 0:43:02 | |
Breathing in normal air and it's coming in through here, | 0:43:02 | 0:43:05 | |
bubbling through this solution. In the flask here, | 0:43:05 | 0:43:08 | |
we have something called lime water. | 0:43:08 | 0:43:10 | |
Then Laura's breathing out through this one. So the out air | 0:43:10 | 0:43:13 | |
is coming out through here. | 0:43:13 | 0:43:14 | |
Now, lime water reacts with carbon dioxide. | 0:43:14 | 0:43:18 | |
There's very little carbon dioxide in the air, | 0:43:18 | 0:43:20 | |
so there's no change taking place here. | 0:43:20 | 0:43:23 | |
When lime water reacts with carbon dioxide, | 0:43:23 | 0:43:26 | |
it turns cloudy due to the formation of calcium carbonate. | 0:43:26 | 0:43:30 | |
No calcium carbonate forming here. But in the out... | 0:43:30 | 0:43:33 | |
Well, we can begin to see already... Keep breathing. Very good. | 0:43:33 | 0:43:35 | |
You're breathing beautifully there. OK. In the out, we can begin | 0:43:35 | 0:43:39 | |
to see that it is going cloudy. And this is because inside Laura, | 0:43:39 | 0:43:43 | |
it is the same reaction we saw taking place there. | 0:43:43 | 0:43:46 | |
The breakfast cereal Laura had this morning is reacting | 0:43:46 | 0:43:50 | |
with the oxygen she's breathing in. It's releasing a lot of energy | 0:43:50 | 0:43:53 | |
and that's keeping her alive, but she's breathing out carbon dioxide | 0:43:53 | 0:43:56 | |
that is formed during this process as the oxygen reacts | 0:43:56 | 0:43:59 | |
with the fuel to produce carbon dioxide. | 0:43:59 | 0:44:02 | |
Thank you very much. Give Laura a round of applause. | 0:44:02 | 0:44:05 | |
APPLAUSE | 0:44:05 | 0:44:07 | |
So, oxygen is incredibly important just to stay alive. | 0:44:11 | 0:44:16 | |
But we've seen that there's only 21% of oxygen in the air. | 0:44:16 | 0:44:22 | |
So, wouldn't it be better if there was much more oxygen in the air? | 0:44:22 | 0:44:26 | |
Well, probably not. | 0:44:26 | 0:44:28 | |
I'm going to demonstrate this now with the help of my volunteer here, | 0:44:28 | 0:44:32 | |
sausage man. OK. Now, sausage man is made of the same sort of things | 0:44:32 | 0:44:36 | |
that I'm made up of. He's made up of meat, of course. | 0:44:36 | 0:44:39 | |
And I'm just going... We've connected him to a heating wire. | 0:44:39 | 0:44:42 | |
I'm just going to turn up this heating wire here. So, there we are. | 0:44:42 | 0:44:45 | |
The heating wire is just... | 0:44:45 | 0:44:47 | |
Just turn it on a very low voltage there. | 0:44:47 | 0:44:50 | |
It's just beginning to heat up. | 0:44:50 | 0:44:52 | |
Now, it's not really causing too much of a problem. | 0:44:52 | 0:44:55 | |
But watch what happens if I increase the amount of oxygen in the air. | 0:44:55 | 0:44:59 | |
Again, we're going to use the liquid oxygen to do this. | 0:44:59 | 0:45:02 | |
It's just to provide a lot of oxygen gas in the environment. | 0:45:02 | 0:45:07 | |
So he's just with the heating coil there. | 0:45:07 | 0:45:10 | |
Is anything beginning to happen? | 0:45:10 | 0:45:13 | |
His leg's smoking a bit as the wire's heating. | 0:45:13 | 0:45:16 | |
So this is like you're on a different planet | 0:45:16 | 0:45:19 | |
and there's a lot of oxygen on the planet here. | 0:45:19 | 0:45:22 | |
You accidentally lean against a cooker... | 0:45:22 | 0:45:25 | |
And look what's happening here. | 0:45:25 | 0:45:27 | |
Poor sausage man is now in flames. | 0:45:28 | 0:45:31 | |
He's gone up rather drastically here. | 0:45:34 | 0:45:39 | |
This is because of the increased oxygen in his environment. | 0:45:39 | 0:45:44 | |
So, yes, of course, we do need oxygen to stay alive. | 0:45:44 | 0:45:46 | |
It does provide us with our energy. | 0:45:46 | 0:45:48 | |
But too much would definitely be a bad thing. | 0:45:48 | 0:45:53 | |
I need to put out our sausage man. I think it might be very difficult | 0:45:53 | 0:45:56 | |
to put him out since there's so much oxygen in there. | 0:45:56 | 0:45:59 | |
Let's try... We've got some tomato ketchup here. | 0:45:59 | 0:46:02 | |
LAUGHTER | 0:46:02 | 0:46:05 | |
It's... | 0:46:05 | 0:46:06 | |
Wow. | 0:46:08 | 0:46:09 | |
It leaks as well. Great. Somebody didn't put the top on properly. | 0:46:13 | 0:46:18 | |
There we are. We've put him out. | 0:46:18 | 0:46:19 | |
Oops. What a mess. OK. | 0:46:22 | 0:46:25 | |
OK. So, you get the idea | 0:46:25 | 0:46:27 | |
that too much oxygen would certainly be bad for us. | 0:46:27 | 0:46:32 | |
But on a serious note, it's incredibly difficult to put out | 0:46:32 | 0:46:36 | |
a forest fire. | 0:46:36 | 0:46:37 | |
These are incredibly difficult to put out, even with just 21% oxygen. | 0:46:37 | 0:46:40 | |
If it was 100% oxygen, there would be no chance. | 0:46:40 | 0:46:44 | |
So 21% of the air is made up of oxygen. | 0:46:44 | 0:46:48 | |
This is how much we need to breathe. | 0:46:48 | 0:46:50 | |
But what happens if you reduce the amount? Can we still stay alive? | 0:46:50 | 0:46:54 | |
Well, I went to a place just outside Cambridge | 0:46:54 | 0:46:56 | |
where they've reduced the amount of oxygen in their rooms there | 0:46:56 | 0:46:59 | |
from 21% down to 15%. | 0:46:59 | 0:47:02 | |
And they say that things just can't burn in this environment. | 0:47:02 | 0:47:05 | |
-Well, let's see what happened. Can I have a fire? -Yes. | 0:47:05 | 0:47:08 | |
-Can I set fire to your newspaper? -I've got a newspaper here | 0:47:08 | 0:47:11 | |
-and you try to light my newspaper. -OK. -All right. | 0:47:11 | 0:47:15 | |
-See if it works. -Shall I use a lighter? -Use the lighter. | 0:47:16 | 0:47:20 | |
I'll try the lighter first of all. OK. | 0:47:20 | 0:47:23 | |
-Oh. Empty? -I don't think it's a very good one. | 0:47:26 | 0:47:29 | |
-Try mine if yours is empty. -This is a new one, is it? | 0:47:29 | 0:47:34 | |
-OK. -OK. Doesn't work. -Matches. -Matches. OK. | 0:47:34 | 0:47:38 | |
Ah! This is better. | 0:47:38 | 0:47:40 | |
OK. Try again. | 0:47:40 | 0:47:41 | |
Of course, the matches are still lighting | 0:47:43 | 0:47:45 | |
because they have their own oxygen built in here. | 0:47:45 | 0:47:47 | |
That's what's allowing them to strike, | 0:47:47 | 0:47:50 | |
but there's not enough oxygen to allow your newspaper | 0:47:50 | 0:47:54 | |
or the match to actually burn. | 0:47:54 | 0:47:56 | |
-It's only the match head with oxygen there. -Absolutely correct. | 0:47:56 | 0:48:00 | |
The newspaper could not burn by itself. Impossible. | 0:48:00 | 0:48:03 | |
Of course, we can breathe fine in here. It doesn't affect us. | 0:48:03 | 0:48:06 | |
It doesn't affect us at all. We could live in here for ever. | 0:48:06 | 0:48:09 | |
Very impressive. | 0:48:09 | 0:48:10 | |
We've come outside to try a slightly larger-scale version of the lighter. | 0:48:15 | 0:48:19 | |
The lighter couldn't start a fire in the room because it didn't bring | 0:48:19 | 0:48:24 | |
any oxygen with it and there wasn't enough oxygen in the room itself. | 0:48:24 | 0:48:28 | |
So this should... This is petrol. | 0:48:28 | 0:48:30 | |
I've soaked this torch here in petrol. | 0:48:30 | 0:48:32 | |
It should light nice and easily. | 0:48:32 | 0:48:34 | |
Yes. Look at that. So, this is burning rather well. | 0:48:34 | 0:48:39 | |
The question is, will this go out in the room? | 0:48:39 | 0:48:42 | |
Well, let's find out. | 0:48:43 | 0:48:45 | |
And the fire has instantly gone out. | 0:48:58 | 0:49:01 | |
There really just isn't enough oxygen in this room to allow this, | 0:49:01 | 0:49:06 | |
my torch here, to carry on burning. | 0:49:06 | 0:49:09 | |
But there is enough for me to carry on living. | 0:49:09 | 0:49:12 | |
So that's pretty good and I'm happy. | 0:49:12 | 0:49:14 | |
So, this fire prevention system works by decreasing | 0:49:16 | 0:49:20 | |
the amount of oxygen and increasing the amount of nitrogen. | 0:49:20 | 0:49:24 | |
Nitrogen is a very important component of the air | 0:49:24 | 0:49:27 | |
because it's so inert, because of these very strong bonds. | 0:49:27 | 0:49:31 | |
So we're now going to look at some of the properties | 0:49:31 | 0:49:34 | |
of this inert gas, nitrogen. | 0:49:34 | 0:49:36 | |
And this is one of the components in many explosives | 0:49:36 | 0:49:40 | |
such as this nitroglycerin here. | 0:49:40 | 0:49:42 | |
This is a very dangerous explosive. | 0:49:42 | 0:49:45 | |
In fact, Alfred Nobel... | 0:49:45 | 0:49:49 | |
earned his money in trying to work out how to make this more stable. | 0:49:49 | 0:49:56 | |
I need to put on some special kit here, some protective clothing | 0:49:56 | 0:49:59 | |
and some ear protectors. OK. | 0:49:59 | 0:50:02 | |
And I'm going to add a drop of nitroglycerin to the filter paper. | 0:50:04 | 0:50:08 | |
Now then. Adding a drop of nitroglycerin. | 0:50:12 | 0:50:16 | |
There we are. That's it. | 0:50:16 | 0:50:18 | |
And I think I'll just remove this nitroglycerin from here. | 0:50:22 | 0:50:28 | |
I don't want to be too close when this goes off. | 0:50:28 | 0:50:30 | |
So I'll hand this to Mark. Thank you. Right. | 0:50:31 | 0:50:35 | |
Now, the nitroglycerin contains a lot of nitrogen locked up | 0:50:35 | 0:50:38 | |
into its chemical composition. | 0:50:38 | 0:50:42 | |
And it's the sudden release of this that gives it its explosive power. | 0:50:42 | 0:50:47 | |
BANG! | 0:50:48 | 0:50:51 | |
That really was quite violent, | 0:51:04 | 0:51:06 | |
the sudden release of that nitrogen gas. | 0:51:06 | 0:51:09 | |
And that's what makes an explosive explosive. | 0:51:09 | 0:51:12 | |
Most of them contain nitrogen built in. | 0:51:12 | 0:51:15 | |
But remarkably, this reaction, this explosive release of nitrogen gas, | 0:51:15 | 0:51:19 | |
has been used to save thousands of lives. | 0:51:19 | 0:51:23 | |
For this, I need a car. | 0:51:23 | 0:51:25 | |
Have you got a car there, please, Chris? | 0:51:25 | 0:51:28 | |
OK. Well, it's not exactly a real car. | 0:51:28 | 0:51:31 | |
But it is a real steering wheel. OK. | 0:51:31 | 0:51:35 | |
So, this contains a compound with nitrogen in it. | 0:51:35 | 0:51:38 | |
It's nitrogen combined with sodium. | 0:51:38 | 0:51:40 | |
Can we have our periodic table up for a second, please? | 0:51:40 | 0:51:43 | |
So, we have nitrogen over here combined with sodium over here. | 0:51:43 | 0:51:47 | |
But it's the formation of our very, very strong | 0:51:47 | 0:51:50 | |
nitrogen-nitrogen bonds that leads to the rapid inflation | 0:51:50 | 0:51:55 | |
of this air bag. | 0:51:55 | 0:51:56 | |
Now, I need a volunteer from the audience for this, please. | 0:51:56 | 0:52:00 | |
Er, who shall we have? Yes, would you like to come down the front? | 0:52:00 | 0:52:03 | |
Thank you very much. Would you like to stand all the way over here? | 0:52:03 | 0:52:05 | |
-And your name is...? -Fred. -Fred. OK, Fred. | 0:52:05 | 0:52:08 | |
Now, you are going to trigger this air bag. | 0:52:08 | 0:52:10 | |
So if I just take this from Chris. Is this primed? | 0:52:10 | 0:52:13 | |
Just going to make sure it's all OK to trigger. | 0:52:13 | 0:52:16 | |
OK. Thank you very much. Now, if you stand over here. | 0:52:20 | 0:52:23 | |
He's very keen to get a hand on the trigger here. | 0:52:23 | 0:52:25 | |
Now, we're going to count down from three. OK. If you hold this. | 0:52:25 | 0:52:28 | |
Don't press the button yet. OK. Now, when we've counted down, | 0:52:28 | 0:52:31 | |
I want you to press the button. | 0:52:31 | 0:52:32 | |
But don't blink. If you blink, you'll miss this. | 0:52:32 | 0:52:35 | |
It's a very quick reaction. OK. So, three, two, one. | 0:52:35 | 0:52:39 | |
-BANG! -There we are. | 0:52:39 | 0:52:42 | |
OK. Thank you very much indeed. A round of applause for Fred. | 0:52:42 | 0:52:45 | |
APPLAUSE | 0:52:45 | 0:52:47 | |
So, this air bag works here | 0:52:47 | 0:52:51 | |
because the nitrogen really wants to bond to itself to form | 0:52:51 | 0:52:55 | |
these nitrogen molecules and it's this explosive release of nitrogen | 0:52:55 | 0:52:59 | |
that inflates the air bag so quickly. We can see this here | 0:52:59 | 0:53:04 | |
in slow motion. Actually, when the crash test dummy hits the bag, | 0:53:04 | 0:53:08 | |
this bag is actually deflating. The air is coming out of this. | 0:53:08 | 0:53:12 | |
But it needs to be released so quickly, | 0:53:12 | 0:53:15 | |
that's why an explosive is needed. | 0:53:15 | 0:53:18 | |
So nitrogen here saving lives. | 0:53:18 | 0:53:20 | |
But actually, nitrogen is vital for life. | 0:53:20 | 0:53:23 | |
We couldn't live without it. | 0:53:23 | 0:53:25 | |
Every protein in every cell in our body is made up of amino acids. | 0:53:25 | 0:53:30 | |
And every one of these amino acids contains nitrogen. | 0:53:30 | 0:53:34 | |
So somehow we need to take the nitrogen from the air | 0:53:34 | 0:53:36 | |
and get it to combine with other elements so we can form compounds | 0:53:36 | 0:53:40 | |
that are useful to us. | 0:53:40 | 0:53:41 | |
Now, plants have learnt how to do this over millions of years, | 0:53:41 | 0:53:44 | |
but it took chemists a long time to do this. | 0:53:44 | 0:53:47 | |
And the first way this was achieved was by emulating nature... | 0:53:47 | 0:53:51 | |
-THUNDER -..a process in nature | 0:53:51 | 0:53:53 | |
where nitrogen and oxygen are beginning to react. | 0:53:53 | 0:53:56 | |
During this electrical storm, | 0:53:56 | 0:53:58 | |
the lightning here is providing sufficient energy to split apart | 0:53:58 | 0:54:02 | |
these molecules and this can allow nitrogen and oxygen to recombine. | 0:54:02 | 0:54:06 | |
We're going to try and do this in the lecture now. And I have... | 0:54:06 | 0:54:10 | |
Well, this is what every mad scientist should have. | 0:54:10 | 0:54:13 | |
It's a Jacob's ladder and here we see it switched on. | 0:54:13 | 0:54:16 | |
So what we're doing here is passing thousands of volts | 0:54:16 | 0:54:19 | |
between these two electrodes and this is causing the molecules | 0:54:19 | 0:54:23 | |
in the air to be ripped apart, ripping their electrons out. | 0:54:23 | 0:54:27 | |
This heats up the air just above it, | 0:54:27 | 0:54:29 | |
making it easier to pass the electric current through that, | 0:54:29 | 0:54:32 | |
which is why this thing is gradually rising. | 0:54:32 | 0:54:34 | |
But how will we know if there is any chemical reaction taking place here? | 0:54:34 | 0:54:39 | |
Well, we're going to keep an eye on this | 0:54:39 | 0:54:42 | |
and look for signs of a reaction. We should see a colour change. | 0:54:42 | 0:54:45 | |
Now, I can demonstrate the colour change that we're going to see. | 0:54:45 | 0:54:48 | |
I have two flasks here. | 0:54:48 | 0:54:50 | |
This contains a compound called nitric oxide. | 0:54:50 | 0:54:53 | |
This is just air. | 0:54:53 | 0:54:55 | |
But when the two come together... | 0:54:55 | 0:54:58 | |
..we form... | 0:54:59 | 0:55:00 | |
..a new compound that we can see, that isn't colourless. | 0:55:03 | 0:55:07 | |
There we are. And this is the gas nitrogen dioxide. | 0:55:07 | 0:55:12 | |
So, this is what we're looking for in our Jacob's ladder. | 0:55:12 | 0:55:16 | |
So the nitrogen, if it combines with the oxygen, | 0:55:16 | 0:55:19 | |
we may be able to see this coloured gas nitrogen dioxide. | 0:55:19 | 0:55:24 | |
We'll keep an eye on the tube there. It just contains air. | 0:55:24 | 0:55:28 | |
I'll just get rid of that. | 0:55:28 | 0:55:31 | |
But this isn't really real lightning. | 0:55:31 | 0:55:35 | |
This is only a very small spark here. | 0:55:35 | 0:55:38 | |
We can maybe begin to see hints of some colour change, | 0:55:38 | 0:55:41 | |
but we'll keep an eye on it. We need a bigger spark. | 0:55:41 | 0:55:44 | |
We need something to produce about a million volts. | 0:55:44 | 0:55:47 | |
And this is what this is for. | 0:55:47 | 0:55:50 | |
This is a Tesla coil | 0:55:50 | 0:55:52 | |
and it can generate a million volts. | 0:55:52 | 0:55:56 | |
We've had some problems with this bit of kit. | 0:55:56 | 0:55:58 | |
It basically fries all the cameras, all the electrics, all the lights. | 0:55:58 | 0:56:02 | |
So this really should give us some rather impressive lightning. | 0:56:02 | 0:56:07 | |
Now, I must ask everyone just to remain in your seats | 0:56:07 | 0:56:11 | |
for this demonstration. Let's see how we go. | 0:56:11 | 0:56:13 | |
BUZZING | 0:56:18 | 0:56:20 | |
Phew. | 0:56:48 | 0:56:51 | |
CHEERING AND APPLAUSE | 0:56:51 | 0:56:53 | |
That really... That really is quite nerve-racking, I must say. | 0:56:59 | 0:57:02 | |
And what we are seeing here with all that energy | 0:57:02 | 0:57:05 | |
was causing the nitrogen molecules and the oxygen molecules | 0:57:05 | 0:57:08 | |
to be ripped apart and then they recombine | 0:57:08 | 0:57:10 | |
to form nitrogen dioxide and that's what we can see, | 0:57:10 | 0:57:14 | |
this brown colour here now in our Jacob's ladder. | 0:57:14 | 0:57:16 | |
And we can also form molecules of ozone. | 0:57:16 | 0:57:19 | |
That's three oxygen atoms together. So, what have we learnt here? | 0:57:19 | 0:57:23 | |
We've learnt that the air is more complicated than we ever thought. | 0:57:23 | 0:57:27 | |
The alchemists thought it was made up of just one element | 0:57:27 | 0:57:30 | |
but they were wrong. It's made up of a number of different elements, | 0:57:30 | 0:57:33 | |
of nitrogen, oxygen. We've seen how important they are to our lives. | 0:57:33 | 0:57:37 | |
Without the oxygen, we'd all be dead. | 0:57:37 | 0:57:40 | |
But with too much, we couldn't survive either. | 0:57:40 | 0:57:42 | |
We've also seen how the very rare gases, the noble gases, can be used | 0:57:42 | 0:57:46 | |
to save lives in hospitals. | 0:57:46 | 0:57:48 | |
Now, the alchemists spent their lives trying to master the elements. | 0:57:48 | 0:57:53 | |
But they only scratched the surface. | 0:57:53 | 0:57:55 | |
They might have been able to play with fire, | 0:57:55 | 0:57:57 | |
but they couldn't control it or understand what it was made of. | 0:57:57 | 0:58:00 | |
Nor could they pick out the elements from the air and use them | 0:58:00 | 0:58:04 | |
to make the world a better place. | 0:58:04 | 0:58:06 | |
This is where the modern alchemist takes over. | 0:58:06 | 0:58:09 | |
Join us in the next lecture where we'll investigate | 0:58:09 | 0:58:13 | |
how a glass of water contains the remnants | 0:58:13 | 0:58:15 | |
of the most violent reactions in the world. | 0:58:15 | 0:58:18 | |
Good night. Thank you. | 0:58:18 | 0:58:19 | |
Subtitles by Red Bee Media Ltd | 0:58:23 | 0:58:26 |